Thermally Conductive Polymer Composites and Articles Made Using the Same
A thermally conductive polymer composite that can have excellent thermal conductivity with a low content of a metal filler and capable of reinforcing mechanical strength by effectively compositing a thermally conductive filler is provided. The polymer composite includes 30 to 85% by volume of a crystalline polymer resin, 5 to 69% by volume of mixed metal fillers, and 1 to 10% by volume of a low-melting-point metal.
1 . A thermally conductive polymer composite comprising:
30 to 85% by volume of a crystalline polymer resin;
5 to 69% by volume of mixed metal fillers; and
1 to 10% by volume of a low-melting-point metal having a solidus temperature lower than a melting point temperature of the crystalline polymer resin.
2 . The polymer composite according to claim 1 , wherein the crystalline polymer resin comprises polyphenylene sulfide (PPS), liquid crystal polymer (LCP), polyamide (PA), syndiotactic polystyrene (sPS), polyetheretherketone (PEEK), polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polyoxymethylene (POM), polypropylene (PP), polyethylene (PE), or a combination thereof.
3 . The polymer composite according to claim 1 , wherein the mixed metal filler comprises fibrous metal fillers and sheet metal fillers.
4 . The polymer composite according to claim 3 , comprising the fibrous metal fillers and sheet metal fillers in a ratio (volume ratio) of 9:1 to 1:9.
5 . The polymer composite according to claim 1 , wherein the mixed metal fillers comprise aluminum, copper, zinc, magnesium, nickel, silver, chromium, iron, molybdenum, stainless steel, or a mixture thereof.
6 . The polymer composite according to claim 3 , wherein the fibrous metal filler has an aspect ratio (length/diameter) of 10 to 10,000.
7 . The polymer composite according to claim 3 , wherein the sheet metal filler has an aspect ratio (length/thickness) of 10 to 100,000.
8 . The polymer composite according to claim 1 , wherein the low-melting-point metal is a metal solid solution comprising two or more metal elements.
9 . The polymer composite according to claim 1 , wherein the low-melting-point metal is a metal solid solution prepared with two or more metals selected from the group consisting of tin, bismuth, lead, copper, aluminum, nickel and silver.
10 . A mold produced from a thermally conductive polymer composite of claim 1 .