Methods for high-rate sputtering of a compound semiconductor on large area substrates
View Patent ↗Methods are generally provided for sputtering thin films on individual substrates. Individual substrates can be conveyed into a vacuum chamber to draw a sputtering pressure that is less than about 50 mTorr. Then, the individual substrates can be conveyed into a sputtering chamber and past a planar magnetron continuously sputtering a target by an ionized gas at the sputtering pressure such that a thin film is formed on a surface of the individual substrate. The target is subjected to a high frequency power having a frequency from about 400 kHz to about 4 MHz at power levels of greater than about 1 kW. In one particular embodiment, the method can be generally directed to sputtering thin films on individual substrates defining a surface having a surface area of about 1000 cm 2 to about 2500 cm 2 .
1. A method of sputtering thin films on individual substrates, the method comprising:
conveying individual substrates into a vacuum chamber to draw a sputtering pressure that is less than about 50 mTorr; and,
conveying the individual substrates into a sputtering chamber and past a planar magnetron continuously sputtering a semiconducting target by an ionized gas at the sputtering pressure such that a thin film is formed on a surface of the individual substrate, and wherein the semiconducting target is subjected to a high frequency power having a frequency from about 400 kHz to about 4 MHz at power levels of greater than about 1 kW, wherein the semiconducting target comprises cadmium sulfide.
2. The method as in claim 1 , wherein the sputtering pressure is from about 1 mTorr to about 25 mTorr.
3. The method as in claim 1 , wherein the substrates are continuously conveyed at a substantially constant linear conveyance rate while sputtering.
4. The method as in claim 1 , wherein the target is subjected to the high frequency power having a frequency from about 1 MHz to about 3 MHz at power levels of from about 2 kW to about 5 kW.
5. The method as in claim 1 , wherein the high frequency power is supplied through an impedance matching network.
6. The method as in claim 1 , wherein the semiconducting target is a planar target having a surface area greater than about 1000 cm 2 .
7. The process as in claim 1 , wherein the semiconducting target is a planar target having a surface area of about 1500 cm 2 to about 2500 cm 2 .
8. The method as in claim 1 , wherein the thin film formed on the surface of the individual substrate has an average thickness of about 50 nm to about 250 nm.
9. The method as in claim 8 , wherein the thin film formed on the surface of the individual substrate has an average thickness of about 70 nm to about 100 nm.
10. The method as in claim 8 , wherein the thin film formed on the surface of the individual substrate has a non-uniformity less than about 20% of the average thickness.
11. The method as in claim 8 , wherein the thin film formed on the surface of the individual substrate has a non-uniformity of about 7% to about 15% of the average thickness.
12. The method as in claim 1 , wherein the thin film is formed on the surface of the individual substrate at a rate faster than 15 nm·m 2 /minute.
13. The method as in claim 1 , wherein the frequency is selected such that magnetic field lines formed during sputtering are not closed in front of the first surface of the substrate.
14. The method as in claim 1 , wherein the ionized gas comprises argon.
15. The method as in claim 1 , wherein the sputtering temperature is about 20° C. to about 25° C.
16. The method as in claim 1 further comprising
heating the individual substrates to a sputtering temperature.
17. The method as in claim 16 , wherein the sputtering temperature is about 50° C. to about 150° C.
18. A method of sputtering thin films on individual substrates defining a surface having a surface area of about 1000 cm 2 to about 2500 cm 2 , the method comprising:
conveying individual substrates into a vacuum chamber to draw a sputtering pressure that is less than about 50 mTorr;
heating the individual substrates to a sputtering temperature of about 50° C. to about 200° C.; and,
conveying the individual substrates into a sputtering chamber and past a planar magnetron continuously sputtering a planar semiconducting target by an ionized gas at the sputtering pressure such that a thin film is formed on the surface of the individual substrate, the planar semiconducting target defining a surface area of about 1000 cm 2 to about 2500 cm 2 , wherein the substrates are continuously conveyed at a substantially constant linear conveyance rate while sputtering such that the thin film formed on the surface of the individual substrate has an average thickness of about 50 nm to about 250 nm with a non-uniformity of about 7% to about 15% of the average thickness, and wherein the semiconducting target is subjected to a high frequency power having a frequency from about 400 kHz to about 4 MHz at power levels of greater than about 1 kW, wherein the semiconducting target comprises cadmium sulfide.
19. The method of claim 1 , wherein a single power source is connected to the semiconducting target to supply the high frequency power.
20. The method of claim 19 , wherein a single power source is connected to the semiconducting target to supply the high frequency power.