Liquid crystal display panel and a method of manufacturing the same
View Patent ↗A black matrix is disposed on a surface of a first base substrate having a switching element, a color filter is disposed on the switching element in a pixel area, a pixel electrode is disposed on the first base substrate having the color filter, and a first alignment layer is disposed on the pixel electrode to form a first substrate. A common electrode layer is disposed on a second base substrate, and a second alignment layer is disposed on the common electrode layer to form a second substrate. A liquid crystal composition including a reactive mesogen (RM) is interposed between opposing surfaces of the first and second substrates. The RM is cured to form a mesogen cured product on the first and second alignment layers. Accordingly, an RM having a planar structure increases curing speed, reduces, manufacturing time, and improves quality of the LCD panel.
1. A method of manufacturing a liquid crystal display panel comprising:
forming a first substrate comprising a black matrix disposed on a surface of a first base substrate having a switching element formed thereon, a color filter disposed on the switching element in a pixel area, a pixel electrode disposed on the substrate having the color filter formed thereon, the pixel electrode being electrically connected to the switching element, and a first alignment layer disposed on the pixel electrode;
forming a second substrate comprising a common electrode layer disposed on a surface of a second base substrate, and a second alignment layer disposed on a surface of the common electrode layer, where the first and second substrates are disposed such that the surfaces having the first and second alignment layers face each other as opposing surfaces;
interposing a liquid crystal composition between the first substrate and the second substrate, the liquid crystal composition comprising a liquid crystal compound and a reactive mesogen represented by the following Chemical Formula 1; and
curing the reactive mesogen to form a liquid crystal layer comprising a mesogen cured product on the first alignment layer and the second alignment layer,
B 1 —Z 1 -A-Z 2 —B 2 Chemical Formula 1
wherein A is a divalent radical represented by
or any combination thereof, each of Z 1 and Z 2 independently represents
a single bond, or any combination thereof, each of B 1 and B 2 independently represents
or any combination thereof, and each occurrence of a hydrogen atom in A is independently replaceable with an alkyl group having 1 to 10 carbon atoms, F, Cl, OCF 3 , OCH 3 , or any combination thereof.
2. The method of claim 1 , wherein the liquid crystal composition comprises about 0.1 percent by weight to about 1.0 percent by weight of the reactive mesogen based on the total weight of the liquid crystal composition.
3. The method of claim 2 , wherein the liquid crystal composition further comprises an initiator.
4. The method of claim 3 , wherein the liquid crystal composition comprises about 0.1 percent by weight to about 1.0 percent by weight of the initiator based on the total weight of the reactive mesogen.
5. The method of claim 3 , wherein the initiator comprises at least one selected from the group consisting of compounds represented by the following Chemical Formulas 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, and any combination thereof:
wherein, R represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.
6. The method of claim 1 , wherein forming the mesogen cured product comprises:
applying a voltage between the first substrate and the second substrate; and
irradiating the first substrate and the second substrate with UV light while the voltage is being applied between the first substrate and the second substrate.
7. The method of claim 6 , wherein forming the mesogen cured product further comprises irradiating the first substrate and the second substrate with UV light while the voltage is not being applied between the first substrate and the second substrate, after irradiating the first substrate and the second substrate with UV light while the voltage is being applied between the first substrate and the second substrate.
8. The method of claim 1 , wherein the first alignment layer and the second alignment layer are configured to arrange a long axis of liquid crystal molecules of the liquid crystal layer in parallel with a vertical direction with respect to a surface of the substrate when a voltage is not applied to the liquid crystal layer.
9. The method of claim 1 , wherein liquid crystal molecules of the liquid crystal compound are pre-tilted by irradiating the liquid crystal molecules with UV light while a voltage is applied to a liquid crystal layer.
10. The method of claim 1 , wherein the pixel electrode comprises a microslit pattern and the common electrode layer is substantially entirely formed on a surface of the second substrate.
11. An LCD panel comprising:
a first substrate comprising a black matrix disposed on a surface of a first base substrate having a switching element formed thereon, a color filter disposed on the switching element in a pixel area, a pixel electrode disposed on a surface of the first base substrate having the color filter formed thereon, the pixel electrode being electrically connected to the switching element, and a first alignment layer disposed on the pixel electrode;
a second substrate comprising a common electrode layer disposed on a surface of a second base substrate, and a second alignment layer disposed on a surface of the common electrode layer where the first and second substrates are disposed such that the surfaces having the first and second alignment layers face each other as opposing surfaces;
a liquid crystal layer interposed between opposing surfaces of the first substrate and the second substrate, the liquid crystal layer comprising a liquid crystal composition comprising a liquid crystal compound and a reactive mesogen represented by the following Chemical Formula 1, wherein the reactive mesogen is cured to form a mesogen cured product on the first alignment layer and the second alignment layer,
B 1 —Z 1 -A-Z 2 —B 2 Chemical Formula 1
wherein A is a divalent radical represented by
or any combination thereof, each of Z 1 and Z 2 independently represents
a single bond, or any combination thereof, each of B 1 and B 2 independently represents
or a combination thereof, and each occurrence of a hydrogen atom in A is independently replaceable with an alkyl group having 1 to 10 carbon atoms, F, Cl, OCF 3 , OCH 3 , or any combination thereof.
12. The LCD panel of claim 11 , wherein the liquid crystal composition comprises about 0.1 percent by weight to about 1.0 percent by weight of the reactive mesogen based on the total weight of the liquid crystal composition.
13. The LCD panel of claim 12 , wherein the liquid crystal composition further comprises an initiator.
14. The LCD panel of claim 13 , wherein the liquid crystal composition comprises about 0.1 percent by weight to about 1.0 percent by weight of the initiator based on a total weight of the reactive mesogen.
15. The LCD panel of claim 13 , wherein the initiator comprises at least one selected from the group consisting of compounds represented by the following Chemical Formulas 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, and any combination thereof:
wherein, R represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.
16. The LCD panel of claim 11 , further comprising a column spacer disposed on the first substrate having a color filter formed thereon to maintain an interval between the first substrate and the second substrate.
17. The LCD panel of claim 16 , wherein the column spacer is formed of a material identical to the black matrix.
18. A liquid crystal composition comprising:
a liquid crystal compound,
0.1 weight percent to 1 weight percent of a reactive mesogen represented by the following Chemical Formula 1, and
an initiator,
wherein the amount of reactive mesogen is based on the total weight of the liquid crystal composition:
B 1 —Z 1 -A-Z 2 —B 2 Chemical Formula 1
wherein A is a divalent radical represented by
or any combination thereof, each of Z 1 and Z 2 independently represents
a single bond, or any combination thereof, each of B 1 and B 2 independently represents
or any combination thereof, and each occurrence of a hydrogen atom in A is independently replaceable with an alkyl group having 1 to 10 carbon atoms, F, Cl, OCF 3 , OCH 3 , or any combination thereof.
19. The liquid crystal composition of claim 18 , wherein the liquid crystal compound comprises a liquid crystal compound of Chemical Formulas 15, 16, 17, 18, 19, 20, or any combination thereof:
wherein in Chemical Formulas 15 to 20, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 and R 12 each independently represent an alkyl-containing group of 1 to 12 carbon atoms.
20. A cure product of the liquid crystal composition of claim 18 .