Method of incorporating an additive into a polyamide-poly(arylene ether) composition, composition prepared thereby, and article comprising the composition
View Patent ↗A method of incorporating an additive into a polyamide-poly(arylene ether) composition includes the step of melt blending a polyamide, a poly(arylene ether), and a dispersion comprising a liquid carrier, an unmodified clay, and an additive. Using the dispersion rather than a polymer-based additive masterbatch saves energy. Like a polymer-based masterbatch, the dispersion provides the additive in a diluted form and therefore preserves the masterbatch's advantages of providing more uniform distribution additive in the plastic and avoiding direct handling of additives in the final compounding step.
1. A method of incorporating an additive into a polyamide-poly(arylene ether) composition, comprising:
melt blending
about 30 to about 70 weight percent of a polyamide,
about 20 to about 50 weight percent of a poly(arylene ether), and
a dispersion comprising
a liquid carrier,
an unmodified clay, and
an additive;
wherein the weight percent values are based on the total weight of the polyamide-poly(arylene ether) composition.
2. The method of claim 1 , wherein the melt blending is conducted under conditions effective to evaporate the liquid carrier.
3. The method of claim 1 , wherein the liquid carrier is selected from the group consisting of water, C 1 -C 18 alcohols, C 2 -C 18 aldehydes, C 3 -C 18 ketones, C 3 -C 18 esters, C 2 -C 18 ethers, mineral oils, organic oils, C 4 -C 18 aliphatic hydrocarbon solvents, C 6 -C 18 aromatic hydrocarbon solvents, liquidized gases, and mixtures thereof.
4. The method of claim 1 , wherein the liquid carrier comprises water.
5. The method of claim 1 , wherein the unmodified clay is selected from the group consisting of kaolinite, dicktite, nacrite, pyrophyillite, talc, vermiculite, sauconite, saponite, nontronite, montmorillonite, illite, amesite, baileychlore, chamosite, clinochlore (kaemmererite), cookeite, corundophilite, daphnite, delessite, gonyerite, nimite, odinite, orthochamosite, penninite, pannantite, rhipidolite (prochlore), sudoite, thuringite, and mixtures thereof.
6. The method of claim 1 , wherein the unmodified clay comprises montmorillonite.
7. The method of claim 1 , wherein the additive is selected from the group consisting of colorants, electrically conductive agents, stabilizers, antioxidants, mold release agents, flame retardants, drip retardants, UV blockers, fragrances, anti-static agents, metal deactivators, antiblocking agents, impact modifiers, and fillers.
8. The method of claim 1 , wherein the additive comprises conductive carbon black, carbon nanotubes, or a combination thereof.
9. The method of claim 1 , wherein the additive comprises carbon nanotubes.
10. The method of claim 1 , wherein the dispersion has a viscosity of about 10 to about 1,000,000 centipoise at 25° C. and a shear rate in the range of about 50 to about 450 sec −1 .
11. The method of claim 1 , wherein the dispersion comprises
about 80 to about 98.9 weight percent of the liquid carrier,
about 1 to about 10 weight percent of the unmodified clay, and
about 0.1 to about 10 weight percent of the additive, wherein the weight percents of the liquid carrier, the unmodified clay, and the additive are based on the weight of the dispersion.
12. The method of claim 1 ,
wherein the dispersion comprises about 83 to about 98 weight percent of the liquid carrier;
wherein the liquid carrier comprises water;
wherein the dispersion comprises about 1 to about 10 weight percent of the unmodified clay;
wherein the unmodified clay comprises montmorillonite;
wherein the dispersion comprises about 1 to about 7 weight percent of the additive;
wherein the additive comprises carbon nanotubes; and
wherein the weight percents of the liquid carrier, the unmodified clay, and the additives are based on the weight of the dispersion.