Light emitting device provided with a wavelength conversion unit incorporating plural kinds of phosphors

1. A light-emitting device, comprising:

a light-emitting element for emitting primary light; and

a wavelength conversion unit for absorbing part of the primary light and emitting secondary lights having wavelengths longer than a wavelength of the primary light,

wherein said wavelength conversion unit includes plural kinds of phosphors having different emission peak wavelengths and different median diameters that are in the order of several microns,

the different median diameters are adjusted so that the plural kinds of phosphors have different settling speeds,

the plural kinds of phosphors include a red phosphor for emitting red light and a green phosphor for emitting green light, and

a concentration of the red phosphor adjacent the light-emitting element is higher than a concentration of the green phosphor adjacent the light-emitting element, and

wherein said red phosphor for emitting red light includes a divalent europium-activated nitride phosphor represented by (MIII 1-j ,Eu j )MIVSiN 3 , where MIII represents at least one kind of element selected from Mg, Ca, Sr and Ba, MIV represents at least one kind of element selected from Al, Ga, In, Sc, Y, La, Gd and Lu, and j represents a number satisfying 0.001≦j≦0.05; and

said green phosphor for emitting green light includes at least one kind selected from

a divalent europium-manganese co-activated aluminate phosphor represented by a(M2,Eu e ,Mn f )O.bAl 2 O 3 ,

a divalent europium-activated silicate phosphor represented by 2(M1 1-g ,Eu g )O.SiO 2 , and

a trivalent cerium-activated silicate phosphor represented by MI 3 (MII 1-h ,Ce h ) 2 (SiO 4 ) 3 ,

where M2 represents at least one kind of element selected from Mg, Ca, Sr, Ba and Zn; a, b, e, and f represent numbers satisfying a>0, b>0, 0.1≦a/b≦1.0, and 0.3≦f/e≦5.0; M1 represents at least one kind of element selected from Mg, Ca, Sr and Ba; g represents a number satisfying 0.005≦g≦0.10; MI represents at least one kind of element selected from Mg, Ca, Sr and Ba; MII represents at least one kind of element selected from Al, Ga, In, Sc, Y, La, Gd and Lu; and h represents a number satisfying 0.005≦h≦0.5.

2. The light-emitting device according to claim 1 , wherein a phosphor having a relatively longer emission peak wavelength has a relatively larger median diameter as compared with a phosphor having a relatively shorter emission peak wavelength.

3. The light-emitting device according to claim 1 , wherein the plural kinds of phosphors further include a phosphor for emitting blue light; and

said phosphor for emitting blue light includes at least one kind selected from

a divalent europium-activated halophosphate phosphor represented by (M1,Eu) 10 (PO 4 ) 6 .Cl 2 ,

a divalent europium-activated aluminate phosphor represented by a(M2,Eu)O.bAl 2 O 3 , and

a divalent europium-manganese co-activated aluminate phosphor represented by a(M2,Eu c ,Mn d )O.bAl 2 O 3 ,

where M1 represents at least one kind of element selected from Mg, Ca, Sr and Ba; M2 represents at least one kind of element selected from Mg, Ca, Sr, Ba and Zn; and a, b, c and d represent numbers satisfying a>0, b>0, 0.1≦a/b≦1.0, and 0.001≦d/c≦0.2.

4. The light-emitting device according to claim 1 , wherein a phosphor having a relatively longer emission peak wavelength has a greater particle-concentration near said light-emitting element as compared with a phosphor having a relatively shorter emission peak wavelength.

5. A light-emitting device, comprising:

a light-emitting element for emitting primary light; and

a wavelength conversion unit for absorbing part of the primary light and emitting secondary lights having wavelengths longer than a wavelength of the primary light,

wherein the wavelength conversion unit includes plural kinds of phosphors having different emission peak wavelengths and different median diameters,

the plural kinds of phosphors contain activators, and

the different median diameters are adjusted so that the plural kinds of phosphors have different settling speeds,

the plural kinds of phosphors include a red phosphor for emitting red light and a green phosphor for emitting green light, and

a concentration of the red phosphor adjacent the light-emitting element is higher than a concentration of the green phosphor adjacent the light-emitting element, and

wherein said red phosphor for emitting red light includes a divalent europium-activated nitride phosphor represented by (MIII 1-j ,Eu j )MIVSiN 3 , where MIII represents at least one kind of element selected from Mg, Ca, Sr and Ba, MIV represents at least one kind of element selected from Al, Ga, In, Sc, Y, La, Gd and Lu, and j represents a number satisfying 0.001≦j≦0.05; and

said green phosphor for emitting green light includes at least one kind selected from

a divalent europium-manganese co-activated aluminate phosphor represented by a(M2,Eu e ,Mn f )O.bAl 2 O 3 ,

a divalent europium-activated silicate phosphor represented by 2(M1 1-g ,Eu e )O.SiO 2 , and

a trivalent cerium-activated silicate phosphor represented by MI 3 (MII 1-h ,Ce h ) 2 (SiO 4 ) 3 ,

where M2 represents at least one kind of element selected from Mg, Ca, Sr, Ba and Zn; a, b, e, and f represent numbers satisfying a>0, b>0, 0.1≦a/b≦1.0, and 0.3≦f/e≦5.0; M1 represents at least one kind of element selected from Mg, Ca, Sr and Ba; g represents a number satisfying 0.005≦g≦0.10; MI represents at least one kind of element selected from Mg, Ca, Sr and Ba; MII represents at least one kind of element selected from Al, Ga, In, Sc, Y, La, Gd and Lu; and h represents a number satisfying 0.005≦h≦0.5.

6. A light-emitting device, comprising:

a light-emitting element for emitting primary light; and

a wavelength conversion unit for absorbing part of the primary light and emitting secondary lights having wavelengths longer than a wavelength of the primary light,

wherein the wavelength conversion unit includes plural kinds of phosphors having different emission peak wavelengths and different median diameters,

the emission peak wavelengths are independent of the median diameters, and

the different median diameters are adjusted so that the plural kinds of phosphors have different settling speeds,

the plural kinds of phosphors include a red phosphor for emitting red light and a green phosphor for emitting green light, and

a concentration of the red phosphor adjacent the light-emitting element is higher than a concentration of the green phosphor adjacent the light-emitting element, and

wherein said red phosphor for emitting red light includes a divalent europium-activated nitride phosphor represented by (MIII 1-j ,Eu j )MIVSiN 3 , where MIII represents at least one kind of element selected from Mg, Ca, Sr and Ba, MIV represents at least one kind of element selected from Al, Ga, In, Sc, Y, La, Gd and Lu, and j represents a number satisfying 0.001≦j≦0.05; and

said green phosphor for emitting green light includes at least one kind selected from

a divalent europium-manganese co-activated aluminate phosphor represented by a(M2,Eu e ,Mn f )O.bAl 2 O 3 ,

a divalent europium-activated silicate phosphor represented by 2(M1 1-g ,Eu g )O.SiO 2 , and

a trivalent cerium-activated silicate phosphor resented by MI 3 (MII 1-h ,Ce h ) 2 (SiO 4 ) 3 ,

where M2 represents at least one kind of element selected from Mg, Ca, Sr, Ba and Zn; a, b, e, and f represent numbers satisfying a>0, b>0, 0.1≦a/b≦1.0, and 0.3≦f/e≦5.0; M1 represents at least one kind of element selected from Mg, Ca, Sr and Ba; g represents a number satisfying 0.005≦g≦0.10; MI represents at least one kind of element selected from Mg, Ca, Sr and Ba; MII represents at least one kind of element selected from Al, Ga, In, Sc, Y, La, Gd and Lu; and h represents a number satisfying 0.005≦h≦0.5.