Compositions and methods for selective deposition modeling
View Patent ↗There is provided compositions and methods for producing three-dimensional objects by selective deposition modeling with a polar build material and a non-polar support material. The build material comprises a hydrocarbon wax material and a viscosity modifier, and the support material comprises a hydrocarbon alcohol wax material and a viscosity modifier. After the selective deposition modeling process has been completed, the object can be placed in a bath of polar solvent to remove the support material. The particular materials provided herein, and the post-processing methods associated therewith, provide for improved part quality of the three-dimensional object and for improved post-processing techniques. The three-dimensional objects can subsequently be used in a number of applications, such as patterns for investment casting.
1. A combination of compositions used to produce a three-dimensional object with a selective deposition modeling apparatus, the combination comprising:
(a) a build material comprising:
(i) a build hydrocarbon wax material defining a melting temperature of between about 70° C. and about 80° C., wherein the build hydrocarbon wax material comprises between 75% and 85% by weight of the build material, and
(ii) at least one build viscosity modifier defining a softening temperature of between about 90° C. and about 145° C. and defining a hydrocarbon resin free of oxygen, wherein the build viscosity modifier comprises between 15% and 25% by weight of the build material,
wherein the build material defines a viscosity of between about 11 and about 14 centipoise at 80° C. and the build material defines a melting temperature of between about 65° C. and about 85° C.; and
(b) a support material comprising:
(i) a support hydrocarbon alcohol wax material defining a melting temperature of between about 52° C. and about 65° C., wherein the support hydrocarbon wax material comprises between 60% and 68% by weight of the support material, and
(ii) at least one support viscosity modifier defining a hydrogenated rosin that comprises between about 60 and about 200 acid number, wherein the support viscosity modifier comprises between 32% and 40% by weight of the support material,
wherein the support material defines a viscosity of between about 11 and about 14 centipoise at 80° C.
2. A combination of compositions in accordance with claim 1 , wherein the build hydrocarbon wax material comprises a paraffin wax.
3. A combination of compositions in accordance with claim 1 , wherein the build viscosity modifier defines a softening temperature of between about 115° C. and about 125° C.
4. A combination of compositions in accordance with claim 1 , wherein the build viscosity modifier comprises a hydrogenated hydrocarbon resin.
5. A combination of compositions in accordance with claim 1 , wherein the build hydrocarbon wax material comprises about 81% by weight of the build material and the build viscosity modifier comprises about 19% by weight of the build material.
6. A combination of compositions in accordance with claim 1 , wherein the support hydrocarbon alcohol wax material comprises at least one of octadecanol and hexadecanol.
7. A combination of compositions in accordance with claim 1 , wherein the support viscosity modifier defines a hydrogenated rosin having about 120 acid number.
8. A combination of compositions in accordance with claim 1 , wherein the support hydrocarbon wax material comprises about 65% by weight of the support material and the support viscosity modifier comprises about 35% by weight of the support material.
9. A combination of compositions in accordance with claim 1 , wherein the build material defines a viscosity of about 12 centipoise at 80° C. and wherein the support material defines a viscosity of about 12.5 centipoise at 80° C.
10. A combination of compositions used to produce a three-dimensional object with a selective deposition modeling apparatus, the combination comprising:
(a) a build material consisting essentially of:
(i) a build hydrocarbon wax material comprising between 75% and 85% by weight of the build material, and
(ii) at least one build viscosity modifier defining a softening temperature of between about 90° C. and about 145° C. and defining a hydrocarbon resin free of oxygen, wherein the build viscosity modifier comprises between 15% and 25% by weight of the build material,
wherein the build material defines a viscosity of between about 11 and about 14 centipoise at 80° C.; and
(b) a support material consisting essentially of:
(i) a support hydrocarbon alcohol wax material comprising between 60% and 68% by weight of the support material, and
(ii) at least one support viscosity modifier defining a hydrogenated rosin that comprises between about 60 and about 200 acid number, wherein the support viscosity modifier comprises between 32% and 40% by weight of the support material,
wherein the support material defines a viscosity of between about 11 and about 14 centipoise at 80° C.
11. A combination of compositions in accordance with claim 10 wherein the build hydrocarbon wax comprises a paraffin wax.
12. A combination of compositions in accordance with claim 10 wherein the build viscosity modifier comprises a hydrogenated hydrocarbon resin.
13. A combination of compositions in accordance with claim 10 wherein the support hydrocarbon alcohol wax comprises at least one of octadecanol and hexadecanol.
14. A combination of compositions in accordance with claim 10 wherein the support viscosity modifier defines a hydrogenated rosin having about 120 acid number.