Recycling methane-rich purge gas to gasifier
View Patent ↗A process for improving the overall carbon conversion efficiency of a gasification process, as well as improving the suitability of a syngas containing 0.5-10% methane for use as a feedstock for chemical production. A gasification reactor converts carbonaceous feedstock to syngas that is, in turn, utilized for a chemical production process in a chemical production reactor. An off-gas from this chemical production reactor is directed to a selective membrane that separates the off-gas into methane-rich and hydrogen-rich fractions. The hydrogen-rich fraction, is re-utilized as feedstock for the chemical production process, while the methane-enriched fraction is returned to the gasification reactor to form additional syngas.
1. A process comprising:
a) providing a gasification reactor;
b) partially oxidizing a carbonaceous feedstock in said reactor to produce a product gas comprising H 2 , CO, and methane;
c) utilizing the product gas as feedstock for a chemical synthesis reactor to thereby produce a reaction product and an off-gas stream;
d) separating the off-gas stream into a hydrogen-rich gas stream, and a methane-rich purge gas stream;
e) compressing the methane-rich purge gas stream, then routing said stream back to the gasification reactor,
wherein said methane-rich purge gas stream serves as carbonaceous feedstock for additional production of said product gas of part b).
2. The process of claim 1 , wherein the separation of part d) is performed by a selective membrane.
3. The process of claim 1 , wherein the gasification reactor comprises a first reaction zone and a second reaction zone, and wherein a partial oxidation of the feedstock is the predominant reaction occurring within the first reaction zone, while pyrolysis of the feedstock is the predominant reaction occurring within the second reaction zone.
4. The process of claim 3 , wherein the methane-rich purge gas stream is compressed, then routed to the first reaction zone of the gasification reactor.
5. The process of claim 1 , wherein the methane-rich purge gas stream of part e) is converted to carbon monoxide and hydrogen gas in the gasification reactor via the steam-methane reforming reaction: CH 4 +H 2 O→CO+3H 2 .
6. The process of claim 1 , wherein said hydrogen-rich gas stream is utilized as a feedstock for a chemical production process that may comprise a Fischer-Tropsch process, or a process for the production of methanol, methyl acetate, urea, urea ammonium nitrate, ammonia or hydrogen.
7. The process of claim 1 , wherein the overall rate of carbonaceous feedstock consumption is decreased by about 2% (by weight) or more.
8. The process of claim 1 , wherein the amount of oxygen required for partially oxidizing said carbonaceous feedstock is decreased.
9. The process of claim 1 , wherein the methane content of the product gas of part a) is between about 0.5% and 10% by weight.
10. The process of claim 1 , wherein the molar fraction of methane in the methane-rich purge gas is between about 10% and about 75%.
11. The process of claim 1 , wherein the molar fraction of methane in the methane-rich purge gas is between about 25% and about 65%.
12. A process comprising:
a) providing a gasification reactor;
b) partially oxidizing a carbonaceous feedstock in said reactor to produce a product gas comprising H 2 , CO, and methane;
c) utilizing the product gas as feedstock for a chemical synthesis reactor to thereby produce a reaction product and an off-gas stream;
d) separating the off-gas stream into a hydrogen-rich gas stream, and a methane-rich purge gas stream,
wherein said separation is performed by a selective membrane;
e) compressing the methane-rich purge gas stream, then routing said stream back to the gasification reactor,
wherein said methane-rich purge gas stream serves as carbonaceous feedstock for additional production of said product gas of part b), and
wherein the methane-rich purge gas stream is converted to carbon monoxide and hydrogen gas in the gasification reactor via the steam-methane reforming reaction:
CH 4 +H 2 O→CO+3H 2 .
13. A process comprising:
a) providing a gasification reactor;
wherein the gasification reactor comprises a first reaction zone and a second reaction zone,
and wherein a partial oxidation of the feedstock is the predominant reaction occurring within the first reaction zone, while pyrolysis of the feedstock is the predominant reaction occurring within the second reaction zone;
b) partially oxidizing a carbonaceous feedstock in said reactor to produce a product gas comprising H 2 , CO, and methane;
c) utilizing the product gas as feedstock for a chemical synthesis reactor to thereby produce a reaction product and an off-gas stream;
d) separating the off-gas stream into a hydrogen-rich gas stream, and a methane-rich purge gas stream,
wherein said separation is performed by a selective membrane;
e) compressing the methane-rich purge gas stream, then routing said stream back to the gasification reactor,
wherein said methane-rich purge gas stream serves as carbonaceous feedstock for additional production of said product gas of part b), and
wherein said methane-rich purge gas stream is routed to the first reaction zone of the gasification reactor, and
wherein the methane-rich purge gas stream is converted to carbon monoxide and hydrogen gas in the gasification reactor via the steam-methane reforming reaction:
CH 4 +H 2 O→CO+3H 2 .
14. The process of claim 12 or 13 , wherein the overall rate of carbonaceous feedstock consumption by said gasification reactor is decreased by about 2% (by weight) or more.
15. The process of claim 12 or 13 , wherein the amount of oxygen required for partially oxidizing said carbonaceous feedstock is decreased.
16. The process of claim 12 or 13 , wherein said hydrogen-rich gas stream is utilized as a feedstock for a chemical production process that may comprise a Fischer-Tropsch process, or a process for the production of methanol, methyl acetate, urea, urea ammonium nitrate, ammonia or hydrogen.