Luminescent ceramic and light-emitting device using the same
Some embodiments provide luminescent ceramics which have a lower amount of dopant than conventional luminescent ceramics. In some embodiments, the luminescent ceramic comprises a host material comprising a rare earth element and at least one rare earth dopant, wherein the rare earth dopant may be about 0.01% to 0.5% of the rare earth atoms present in the material. Some embodiments provide luminescent ceramic comprising: a polycrystalline phosphor represented by the formula (A 1-x E x ) 3 B 5 O 12 . Some embodiments provide a light-emitting device comprising a luminescent ceramic disclosed herein.
1. A luminescent ceramic comprising:
a polycrystalline phosphor represented by the formula (A 1-x E x ) 3 B 5 O 12 ;
wherein A comprises Y and Gd;
x is in the range of about 0.0001 to about 0.004;
B is Al; and
E is Ce;
wherein the ceramic has a wavelength of maximum absorbance in the range of about 420 nm to about 480 nm, and wherein said ceramic has a first luminescent efficiency at 200° C. and a second luminescent efficiency at 25° C., wherein the first luminescent efficiency is at least about 82% of the second luminescent efficiency.
2. The ceramic of claim 1 , wherein the ceramic emits light having a wavelength of maximum emission in the range of about 500 nm to about 750 nm.
3. The ceramic of claim 1 , wherein no more than about 0.05 mole percent of A is the Gd.
4. The ceramic of claim 1 , wherein the phosphor is further represented by the formula (Y 1-(x+y) Gd y Ce x ) 3 B 5 O 12 , wherein y is in the range of about 0.005 to about 0.05.
5. The ceramic of claim 1 , wherein x is in the range of about 0.0001 to about 0.003.
6. The ceramic of claim 1 , wherein the phosphor is further represented by the formula (Y 0.978 Gd 0.02 Ce 0.002 ) 3 Al 5 O 12 .
7. The ceramic of claim 1 , further comprising a second component different from the polycrystalline phosphor.
8. The ceramic of claim 7 , wherein said second component is selected from alumina, yttria, and yttrium aluminum oxide.
9. A light-emitting device comprising:
a light-emitting diode having a wavelength of maximum emission in the range of about 420 nm to about 480 nm, and
a luminescent ceramic according to claim 1 , wherein the luminescent ceramic is positioned to receive and convert at least a portion of the light emitted from the light-emitting diode to light having a wavelength of maximum emission in the range of about 500 nm to about 700 nm.
10. The light-emitting device of claim 9 , wherein said luminescent ceramic has a thickness in the range of about 50 μm to about 5 mm.
11. The light-emitting device of claim 9 , wherein the total light transmittance of said luminescent ceramic is greater than or equal to about 50%.
12. The light-emitting device of claim 9 , wherein x is in the range of about 0.0001 to about 0.002.
13. The light-emitting device of claim 9 , wherein the phosphor is further represented by the formula (Y 1-(x+y) Gd y Ce x ) 3 B 5 O 12 , wherein y is in the range of about 0.005 to about 0.05.
14. The light-emitting device of claim 9 , further comprising at least a second ceramic component.
15. The light-emitting device of claim 14 , wherein the second component is selected from alumina, yttria, and yttrium aluminum oxide.
16. The luminescent ceramic of claim 1 , wherein x is in the range of about 0.0001 to about 0.002.
17. The luminescent ceramic of claim 1 , wherein the luminescent ceramic is substantially void-free.