Display device having polarizing layer and manufacturing method of the same
View Patent ↗The present invention relates to a polarization layer for an LCD and a manufacturing method thereof that improve light transmittance and polarization performance of a polarization layer by controlling a pre-tilt angle of an alignment layer. The manufacturing method of the present invention includes forming an alignment layer treated by inorganic alignment, forming a liquid crystal mixture including a dichroic dye, a liquid crystal monomer, a photo-initiator, and a gelator on the alignment layer, irradiating light to the liquid crystal mixture for photo-polymerizing it, and forming a color filter (CF) or a thin film transistor (TFT) on the polymerized and solidified liquid crystal mixture. Accordingly, the polarization layer manufactured by the present invention has the high light transmittance thereby increasing the polarization efficiency and realizing the liquid crystal display of high quality compared with the conventional polarization layer by the rubbing alignment.
1. A method for manufacturing a liquid crystal display, comprising:
providing a first insulation substrate;
forming a thin film transistor on the first insulation substrate;
forming a first substrate on the thin film transistor;
forming a first alignment layer on the first substrate;
coating a dichroic pigment, a liquid crystal mixture, a photo-initiator, and a gelator on the first alignment layer;
sequentially applying a high temperature and a low temperature to the liquid crystal mixture to arrange the liquid crystal on the first alignment layer; and
solidifying the arranged liquid crystal mixture through polymerization by the gelator to form a first polarization layer.
2. The method of claim 1 , wherein
the high temperature for the liquid crystal mixture is in the range of about 120 to about 130° C., and the low temperature is near room temperature.
3. The method of claim 2 , further comprising:
providing a second insulation substrate corresponding to the first insulation substrate;
forming a second substrate on the second insulation substrate;
forming a second alignment layer on the second substrate;
coating a dichroic pigment, a liquid crystal mixture, a photo-initiator, and a gelator on the second alignment layer;
sequentially applying a high temperature and a low temperature to the liquid crystal mixture to arrange the liquid crystal on the second alignment layer; and
solidifying the arranged liquid crystal mixture through polymerization by the gelator to form a second polarization layer.
4. The method of claim 3 , further comprising
forming a color filter on the thin film transistor or the second insulation substrate.
5. The method of claim 4 , wherein
an alignment direction of the first alignment layer and an alignment direction of the second alignment layer are perpendicular to each other.
6. The method of claim 4 , further comprising
forming a pre-tilt on the first and second alignment layers.
7. The method of claim 6 , wherein
the pre-tilt of the first and second alignment layers is formed by one of ion beam irradiation, plasma arrangement, and photo-alignment.
8. The method of claim 7 , wherein
the pre-tilt of the first and second alignment layers by the ion beam irradiation is formed with irradiation energy of less than about 100 eV.
9. The method of claim 8 , wherein
the first and second alignment layers are formed by one of spin coating, imprinting, and Inkjet printing.
10. A liquid crystal display comprising:
a first insulation substrate;
a thin film transistor formed on the first insulation substrate;
a first substrate formed on the thin film transistor;
a first alignment layer formed on the first substrate; and
a first polarization layer formed on the first alignment layer, the first polarization layer including a dichroic pigment and a photo-hardener, and a cross-linked liquid crystal mixture and a gelator polymerized in a predetermined arrangement,
wherein a pre-tilt angle of the first alignment layer is less than about 2 degrees.
11. The liquid crystal display of claim 10 , wherein
the dichroic pigment is a dichroic dye.
12. The liquid crystal display of claim 11 wherein
the liquid crystal mixture is a diacrylate reactive mesongen (RM) as shown in Chemical Formula 1;
13. The liquid crystal display of claim 12 , further comprising:
a second insulation substrate corresponding to the first insulation substrate;
a second substrate formed on the second insulation substrate;
a second alignment layer formed on the second substrate; and
a second polarization layer formed on the second alignment layer, the second polarization layer including a dichroic pigment and a photo-hardener, and a cross-linked liquid crystal mixture and a gelator polymerized in a predetermined arrangement.
14. The liquid crystal display of claim 13 , wherein
an alignment direction of the first alignment layer and an alignment direction of the second alignment layer are perpendicular to each other.
15. The liquid crystal display of claim 14 , further comprising
a color filter formed on the thin film transistor or the second substrate.
16. The liquid crystal display of claim 15 , wherein
a pre-tilt angle of the second alignment layer is less than about 2 degrees.
17. The liquid crystal display of claim 16 , wherein
the first and second alignment layers are at least one of diamond-like carbon (DLC), SiOx, and a photo-alignment layer.
18. A method for manufacturing a liquid crystal display, comprising:
providing a first insulation substrate;
forming one of a thin film transistor and a color filter on the first insulation substrate;
forming a first substrate on the one of the thin film transistor and the color filter formed on the first insulation substrate;
forming a first alignment layer on the first substrate;
coating a dichroic pigment, a liquid crystal mixture, a photo-initiator, and a gelator on the first alignment layer;
applying a high temperature and a low temperature to the liquid crystal mixture to arrange the liquid crystal on the first alignment layer; and
solidifying the arranged liquid crystal mixture through polymerization by the gelator to form a first polarization layer.
19. The method of claim 18 , further comprising:
providing a second insulation substrate corresponding to the first insulation substrate;
forming the other of the thin film transistor and the color filter on the second insulation substrate;
forming a second substrate on the thin film transistor and the color filter formed on the second insulation substrate;
forming a second alignment layer on the second substrate;
coating a dichroic pigment, a liquid crystal mixture, a photo-initiator, and a gelator on the second alignment layer;
applying a high temperature and a low temperature to the liquid crystal mixture to arrange the liquid crystal on the second alignment layer; and
solidifying the arranged liquid crystal mixture through polymerization by the gelator to form a second polarization layer.
20. The method of claim 19 , wherein the thin film transistor is formed on the first insulation substrate and the first substrate is formed on the thin film transistor and wherein the color filter is formed on the second insulation substrate and the second substrate is formed on the color filter.