Non-corrosive EP grease composition
View Patent ↗The invention relates to an extreme pressure additive composition with excellent corrosion resistance properties for use in grease, as well as a lubricating grease composition containing the additive. The additive composition is based on (a) approximately equal amounts by mass of antimony diamyldithiocarbamate and zinc diamyldithiocarbamate, and (b) thiadiazole dimer poly(ether)glycol complex; at (a):(b) mass ratio of about 1.6:1 to about 9.6:1.
1. A lubricating composition for providing extreme pressure protection and corrosion resistance, comprising a major amount of base grease, and
(a) approximately equal amounts by mass of antimony diamyldithiocarbamate and zinc diamyldithiocarbamate, at a total of about 1.6-2.4 mass %, and
(b) thiadiazole dimer poly(ether)glycol complex at about 0.25-1.0 mass %.
2. The composition of claim 1 , wherein the thiadiazole dimer poly(ether)glycol complex comprises:
(i) one or more thiadiazole compound as follows:
(A) dimers of 2,5-dimercapto-1,3,4-thiadiazole (DMTD) having the formula:
wherein n is 1 and/or 2; and/or
(B) 2-mercapto-1,3,4-thiadiazole (MTD) having formula:
and (ii) poly(ether)glycol having formula:
wherein R 1 is hydrogen, a branched or straight chain C 1 to C 4 alkyl radical, a phenyl radical, alkylated phenyl radical, a C 1 to C 8 branched and straight chain acyl radical, and combination thereof, and m is 1 to 20.
3. The composition of claim 2 , wherein the poly(ether) glycols is chosen from one or more in combination of butoxytriglycol, polyethylene glycol and iso-octyl phenoxy poly(ether)glycoll.
4. The composition of claim 3 , wherein the poly(ether) glycol is a combination of butoxytriglycol and polyethylene glycol.
5. The composition of claim 2 , wherein the thiadiazole dimer poly(ether)glycol complex comprises, in mass percent, about 10% to 60% thiadiazole compound(s) and about 40% to 90% poly(ether)glycol compound(s).
6. The composition of claim 5 , wherein the thiadiazole dimer poly(ether)glycol complex comprises, in mass percent, about 25% to 50% thiadiazole compound(s) and about 50% to 75% poly(ether)glycol compound(s).
7. The composition of claim 6 , wherein the thiadiazole dimer poly(ether)glycol complex comprises, in mass percent, about 30% to 40% thiadiazole compound(s) and about 60% to 70% poly(ether)glycol.
8. The composition of claim 7 , wherein the thiadiazole dimer poly(ether)glycol complex comprises, in mass percent, about:
(i) (A) 15% mono sulfide dimer of DMTD, and 10% disulfide dimer of DMTD,
(B) 10% MTD; and
(ii) 65% poly(ether)glycol, being either (I) a combination of 49% butoxytriglycol and 16% polyethylene glycol, or (II) iso-octyl phenoxy poly(ether)glycol.