Process for agglomeration of superabsorbent polymer fine particles

1. A process for producing an agglomerated superabsorbent polymer particle comprising less than about 10 wt. %, based on the total weight of the agglomerated superabsorbent polymer particle, of superabsorbent polymer fine particles having a particle size of less than about 150 μm, said process steps comprising:

(A) supplying (i) post crosslinked superabsorbent polymer fine particles having at least about 40 wt. %, based on the total weight of the agglomerated superabsorbent polymer particle, a particle size of less than about 150 μm

(B) spraying or mixing the post crosslinked superabsorbent polymer fine particles of (A) with a fluid comprising a) more than about 18 wt. % to about 55 wt %, based on the total weight of the fluid, of a cross-linkable, uncross-linked polyacrylate solution neutralized to from about 45 mol % to about 55 mole %, which polyacrylate solution is based on polymerized, polyacrylic acid or salts thereof to at least about 20 wt. %, based on the total weight of the cross-linkable, uncrosslinked polymer, and b) a crosslinker;

(C) heating the post crosslinked superabsorbent polymer fine particles brought into contact with the fluid of step (B) to a temperature within a range from about 100 to about 200° C., so that the cross-linkable, uncross-linked polymer at least partially crosslinks to form agglomerated superabsorbent polymer particles having a particle size of more than about 850 μm; and

(D) comminuting the agglomerated superabsorbent polymer particles of step (C) to produce at least about 80 wt. % of the agglomerated superabsorbent polymer particles of step (C) to have a particle size within the range of about 200 μm to about 900 μm;

wherein

(a) the cross-linkable, uncross-linked polyacrylate solution comprises, besides the polymerized, ethylenically unsaturated, acid groups-bearing monomers, further polymerized, ethylenically unsaturated monomers (M) capable of reacting with polymerized acid group-bearing monomers in a condensation reaction, in an addition reaction, or in a ring opening reaction, and

(b) wherein the agglomerated superabsorbent polymer particle has less than about 10 wt. %, based on the total weight of the agglomerated superabsorbent polymer particle, of superabsorbent polymer fine particle size of less than about 150 μm.

2. The process according to claim 1 , wherein the post crosslinked superabsorbent polymer fine particles comprise:

(α1) from about 0.1 wt. % to about 99.999 wt. % of polymerized, ethylenically unsaturated, acidic group-containing monomers or salts thereof, or polymerized, ethylenically unsaturated monomers containing a protonated or a quaternary nitrogen, or mixtures thereof, wherein mixtures comprising at least ethylenically unsaturated, acidic groups-containing monomers, preferably acrylic acid, are one aspect;

(α2) from 0 wt % to about 70 wt % of polymerized, ethylenically unsaturated monomers which can be co-polymerized with (α1);

(α3) from about 0.001 wt. % to about 10 wt. % of one or more cross-linkers;

(α4) from 0 wt % to about 30 wt % of water-soluble polymers;

(α5) from 0.3 wt % to about 5 wt % of hased on the weight of the superabsorbent polymer fine particles of a post crosslinker;

(α6) from 0 wt % to about 20 wt % of one or more auxiliaries, wherein the sum of the component weights (α1) to (α6) amounts to about 100 wt. %.

3. The process according to claim 1 , wherein the cross-linkable, uncrosslinked polyacrylate solution comprises a weight average molecular weight of more than about 8000 g/mol.

4. The process according to claim 1 , wherein the monomer (M) comprises a polymerized, ethylenically unsaturated conversion product of saturated aliphatic, cycloaliphatic, aromatic alcohols, amines or thiols with ethylenically unsaturated carboxylic acid, carboxylic acid derivatives or allyl halides.

5. The process according to claim 1 , wherein the postcrosslinker is ethylene carbonate.

6. The process according to claim 1 , wherein the bringing into contact of the superabsorbent polymer fine particles with the fluid occurs in the presence of an effect material comprising a polysaccharide or a polyalkylether polyol or a silicon-oxygen-comprising compound or a mixture of at least two thereof.

7. The process according to claim 6 , wherein the effect material comprises a zeolite.

8. The process according to claim 1 , wherein the bringing into contact occurs in a fluidized bed.

9. An agglomerated superabsorbent polymer particle obtained by a process according to claim 1 .

10. The agglomerated superabsorbent polymer particles made according to the process of claim 1 , wherein the agglomerated superabsorbent polymer particles have at least one of the following properties:

a1) a particle size distribution, whereby at least about 90 wt. % of the agglomerated superabsorbent polymer particles of step (C) to have a particle size within the range of about 200 μm to about 900 μm;

a2) a Centrifuge Retention Capacity (CRC) of at least about 5 g/g;

a3) an Absorption Against Pressure (AAP) at about 0.7 psi of at least about 5 g/g;

a4) a water-soluble polymer content of less than about 25 wt. % after about 16 hours extraction.