IP Library Granted Patent US 8,377,835
Granted Patent B2
US 8,377,835 · App. 12/790,141 · Granted Feb 19, 2013

Optical glass

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Quick Facts
Patent No.
US 8,377,835
App. No.
12/790,141
Granted
Feb 19, 2013
Kind
B2
Abstract

The present invention relates to an optical glass containing, in terms of mass % on the basis of oxides, B 2 O 3 : 10 to 20%, SiO 2 : 0.5 to 12%, ZnO: 5 to 19%, Ta 2 O 5 : 2.5 to 17%, Li 2 O: 0.2 to 3%, ZrO 2 : 0.6 to 4.9%, WO 3 : 1 to 20%, La 2 O 3 : 25 to 50%, Gd 2 O 3 : 0 to 13%, and Y 2 O 3 : 0.2 to 20%, provided that La 2 O 3 +Gd 2 O 3 +Y 2 O 3 is 35 to 60%, in which the optical glass does not substantially contain Nb 2 O 5 , and has a refractive index (n d ) of 1.82 to 1.86, an Abbe's number (ν d ) of 37 to 44 and a glass transition point (T g ) of 630° C. or lower.

Claims (44)

1. An optical glass comprising, in terms of mass % on the basis of oxides:

B 2 O 3 : 10 to 20%,

SiO 2 : more than 2 to 12%,

ZnO: 5 to 19%,

Ta 2 O 5 : 2.5 to 17%,

Li 2 O: 0.2 to 3%,

ZrO 2 : 0.6 to 4.9%,

WO 3 : 1 to 20%,

La 2 O 3 : 25 to 50%,

Gd 2 O 3 : 0 to 13%, and

Y 2 O 3 : 0.2 to 20%,

provided that La 2 O 3 +Gd 2 O 3 +Y 2 O 3 is 35 to 60%,

wherein the optical glass does not substantially comprise Nb 2 O 5 , and has a refractive index (n d ) of 1.82 to 1.86, an Abbe's number (ν d ) of 37 to 44 and a glass transition point (T g ) of 630° C. or lower.

2. The optical glass according to claim 1 , having a liquidus temperature (T L ) of 1130° C. or lower.

3. The optical glass according to claim 2 , wherein, at the liquidus temperature (T L ) or lower of the optical glass, a plurality of devitrified substances do not precipitate and only LaBO 3 precipitates.

4. The optical glass according to claim 1 , having a liquidus temperature viscosity (η TL ) of 5 dPa·s or more.

5. The optical glass according to claim 1 , wherein a mass % fraction of a content of La 2 O 3 to a total content of La 2 O 3 , Gd 2 O 3 , Y 2 O 3 and Yb 2 O 3 is 0.67 to 0.90.

6. A preform for precision press molding, comprising the optical glass according to claim 1 .

7. An optical element obtained by subjecting the optical glass according to claim 1 to precision press molding.

8. The optical glass according to claim 1 , wherein the mass % on the basis of oxides is:

B 2 O 3 : 12 to 19.5%,

SiO 2 : more than 2 to 10%,

ZnO: 6.5 to 17%,

Ta 2 O 5 : 8 to 13%,

Li 2 O: 0.5 to 2%,

ZrO 2 : 1.5 to 4.5%,

WO 3 : 8 to 16%,

La 2 O 3 : 30 to 46%,

Gd 2 O 3 : 2 to 12%, and

Y 2 O 3 : 1 to 15%,

provided that La 2 O 3 +Gd 2 O 3 +Y 2 O 3 is 43 to 55%.

9. An optical glass comprising, in terms of mol % on the basis of oxides:

B 2 O 3 : 20 to 40%,

SiO 2 : 8.3 to 30%,

ZnO: 10 to 34%,

Ta 2 O 5 : 0.8 to 8%,

Li 2 O: 0.5 to 15%,

ZrO 2 : 0.5 to 10%,

WO 3 : 3 to 15%,

La 2 O 3 : 10 to 25%,

Gd 2 O 3 : 0 to less than 5%, and

Y 2 O 3 : 0.1 to 15%,

provided that La 2 O 3 +Gd 2 O 3 +Y 2 O 3 is 15 to 30%,

wherein the optical glass does not substantially comprise Nb 2 O 5 , and has a refractive index (n d ) of 1.82 to 1.86 and an Abbe's number (ν d ) of 37 to 44 and a glass transition point (T g ) of 630° C. or lower.

Assignments (2)
CORPORATE ADDRESS CHANGE Recorded Nov 9, 2011
From: ASAHI GLASS COMPANY, LIMITED
To: ASAHI GLASS COMPANY, LIMITED
Reel/Frame 027197/0541 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 1, 2010
From: TOMENO, SATORU; KONDO, YUKI
To: ASAHI GLASS COMPANY, LIMITED
Reel/Frame 024464/0918 →