Polyimide powder for antistatic polyimide molded product and polyimide molded product thereby
View Patent ↗A polyimide powder for an antistatic polyimide molded product is disclosed. The polyimide powder comprises a polyimide-powder prepared from an aromatic tetracarboxylic acid component and a diamine component, and a conductive carbon black having a DBP oil absorption of 300 ml/100 g or more; wherein the amount of the conductive carbon black is within a range of 0.75 wt % to 5 wt % relative to the polyimide-powder. A polyimide molded product with sufficient antistatic property can be formed by molding the above polyimide powder.
1. A product molded from a composition comprising a polyimide-powder which is prepared from an aromatic tetracarboxylic acid component and a diamine component, and a conductive carbon black having a DBP oil absorption of 300 ml/100 g or more; wherein the polyimide-powder is mixed with the conductive carbon black, the amount of the conductive carbon black is within a range of 0.75 wt % to 5 wt % relative to the polyimide-powder and wherein the molded product has a surface resistivity of 10 4 Ω/□ to 10 7 Ω/□.
2. A molded product according to claim 1 , wherein the amount of the conductive carbon black is within a range of 1 wt % to 3 wt % relative to the polyimide-powder.
3. A molded product according to claim 1 , wherein the aromatic tetracarboxylic acid component comprises 3,3′,4,4′-biphenyltetracarboxylic dianhydride.
4. A molded product according to claim 1 , wherein the aromatic tetracarboxylic acid component comprises 3,3′,4,4′-biphenyltetracarboxylic dianhydride and 2,3,3′,4′-biphenyltetracarboxylic dianhydride.
5. A molded product according to claim 1 , wherein the aromatic tetracarboxylic acid component comprises 3,3′,4,4′-biphenyltetracarboxylic dianhydride and not less than 0.5 mol % but less than 30 mol % of 2,3,3′,4′-biphenyltetracarboxylic dianhydride, and the aromatic diamine component comprises at least 80 mol % of p-phenylenediamine.
6. A molded product according to claim 1 , wherein the aromatic diamine component comprises p-phenylenediamine or 4,4′-diaminodiphenylether.
7. A molded product according to claim 1 , wherein the molded product is formed by
filling a mold with the composition; and
applying pressure and heat to the composition in the mold at the same time or different times.
8. A molded product according to claim 7 , wherein the composition in the mold is pressed at a temperature of 350° C. to 600° C. and a pressure of 30 MPa to 2,000 MPa for molding.
9. A molded product according to claim 7 , wherein the composition in the mold is pressed at a temperature of room temperature to 350° C. and a pressure of 30 MPa to 2,000 MPa, and then sintered at a temperature of 350° C. to 600° C. without compression for molding.