Rocks and aggregate, and methods of making and using the same
Compositions comprising synthetic rock, e.g., aggregate, and methods of producing and using them are provided. The rock, e.g., aggregate, contains CO 2 and/or other components of an industrial waste stream. The CO 2 may be in the form of divalent cation carbonates, e.g., magnesium and calcium carbonates. Aspects of the invention include contacting a CO 2 containing gaseous stream with a water to dissolve CO 2 , and placing the water under precipitation conditions sufficient to produce a carbonate containing precipitate product, e.g., a divalent cation carbonate.
1. A method of sequestering CO 2 comprising:
(i) precipitating a CO 2 -sequestering carbonate compound composition from a divalent cation-containing water that has contacted or is contacting a CO 2 source comprising at least one of:
an industrial waste stream;
a flue gas from a power plant;
a flue gas from a cement plant;
CO 2 from the combustion of a fossil fuel; or
CO 2 dissolved in a liquid
to form a precipitate; and
(ii) producing aggregate comprising 80% or more by weight of the CO 2 -sequestering carbonate compound composition wherein the aggregate has a hardness of at least 3 on the Mohs hardness scale and wherein the aggregate is suitable for use in a building material.
2. The method of claim 1 wherein producing the aggregate comprises subjecting the precipitate of claim 1 to elevated temperature, elevated pressure, or a combination thereof.
3. The method of claim 1 , wherein the divalent cation-containing water has contacted or is contacting CO 2 from an industrial waste gas stream.
4. The method of claim 1 wherein the divalent cation-containing has contacted or is contacting with CO 2 from the combustion of a fossil fuel.
5. The method of claim 1 wherein the divalent cation-containing has contacted or is contacting a flue gas from a power plant or a cement plant.
6. The method of claim 1 wherein the divalent cations of the divalent cation-containing water come at least partially from a saltwater.
7. The method of claim 6 wherein the saltwater comprises seawater or brine.
8. The method of claim 1 wherein the producing of the aggregate comprises producing aggregate of a predetermined size and shape.
9. The method of claim 1 ,
wherein the divalent cation-containing water has contacted or is contacting a CO 2 source comprising CO 2 dissolved in a liquid.
10. The method of claim 1 wherein the precipitating comprises subjecting the divalent cation-containing water to carbonate and/or bicarbonate compound precipitation conditions.
11. The method of claim 1 wherein the precipitating comprises adjusting the magnesium to calcium ratio (Mg:Ca) of the divalent cation-containing water to be between 10/1 to 1/10.
12. The method of claim 1 , further comprising adding siliceous materials during the precipitating.
13. The method of claim 12 , wherein the siliceous materials comprise diatomaceous earth, fly ash, silica fume and metal silicates.
14. The method of claim 1 , wherein the processing conditions comprise:
a) separation of the precipitate from the water; and
b) producing a set product, wherein the aggregate comprises the set product.
15. The method of claim 14 , wherein the processing conditions further comprise adding fresh water with or without drying the precipitate first to produce the set product.
16. The method of claim 15 , wherein the processing conditions further comprise washing the precipitate.
17. The method of any of claims 14 to 16 , wherein the processing conditions further comprise mechanical processing of the set product.
18. The method of claim 1 , wherein producing the aggregate comprises subjecting the precipitate to exposure to the open environment and mechanically processing.
19. The method of claim 1 , wherein the temperature of the water is maintained between 5 to 70° C. during precipitation.
20. The method of claim 1 , wherein the carbonate compound composition forms a settable composition upon combination with water and wherein producing the aggregate comprises:
a) generating a settable composition consisting essentially of the CO 2 -sequestering carbonate compound composition and water;
b) allowing the settable composition to form a solid product having a hardness of at least 3 on the Mohs hardness scale; and
c) forming the aggregate from the solid product.