Treatment additives, methods for making and methods for clarifying aqueous media
View Patent ↗A coagulant composition includes chitosan, methacryloyloxyethyltrimethyl ammonium methyl sulfate and a redox initiator. A coagulant, method for making the coagulant and clarifying wastewater is also provided.
1. A method for making a coagulant comprising polymerizing 2-methacryloyloxyethyltrimethyl ammonium methyl sulfate and chitosan in the presence of redox initiators, said redox initiators comprising an oxidizing agent and a reductant therein, and wherein said oxidizing agent is t-butyl hydroperoxide.
2. The method according to claim 1 wherein chitosan is present from about 5 percent by weight to about 30 percent by weight, based on the weight of the reactants.
3. The method according to claim 1 wherein 2-Methacryloyloxyethyltrimethyl ammonium methyl sulfate is present from about 25 percent by weight to about 75 percent by weight, based on the weight of the reactants.
4. The method according to claim 1 wherein the redox initiator is present from about 1 percent by weight to about 10 percent by weight based on the weight of the reactants.
5. The method according to claim 1 wherein the oxidizing agent is present from about 0.5 percent by weight to about 5 percent by weight, based on the weight of the reactants and the reductant is present from about 0.5 percent by weight to about 5 percent by weight, based on the weight of the reactants.
6. The method according to claim 1 wherein the reductant is selected from the group consisting of sodium metabisulfite, sodium hydrosulfate and sodium thiosulfate.
7. The method of claim 1 , wherein polymerization is in the presence of an acid.
8. The method of claim 7 , wherein the acid is selected from the group consisting of citric acid, acetic acid, methanesulfonic acid and sulfamic acid.
9. The method of claim 7 , wherein the acid is present from about 10 percent by weight to about 50 percent by weight based on the weight of the composition.
10. The method of claim 1 , wherein the polymerization is at an elevated temperature.
11. The method of claim 10 , wherein the polymerization is at a temperature from about 40° C. to about 90° C.