A golf ball which has excellent abrasion-resistance and spin performance is provided. The golf ball of the present invention includes a core and a cover covering the core and containing polyurethane as a resin component, wherein the polyurethane has, as a constituting component, a polyisocyanate component, a high-molecular weight polyol component, and a mixture of cis-1,4-cyclohexane dimethanol and trans-1,4-cyclohexane dimethanol as a chain extender.
1. A golf ball comprising:
a core; and
a cover covering the core and containing polyurethane as a resin component, wherein the polyurethane has a straight chain structure and has, as a constituting component, a polyisocyanate component, a high-molecular weight polyol component, and a mixture of cis-1,4-cyclohexane dimethanol and trans-1,4-cyclohexane dimethanol as a chain extender, and wherein said cover has a shore D hardness ranging from 20 to 48.
2. The golf ball according to claim 1 , wherein a mixing ratio of cis-1,4-cyclohexane dimethanol to trans-1,4-cyclohexane dimethanol falls within a range from 10/90 to 70/30 in a mass ratio.
3. The golf ball according to claim 1 , wherein a mixing ratio of cis-1,4-cyclohexane dimethanol to trans-1,4-cyclohexane dimethanol falls within a range from 30/70 to 40/60 in a mass ratio.
4. The golf ball according to claim 1 , wherein the polyurethane contains diphenylmethane diisocyanate as the polyisocyanate component.
5. The golf ball according to claim 1 , wherein the polyurethane contains polyoxytetramethyleneglycol as the high-molecular weight polyol component.
6. The golf ball according to claim 1 , wherein the cover has a thickness ranging from 0.3 mm to 2.5 mm.
7. The golf ball according to claim 1 , wherein the core is a multi-layered core having a center and at least one intermediate layer covering the center.
8. The golf ball according to claim 7 , wherein the intermediate layer has a hardness ranging from 50 to 75 in Shore D hardness.
9. The golf ball according to claim 7 , wherein the intermediate layer has a thickness ranging from 0.3 mm to 6.0 mm.
10. The golf ball according to claim 1 , wherein the core has a hardness difference between a surface hardness and a center hardness ranging from 10 to 40 in JIS-C hardness.
11. The golf ball according to claim 1 , wherein the high-molecular weight polyol has a number average molecular weight of more than 400 and 10,000 or less.
12. The golf ball according to claim 1 , wherein the high-molecular weight polyol has a hydroxyl value of 500 mgKOH/g or less.
13. The golf ball according to claim 1 , wherein the polyurethane has a hardness ranging from 15 to 50 in Shore D hardness.
14. The golf ball according to claim 1 , wherein the polyurethane is obtained by a reaction of the polyisocyanate component, the high-molecular weight polyol and the chain extender in a molar ratio (NCO/OH) of an isocyanate group (NCO) contained in the polyisocyanate component to a hydroxyl group (OH) contained in the high-molecular weight polyol component ranging from 1 to 10.
15. The golf ball according to claim 1 , wherein the polyurethane is obtained by a reaction of the polyisocyanate component, the high-molecular weight polyol and the chain extender in a molar ratio (NCO/OH) of an isocyanate group (NCO) contained in an isocyanate group terminated urethane prepolymer to a hydroxyl group (OH) contained in the chain extender ranging from 0.9 to 1.1.
16. A golf ball comprising:
a core; and
a cover covering the core and containing polyurethane as a resin component, wherein the polyurethane has a straight chain structure and has, as a constituting component, a polyisocyanate component, a high-molecular weight polyol component, and a mixture of cis-1,4-cyclohexane dimethanol and trans-1,4-cyclohexane dimethanol as a chain extender,
wherein a mass ratio of cis-1,4-cyclohexane dimethanol to trans-1,4-cyclohexane dimethanol in said cover falls within a range from 10/90 to 70/30, and
wherein said cover has a shore D hardness ranging from 20 to 48.
17. The golf ball according to claim 16 , wherein the polyurethane contains diphenylmethane diisocyanate as the polyisocyanate component and polyoxytetramethyleneglycol as the high-molecular weight polyol component, and the polyurethane has a hardness ranging from 15 to 50 in Shore D hardness.
18. The golf ball according to claim 17 , wherein the core is a multi-layered core having a center and at least one intermediate layer covering the center, and said intermediate layer has a thickness ranging from 0.3 mm to 6.0 mm and a Shore D hardness ranging from 50 to 75.
19. The golf ball according to claim 18 , wherein a mixing ratio of cis-1,4-cyclohexane dimethanol to trans-1,4-cyclohexane dimethanol falls within a range from 30/70 to 40/60 in a mass ratio.
20. The golf ball according to claim 18 , wherein a mixing ratio of cis-1,4-cyclohexane dimethanol to trans-1,4-cyclohexane dimethanol falls within a range from 40/60 to 70/30 in a mass ratio.
21. The golf ball according to claim 1 , wherein a mixing ratio of cis-1,4-cyclohexane dimethanol to trans-1,4-cyclohexane dimethanol falls within a range from 40/60 to 70/30 in a mass ratio.