Highly dispersed metal catalyst
View Patent ↗A supported catalyst having an atomic level single atom structure is provided such that substantially all the catalyst is available for catalytic function. A process of forming a single atom catalyst unto a porous catalyst support is also provided.
1. A catalyst consisting of platinum, a promoter metal selected from a group consisting of tin and cobalt, and with the platinum and promoter metal carried by an activated carbon catalyst support; and
the platinum, promoter metal and catalyst support being formed using aqueous solvents so that the catalytic activity of the catalyst increases over multiple cycles with the platinum being present at a loading level of between 1.1 and 1.5% by weight and the catalyst having a dispersion value of greater than 100% using a hydrogen-oxygen titration dispersion calculation based on the ratio of the number of moles of adsorptive chemisorbed to the number of moles of platinum in the catalyst.
2. A catalyst formed using aqueous solvents consisting essentially of a combination of platinum in the presence of a tin promoter, the platinum and tin being supported on an activated carbon support and in which the platinum is present at between 1.1 to 1.5% weight loading and a dispersion value greater than 100% using a hydrogen-oxygen titration dispersion calculation based on the ratio of the number of moles of adsorptive chemisorbed to the number of moles of platinum in the catalyst.
3. The catalyst according to claim 1 wherein the platinum forms an atomic structure on the support such that every atom of the platinum is capable of interaction during catalytic activity.
4. The catalyst according to claim 1 wherein the platinum is present in an amount that is equivalent to an amount of the promoter present.
5. The catalyst according to claim 4 wherein the platinum is present in an amount that is equivalent to an amount of the tin present.
6. The catalyst according to claim 4 wherein the platinum is present in an amount that is equivalent to an amount of the cobalt present.
7. The catalyst according to claim 2 wherein the platinum forms an atomic structure on the support such that every atom of the platinum is capable of interaction during catalytic activity.
8. The catalyst according to claim 2 wherein the platinum is present in an amount that is equivalent to an amount of the tin present.