Thin gauge steel sheet excellent in surface conditions, formability, and workability and method for producing the same
View Patent ↗The present invention provides ultralow carbon thin gauge steel sheet and a method for producing the same where coalescence and growth of inclusions in the molten steel are prevented and the inclusions are finely dispersed in the steel sheet, whereby surface defects and cracks at the time of press forming are prevented, growth of recrystallized grains at the time of continuous annealing is promoted, and a high r value (r value≧2.0) and elongation (total elongation≧50%) are exhibited, that is, ultralow carbon thin gauge steel sheet excellent in surface conditions, formability, and workability comprised of, by mass %, 0.00030.003%≦C≦0.003%, Si≦0.01%, Mn≦0.1%, P≦0.02%, S≦0.01%, 0.0005%≦N≦0.0025%, 0.01%≦acid soluble Ti≦0.07%, acid soluble Al≦0.003%, and 0.002%≦La+Ce+Nd≦0.02% and a balance of iron and unavoidable impurities, said steel sheet characterized by containing at least cerium oxysulfite, lanthanum oxysulfite, and neodymium oxysulfite.
1. A method for producing an ultralow carbon thin gauge steel sheet excellent in surface conditions, formability, and workability, the method comprising the steps of:
casting a molten steel consisting of, by mass %,
0.0003%≦C≦0.003%,
Si≦0.01%,
Mn≦0.1%,
P≦0.02%,
0.005%≦S≦0.01%,
0.0005%≦N≦0.0025%,
0.01%≦acid soluble Ti≦0.07%,
acid soluble Al≦0.003%, and
0.002%≦La+Ce+Nd≦0.02%, and
a balance of iron and unavoidable impurities,
heating a cast slab obtained from the casting step,
hot rolling and coiling the slab to obtain a hot rolled steel strip,
cold rolling the steel strip at a cold rolling rate of 70% or more and then continuously annealing the cold-rolled steel strip at a recrystallization annealing temperature of 600 to 780° C.,
wherein the cold-rolled and annealed steel sheet has an r-value of 2.0 or more, and
wherein the step of casting a molten steel comprises the successive steps of:
(a) adding Al to perform preliminary deoxidation of the molten steel;
(b) adding Ti to deoxidize the molten steel; and
(c) adding one or more of La, Ce, and Nd to form complex oxides of La oxides, Ce oxides, and Nd oxides with Ti oxides, and one or more of cerium oxysulfite, lanthanum oxysulfite, and neodymium oxysulfite to fix the solute S in the molten steel, and
(d) continuously casting.
2. A method for producing an ultralow carbon thin gauge steel sheet excellent in surface conditions, formability, and workability, the method comprising the steps of:
casting a molten steel consisting of, by mass %,
0.0003%≦C≦0.003%,
Si≦0.01%,
Mn≦0.1%,
P≦0.02%
0.005%≦S≦0.01%,
0.0005%≦N≦0.0025%,
0.01%≦acid soluble Ti≦0.07%,
acid soluble Al≦0.003%,
0.002%≦La+Ce+Nd≦0.02%, and
0.0004%≦Nb≦0.05% and
a balance of iron and unavoidable impurities,
heating a cast slab obtained from the casting step,
hot rolling and coiling the slab to obtain a hot rolled steel strip,
cold rolling the steel strip at a cold rolling rate of 70% or more and then continuously annealing the cold-rolled steel strip at a recrystallization annealing temperature of 600 to 780° C.,
wherein the cold-rolled and annealed steel sheet has an r-value of 2.0 or more, and
wherein the step of casting a molten steel comprises the successive steps of:
(a) adding Al to 5 form preliminary deoxidation of the molten steel;
(b) adding Ti to deoxidize the molten steel; and
(c) adding one or more of La, Ce, and Nd to form complex oxides of La oxides, Ce oxides, and Nd oxides with Ti oxides, and one or more of cerium oxysulfite, lanthanum oxysulfite, and neodymium oxysulfite to fix the solute S in the molten steel, and
(d) continuously casting.
3. A method for producing an ultralow carbon thin gauge steel sheet excellent in surface conditions, formability, and workability, the method comprising the steps of:
casting a molten steel consisting of, by mass %,
0.0003%≦C≦0.003%,
Si≦0.01%,
Mn≦0.1%,
P≦0.02%,
0.005%≦S≦0.01%,
0.0005%≦N≦0.0025%,
0.0004%≦B≦0.005%,
0.01%≦acid soluble Ti≦0.07%,
acid soluble Al≦0.003%, and
0.002%≦La+Ce+Nd≦0.02%, and
a balance of iron and unavoidable impurities,
heating a cast slab obtained from the casting step,
hot rolling and coiling the slab to obtain a hot rolled steel strip,
cold rolling the steel strip at a cold rolling rate of 70% or more and then continuously annealing the cold-rolled steel strip at a recrystallization annealing temperature of 600 to 780° C.,
wherein the cold-rolled and annealed steel sheet has an r-value of 2.0 or more, and
wherein the step of casting a molten steel comprises the successive steps of:
(a) adding Al to perform preliminary deoxidation of the molten steel;
(b) adding Ti to deoxidize the molten steel; and
(c) adding one or more of La, Ce, and Nd to form complex oxides of La oxides, Ce oxides, and Nd oxides with Ti oxides, and one or more of cerium oxysulfite, lanthanum oxysulfite, and neodymium oxysulfite to fix the solute S in the molten steel, and
(d) continuously casting.
4. A method for producing an ultralow carbon thin gauge steel sheet excellent in surface conditions, formability, and workability the method comprising the steps of:
casting a molten steel consisting of, by mass %,
0.0003%≦C≦0.003%,
Si≦0.01%,
Mn≦0.1%,
P≦0.02%
0.005%≦S≦0.01%,
0.0005%≦N≦0.0025%,
0.0004%≦B≦0.005%,
0.01%≦acid soluble Ti≦0.07%,
acid soluble Al≦0.003%,
0.002%≦La+Ce+Nd≦0.02%, and
0.0004%≦Nb≦0.05%, and
a balance of iron and unavoidable impurities,
heating a cast slab obtained from the casting step,
hot rolling and coiling the slab to obtain a hot rolled steel strip,
cold rolling the steel strip at a cold rolling rate of 70% or more and then continuously annealing the cold-rolled steel strip at a recrystallization annealing temperature of 600 to 780° C.,
wherein the cold-rolled and annealed steel sheet has an r-value of 2.0 or more, and
wherein the step of casting a molten steel comprises the successive steps of:
(a) adding Al to perform preliminary deoxidation of the molten steel;
(b) adding Ti to deoxidize the molten steel; and
(c) adding one or more of La, Ce, and Nd to form complex oxides of La oxides, Ce oxides, and Nd oxides with Ti oxides, and one or more of cerium oxysulfite, lanthanum oxysulfite, and neodymium oxysulfite to fix the solute S in the molten steel, and
(d) continuously casting.