IP Library Granted Patent US 8,426,478
Granted Patent B2
US 8,426,478 · App. 12/808,618 · Granted Apr 23, 2013

Defoamer formulation

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Quick Facts
Patent No.
US 8,426,478
App. No.
12/808,618
Granted
Apr 23, 2013
Kind
B2
Abstract

Formulation comprising hydrophobicized particles of silicon dioxide, mineral oil and one or more emulsifiers, where the hydrophobicized silicon dioxide is a fumed silicon dioxide, possesses a BET surface area of 200 to 300 m 2 /g, has on the surface of the particles O—Si—(C n H 2n+1 ) 3 groups, where n is 1 to 3 and where the (C n H 2n+1 ) units are alike or different, has a carbon content of 1.5% to 5% by weight, based on the hydrophobic silicon dioxide, and is present in the formulation with a fraction of 0.05% to 5% by weight.

Claims (23)

1. A formulation consisting of hydrophobicized particles of silicon dioxide, mineral oil and one or more emulsifiers,

wherein

the hydrophobicized particles of silicon dioxide

are fumed,

possesses a BET surface area of 200 to 300 m 2 /g,

have on the surface of the particles O—Si—(C n H 2n+1 ) 3 groups, where n is 1 to 3 and where the (C n H 2n+1 ) units are alike or different,

have a carbon content of 1.5% to 5% by weight, based on the hydrophobicized particles of silicon dioxide, and

are present in the formulation in an amount of from 0.05% to 5% by weight, based on the total weight of the formulation,

wherein the formulation comprises:

40% to 90% by weight, based on the total weight of the formulation, of the mineral oil, and

2% to 25% by weight, based on the total weight of the formulation, of the emulsifier.

2. The formulation according to claim 1 , wherein n is 1.

3. The formulation according to claim 1 , wherein the BET surface area is 230 to 290 m 2 /g.

4. The formulation according to claim 1 , wherein the carbon content is 2% to 5%, based on the hydrophobicized particles of silicon dioxide.

5. The formulation according to claim 1 , wherein the fraction of hydrophobicized silicon dioxide is 0.1% to 1% by weight, based on the formulation.

6. The formulation according to claim 1 , wherein the BET surface area is 250 to 270 m 2 /g.

7. The formulation according to claim 1 , wherein the carbon content is 2% to 3% by weight, based on the hydrophobicized particles of silicon dioxide.

8. The formulation according to claim 1 , which contains 0.1% to 0.5% by weight of the hydrophobicized particles of silicon dioxide, based on the total weight of the formulation.

9. The formulation according to claim 1 , wherein the (C n H 2n+1 ) units are alike.

10. The formulation according to claim 1 , wherein the (C n H 2n+1 ) units are different.

11. The formulation according to claim 1 , wherein the carbon content is 2% to 3% by weight, based on the hydrophobicized particles of silicon dioxide.

12. A composition comprising the formulation according to claim 1 and at least one acrylic ester.

13. A method of defoaming aqueous systems comprising adding the formulation according to claim 1 to an aqueous polymeric system comprising an acrylic ester.

Assignments (2)
CHANGE OF NAME Recorded Jan 31, 2020
From: EVONIK DEGUSSA GMBH
To: EVONIK OPERATIONS GMBH
Reel/Frame 051765/0166 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 24, 2010
From: DABROWSKI, LARA; MENZEL, FRANK; WOLLENWEBER, HORST-WERNER
To: EVONIK DEGUSSA GMBH
Reel/Frame 024586/0586 →