Pneumatic tire
View Patent ↗A tread rubber is made of a rubber composition containing 100 pbw of a diene rubber, 30 to 100 pbw of a reinforcing filler including at least 10 pbw of silica, and 1 to 20 pbw of microcapsules each encapsulating a heat-expandable substance. A sulfur-containing silane coupling agent is mixed in the rubber composition in an amount of 3 to 15 wt. % based on the weight of the silica. A shell material of each microcapsule is made of a thermoplastic resin which essentially contains a nitrile monomer. A vapor pressure of the heat-expandable substance is 1.4 to 3.0 MPa at 150° C. An average diameter of the microcapsules is 20 to 30 μm before vulcanization of the rubber composition. An average diameter of the microcapsules expanded due to the vulcanization is 40 to 80 μm. The tread rubber has a proportion of a cell-occupying area of 5 to 30%.
1. A pneumatic tire comprising:
tread rubber made from a rubber composition containing 100 parts by weight of a diene rubber, 30 to 100 parts by weight of a reinforcing filler including at least 10 parts by weight of silica, and 1 to 20 parts by weight of microcapsules each encapsulating a heat-expandable substance,
the rubber composition containing a sulfur-containing silane coupling agent in an amount of 3 to 15 wt. % based on the weight of the silica;
each microcapsule comprising a shell material made of a thermoplastic resin obtained by polymerizing together a nitrile monomer (I) in a major proportion and a monomer (II) having an unsaturated double bond and a carboxyl group in its molecule;
the heat-expandable substance having a vapor pressure of 1.4 to 3.0 MPa at 150° C.;
the microcapsules having an average particle diameter of 20 to 30 μm before vulcanization of the rubber composition;
the microcapsules as expanded due to the vulcanization having an average particle diameter of 40 to 80 μm; and
the tread rubber having a proportion of a cell-occupying area of 5 to 30%.
2. The pneumatic tire according to claim 1 , wherein
the shell material of each microcapsule is made of the thermoplastic resin which further contains, as a monomer, a monomer (III) having at least two polymerizable double bonds and/or a copolymerizable monomer (IV).
3. The pneumatic tire according to claim 1 , wherein
the nitrile monomer (I) is at least one selected from acrylonitrile, methacrylonitrile, α-chloroacrylonitrile, α-ethoxy acrylonitrile and fumaronitrile.
4. The pneumatic tire according to claim 1 , wherein
the monomer (II) having an unsaturated double bond and a carboxyl group in its molecule is at least one selected from an acrylic acid, a methacrylic acid, an itaconic acid, a maleic acid, a fumaric acid and a citraconic acid.
5. The pneumatic tire according to claim 2 , wherein
the monomer (III) having at least two polymerizable double bonds is at least one selected from divinylbenzene, divinylnaphthalene, allyl methacrylate, triacrylformal, triallyl isocyanate, ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, 1,4-butanediol di(meth)acrylate, 1,9-nonanediol di(meth)acrylate, polyethylene glycol (PEG#200) di(meth)acrylate with a weight average molecular weight of 200, polyethylene glycol (PEG#400) di(meth)acrylate with a weight average molecular weight of 400, 1,6-hexanediol (meth)acrylate, and trimethylolpropane trimethacrylate.
6. The pneumatic tire according to claim 2 , wherein
the copolymerizable monomer (IV) is at least one selected from: vinylidene chloride; vinyl acetate; (meth)acrylate esters including methyl (meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate and t-butyl (meth)acrylate; styrene; styrene sulfonate; α-methyl styrene; chlorostyrene; acrylamide; a substituted acrylamide; methacrylamide; and a substituted methacrylamide.
7. The pneumatic tire according to claim 1 , wherein
the heat-expandable substance is at least one selected from the group consisting of isoalkanes and normal alkanes.
8. The pneumatic tire according to claim 1 , wherein
the sulfur-containing silane coupling agent is at least one selected from bis-(3-triethoxysilylpropyl)tetrasulfide, bis(3-triethoxysilylpropyl)disulfide, and 3-trimethoxysilylpropyl benzothiazole tetrasulfide.