IP Library Granted Patent US 8,728,969
Granted Patent B2
US 8,728,969 · App. 12/811,216 · Granted May 20, 2014

Process for obtaining a catalyst composite

Inventors: Nikolai Nesterenko (Nivelles, BE); Walter Vermeiren (Houthalen, BE); Sander Van Donk (Sainte-Adresse, FR)
Assignee: Total Research & Technology Feluy
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Quick Facts
Patent No.
US 8,728,969
App. No.
12/811,216
Granted
May 20, 2014
Kind
B2
Abstract

A process for obtaining a catalyst composite comprising the following steps: a). selecting a molecular sieve having pores of 10-or more-membered rings b). contacting the molecular sieve with a metal silicate different from said molecular sieve comprising at least one alkaline earth metal and one or more of the following metals: Ga, Al, Ce, In, Cs, Sc, Sn, Li, Zn, Co, Mo, Mn, Ni, Fe, Cu, Cr, Ti and V, such that the composite comprises at least 0.1 wt % of silicate.

Claims (14)

1. A catalyst composite comprising:

at least 10 wt % of a molecular sieve comprising pores of 10-or more-membered rings, wherein the molecular sieve is a ZSM-5 zeolite; and

at least one metal silicate, different from the molecular sieve, wherein the metal silicate is xonotlite (Ca 6 Si 6 O 17 (OH) 2 ); and

wherein the catalyst composite comprises at least 0.1 wt % of silicate based on the total weight of the catalyst composite.

2. The catalyst composite of claim 1 , wherein the metal silicate is present in the catalyst composite in an amount of up to 10 wt %.

3. A catalyst composite comprising:

at least 10 wt % of a molecular sieve comprising pores of 10-or more-membered rings, wherein the molecular sieve is a zeolite; and

at least one metal silicate, different from the molecular sieve, wherein the metal silicate is xonotlite (Ca 6 Si 6 O 17 (OH) 2 ); and

wherein the catalyst composite comprises at least 0.1 wt % of silicate based on the total weight of the catalyst composite.

4. The catalyst composite of claim 3 , wherein the molecular sieve is selected from the group consisting of MFI, MOR, MEL, clinoptilolite, FER, FAU, MWW, BETA, ZSM-21, ZSM-22, ZSM-23, ZSM-42, ZSM-57, and LTL, and combinations thereof.

5. The catalyst composite of claim 3 , wherein the molecular sieve is selected from the group consisting of MFI, MOR, MEL, clinoptilolite and FER and combinations thereof, wherein the molecular sieve is synthesized without direct addition of template.

6. The catalyst composite of claim 3 , wherein the molecular sieve is a P-modified zeolite.

7. The catalyst composite according to claim 6 , wherein the zeolite is modified with P by undergoing a steam treatment step, whereby the zeolite is dealuminated, followed by a leaching step using an acid solution comprising a source of P.

8. The catalyst composite of claim 3 , wherein the metal silicate is present in the catalyst composite in an amount of up to 10 wt %.

Assignments (3)
CHANGE OF NAME Recorded Mar 28, 2014
From: TOTAL PETROCHEMICALS RESEARCH FELUY
To: TOTAL RESEARCH & TECHNOLOGY FELUY
Reel/Frame 032553/0832 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 2, 2012
From: NESTERENKO, NIKOLAI; VERMEIREN, WALTER; VAN DONK, SANDER
To: TOTAL PETROCHEMICALS RESEARCH FELUY
Reel/Frame 029059/0437 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 8, 2012
From: NESTERENKO, NIKOLAI; VERMEIREN, WALTER; VAN DONK, SANDER; MINOUX, DELPHINE
To: TOTAL PETROCHEMICALS RESEARCH FELUY
Reel/Frame 028343/0675 →
Priority Claims (1)
EP 08150685 · Jan 25, 2008 · regional
Continuity (1)
Related Publication 20110118518A1 · May 19, 2011