IP Library Granted Patent US 8,197,605
Granted Patent B2
US 8,197,605 · App. 12/811,433 · Granted Jun 12, 2012

Use of alkanesulfonic acid as agent for cleaning cement, mortar and concrete

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Quick Facts
Patent No.
US 8,197,605
App. No.
12/811,433
Granted
Jun 12, 2012
Kind
B2
Abstract

The present invention relates to the use of at least one alkanesulfonic acid of formula R—SO 3 H, in which R represents a saturated, linear or branched, hydrocarbon chain containing 1 to 4 carbon atoms, as agent for cleaning cement, mortar, concrete, lime, laitance and other derived products. The invention also relates to a method of cleaning cement, mortar, concrete, lime, laitance and other derived products using at least one alkanesulfonic acid.

Claims (39)

1. A method for cleaning cement, mortar, concrete, calcium oxide, calcium hydroxide, or a laitance thereof from a surface which comprises

contacting at least one alkanesulfonic acid of formula R—SO 3 H, where R represents a saturated and linear or branched hydrocarbon chain comprising from 1 to 4 carbon atoms with the cement, mortar, concrete, the calcium oxide, the calcium hydroxide, or the laitance and then

removing the cement, mortar, concrete, the calcium oxide, the calcium hydroxide, or the laitance from the surface.

2. The method of claim 1 , wherein the at least one alkanesulfonic acid is methanesulfonic acid, ethanesulfonic acid, n-propanesulfonic acid, isopropanesulfonic acid, n-butanesulfonic acid, isobutanesulfonic acid, sec-butanesulfonic acid, tert-butanesulfonic acid, or a mixture of two or more of them in all proportions.

3. The method of claim 1 , wherein the at least one alkanesulfonic acid is methanesulfonic acid or ethanesulfonic acid.

4. The method of claim 1 , wherein the at least one alkanesulfonic acid is used in a formulation form a concentration of the at least one alkanesulfonic acid being between 0.01% and 100% weight by weight.

5. The method of claim 1 , wherein the at least one alkanesulfonic acid is present in a formulation selected from the group consisting of an aqueous formulation, an organic formulation, or an aqueous/organic formulation.

6. The method of claim 1 , wherein the at least one alkanesulfonic acid is used in combination with one or more additives selected from the group consisting of:

hydrotropic or solubilizing or gelling agents or solvents,

biocides or disinfectants,

rheological or texturizing or thickening agents,

organic or inorganic acids,

flame retardants,

preservatives,

surfactants of anionic, cationic, nonionic or amphoteric type, emulsifiers, detergents, soaps and others,

foaming or antifoaming agents,

antifreezes;

colorants, and

fragrances or odorous agents.

7. The method of claim 1 , wherein the at least one alkanesulfonic acid is used in the form of a liquid, gel or foaming gel formulation.

8. The method of claim 1 , wherein the surface is a metal surface or a surface made of concrete, cement, tiling, tiles, stone, porcelain, wood, paper, board, textiles, polymers, or glass.

9. The method of claim 1 , wherein the at least one alkanesulfonic acid is methanesulfonic acid.

10. The method of claim 1 , wherein the surface is a plastic surface, a varnished surface, a painted surface, or a lacquered surface.

11. The method of claim 4 , wherein the concentration of the at least one alkanesulfonic acid is between 0.05% and 90% by weight with respect to the total weight of said formulation.

12. The method of claim 4 , wherein the concentration of the at least one alkanesulfonic acid is between 0.5% and 75% by weight with respect to the total weight of said formulation.

13. The method of claim 5 , wherein the formulation is concentrated, ready for use, or to be diluted before use.

14. The method of claim 6 , wherein

the hydrotropic or solubilizing or gelling agents or solvents are selected from the group consisting of alcohols, esters, ketones, and amides.

15. The method of claim 6 , wherein

the biocides or disinfectants are selected from the group consisting of bromoacetic acid, peracetic acid, and aqueous hydrogen peroxide solution.

16. The method of claim 6 , wherein

the rheological or texturizing or thickening agents are selected from the group consisting of sugars, polysaccharides, alginates, silica, amorphous silica, and gums.

17. The method of claim 6 , wherein

the organic or inorganic acids are selected from the group consisting of sulfuric acid, phosphoric acid, nitric acid, sulfamic acid, acetic acid, citric acid, formic acid, lactic acid, glycolic acid, and oxalic acid.

18. The method of claim 6 , wherein

the surfactants of anionic, cationic, nonionic or amphoteric type are selected from the group consisting of ethoxylated alcohols, amines, alkylsulfonates, and arylsulfonates.

19. The method of claim 6 , wherein

the antifreezes are selected from the group consisting of ethylene glycol and propylene glycol.

20. The method of claim 8 , wherein the metal surface is made of iron, steel, copper, or an alloy.

Assignments (2)
CHANGE OF ADDRESS Recorded Jul 4, 2025
From: ARKEMA FRANCE
To: ARKEMA FRANCE
Reel/Frame 071814/0739 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 30, 2010
From: LAFFITTE, JEAN-ALEX; MONGUILLON, BERNARD
To: ARKEMA FRANCE
Reel/Frame 024903/0397 →