Light scattering by controlled porosity in optical ceramics for LEDs
View Patent ↗The present invention relates to a light emitting device ( 100 ) comprising at least one light emitting diode ( 101 ) and at least one porous ceramic element ( 102 ), which ceramic element ( 102 ) is arranged to receive light from the light emitting diode(s) ( 101 ). The present invention also relates to methods for the manufacture of the light emitting device ( 100 ) and of the porous ceramic element ( 102 ).
1. A method for the manufacture of a light emitting device comprising:
providing a slurry comprising ceramic particles of at least one wavelength converting material and polymeric particles having a diameter of from 2 μm to 10 μm;
forming a ceramic body from said slurry;
removing said polymeric particles from said ceramic body to provide a porous ceramic element having an average pore diameter of from 2 μm to 10 μm; and
arranging said porous ceramic element to receive light from at least one light emitting diode.
2. A method according to claim 1 , wherein said ceramic particles have an average particle size of from 5 μm to 10 μm.
3. A method according to claim 1 , wherein said polymeric particles have an average diameter of from 2 μm to 5 μm.
4. A method according to claim 1 , wherein said polymeric particles comprise polystyrene or polyacrylate.
5. A method according to claim 1 , further comprising subjecting said porous ceramic element to a thermal treatment at a temperature above 1000° C.
6. A method according to claim 1 , wherein removing said polymeric particles from said ceramic body comprises applying a thermal treatment such that the polymeric particles are decomposed or oxidized.
7. A method according to claim 1 , wherein forming a ceramic body from said slurry comprises one of pressing, slip casting, tape casting, roller pressing, extruding, and injection molding.
8. A method according to claim 1 , wherein the porous ceramic element is self-supporting.
9. A method according to claim 1 , wherein the at least one light emitting diode is a blue light emitting LED and the porous ceramic element is adapted to absorb blue light, while emitting yellow light.
10. A method according to claim 2 , wherein said polymeric particles are removed by subjecting said ceramic body to a thermal treatment at a temperature up to 1000° C.
11. A method according to claim 10 , wherein during said thermal treatment, the ceramic body is sintered such that the ceramic particles are fused together.
12. A method for the manufacture of a porous ceramic element comprising:
providing a slurry comprising ceramic particles of at least one wavelength converting material and polymeric particles having a diameter of from 2 μm to 10 μm;
forming a ceramic body from said slurry; and
removing said polymeric particles from said ceramic body to provide a porous ceramic element having an average pore diameter of from 2 μm to 10 μm.