Electrolyte having eutectic mixture and electrochemical device containing the same
View Patent ↗An electrolyte includes a eutectic mixture comprising (a) an alkoxy alkyl group-containing amide compound having a specific chemistry formula 1 or 2: wherein each of X, R, R1, R2, m and n is defined; and (b) an ionizable lithium salt. The eutectic mixture-containing electrolyte exhibits excellent high temperature stability as well as inherent characteristics of eutectic mixtures, including excellent thermal and chemical stability, thus contributing to improved high temperature stability and decreased lowest limit of electrochemical window. The electrolyte is useful in electrochemical devices comprising various anode materials.
1. An electrolyte, comprising a eutectic mixture comprising:
(a) an alkoxy alkyl group-containing amide compound expressed by the following Chemistry FIG. 1 or 2 ; and
(b) an ionizable lithium salt,
wherein the eutectic mixture contains the alkoxy alkyl group-containing compound and the lithium salt at a mole ratio of 1:1 to 8:1,
wherein R 1 is an alkoxy alkyl group expressed by CH 3 —(CH 2 )p-O(CH 2 )q, where p is an integer of 0 to 8 and q is an integer of 1 to 8,
wherein R 2 is hydrogen, halogen or any one selected from the group consisting of alkyl group, alkylamine group, alkenyl group and aryl group having 1 to 20 carbons, independently, among which at least one is an alkoxy alkyl group expressed by CH 3 —(CH 2 )p-O(CH 2 )q, where p is an integer of 0 to 8 and q is an integer of 1 to 8,
wherein R is hydrogen, halogen or any one selected from the group consisting of alkyl group, alkylamine group, alkenyl group and aryl group having 1 to 20 carbons, and
wherein X is any one selected from the group consisting of carbon, silicon, oxygen, phosphorus, sulfur and hydrogen, wherein i) m is 0 when X is hydrogen, ii) m is 1 when X is oxygen or sulfur, iii) m is 2 when X is phosphorus, and iv) m is 3 when X is carbon or silicon;
wherein R is hydrogen, or any one selected from the group consisting of alkyl group, alkylamine group, alkenyl group, aryl group and allyl group having 1 to 20 carbons,
wherein R 1 is an alkoxy alkyl group expressed by CH 3 —(CH 2 )p-O(CH 2 )q, where p is an integer of 0 to 8 and q is an integer of 1 to 8,
wherein X is any one selected from the group consisting of carbon, silicon, oxygen, phosphorus and sulfur, wherein i) m is 0 when X is oxygen or sulfur, ii) m is 1 when X is phosphorus, and iii) m is 2 when X is carbon or silicon, and
where n is an integer of 1 to 10, and wherein the eutectic mixture has a viscosity of 200 cP or less.
2. The electrolyte according to claim 1 , wherein the alkoxy alkyl group-containing amide compound is any one selected from the group consisting of N-methoxyethyl methylcarbamate, N-methoxyethyl-N-methyl methylcarbamate, N-methoxymethyl-N-methyl methylcarbamate, N methyl-N-methoxyethyl methoxymethyl carbamate, N-methoxyethyl caprolactam and N-methoxyethyl oxazolidinone.
3. The electrolyte according to claim 1 , wherein an anion of the lithium salt is any one selected from the group consisting of F—, Cl—, Br—, I—, NO3-, N(CN)2-, BF4-, ClO4-, PF6-, (CF3)2PF4-, (CF3)3PF3-, (CF3)4PF2-, (CF3)5PF—, (CF3)6P—, CF3SO3-, CF3CF2SO3-, (CF3SO2)2N—, (FSO2)2N—, CF3CF2(CF3)2CO—, (CF3SO2)2CH—, (SF5)3C—, (CF3SO2)3C—, CF3(CF2)7SO3-, CF3CO2-, CH3CO2-, SCN— and (CF3CF2SO2)2N—.
4. The electrolyte according to claim 1 , wherein an anion of the lithium salt is identical to an anion of the ionizable lithium salt in the eutectic mixture.
5. The electrolyte according to claim 1 , wherein the electrolyte is a polymer electrolyte.
6. The electrolyte according to claim 5 , wherein the polymer electrolyte is a gel-type polymer electrolyte formed by polymerization of (i) the eutectic compound, and (ii) a precursor solution containing a monomer that forms a polymer by polymerization reaction.
7. The electrolyte according to claim 6 , wherein the monomer is a vinyl monomer.
8. The electrolyte according to claim 7 , wherein the vinyl monomer is any one selected from the group consisting of acrylonitrile, methylmethacrylate, methylacrylate, methacrylonitrile, methylstyrene, vinylester, vinyl chloride, vinylidene chloride, acrylamide, tetrafluoroethylene, vinylacetate, methylvinylketone, ethylene, styrene, paramethoxystyrene and paracyanostyrene, or their mixtures.
9. The electrolyte according to claim 6 , wherein a content ratio of the eutectic mixture and the monomer in the precursor solution is 0.5˜0.95:0.05˜0.5.
10. The electrolyte according to claim 6 , wherein the gel-type polymer electrolyte is obtained by in-situ polymerization in an electrochemical device.
11. The electrolyte according to claim 5 , wherein the polymer electrolyte is obtained by impregnating the eutectic mixture in a polymer.
12. The electrolyte according to claim 11 , wherein the polymer is any one selected from the group consisting of polymethylmethacrylate, polyvinylidene difluoride, polyvinyl chloride, polyethylene oxide and polyhydroxyethylmethacrylate, or their mixtures.
13. An electrochemical device, comprising a cathode, an anode and the electrolyte of claim 1 .
14. The electrochemical device according to claim 13 , wherein the electrochemical device is a lithium secondary battery.