Environmentally-friendly cementitious articles, formulations, methods of making and uses
View Patent ↗Described herein is a cementitious article and a method of making using a water-based manufacturing system that incorporates a closed-loop or partially closed loop water recycling system and an alkali removal process. The system, as such is environmentally friendly, saves resources, such as water and other raw materials, and reduces waste disposal. The system further provides for a cementitious article having a low alkali content. Articles prepared by one or more processes described herein have characteristics that include a low apparent density, high strength and high freeze-thaw performance as compared with an article of the same general formulation but made from a comparative manufacturing system that does not include an alkali removal process. Articles described herein are suitable for use as building products, such as siding, the underlayment panel, board, trim, fascia, roofing, decking, and fence.
1. A method of recycling spent process water from a cementitious shaped article forming process comprising:
removing calcium, sodium, and potassium ions from the spent process water to provide a process water with a reduced metal ion content, wherein calcium ions are first removed before sodium and potassium ions are removed from the spent process water;
converting calcium to a calcium salt:
adding calcium from the calcium salt to the process water to produce a calcium enriched process water with a reduced potassium and sodium ion content; and
reintroducing at least a portion of the calcium enriched process water with a reduced metal ion content into the cementitious shaped article forming process.
2. The method of claim 1 , wherein the calcium, sodium, and potassium ions are removed from the process water by an ion exchange process.
3. The method of claim 2 , wherein the ion exchange process comprises a first ion exchange resin having a weak acid functional group and a second ion exchange resin having a strong acid functional group.
4. The method of claim 3 , wherein the weak acid functional group is —COOH.
5. The method of claim 3 , wherein the strong acid functional group is —SO 3 H.
6. The method of claim 1 , further comprising removing chromium ions from the process water.
7. The method of claim 1 , wherein the calcium salt comprises calcium sulfate.
8. The method of claim 1 , wherein the calcium from the calcium salt is added to the process water via an ion exchange process.
9. The method of claim 1 , wherein the calcium salt is transported to an ion exchanger and the process water is moved through the ion exchanger.