Single conductive pellets of long glass fiber reinforced thermoplastic resin and manufacturing method thereof
View Patent ↗Single pellets of a thermoplastic resin containing long glass fibers and a conductive filler are set forth that enable molded articles made from these pellets to exhibit conductivity and, at the same time, high mechanical properties. These pellets have mechanical properties that are substantially equivalent to non-conductive pellets of a thermoplastic resin containing same loading of long glass and provide conductivity that is substantially equivalent to articles obtained by blending two kinds of pellets, one pellet having a conductive filler and the other pellet one containing long glass fibers. The pellets include a thermoplastic resin, a long fiber reinforcing filler and a conductive additive dispersed in the pellet.
1. A pellet, comprising:
a) from 30 to 70 wt % of a thermoplastic resin;
b) from 20 to 60 wt % of a plurality of long reinforcing fibers aligned substantially parallel along a longitudinal axis of the pellet and having a length of at least 0.4 mm; and
c) 0.1 to 10 wt % of a conductive filler dispersed in the pellet, wherein the conductive filler comprises carbon black having a pore volume (DBP) equal or greater than 480 ml/100 g and an iodine adsorption equal or greater than 1000 mg/g.
2. The pellet of claim 1 , wherein the thermoplastic resin comprises a polyamide resin.
3. The pellet of claim 2 , wherein the thermoplastic resin comprises nylon 66.
4. The pellet of claim 1 , wherein the long reinforcing fibers comprise glass fibers.
5. The pellet of claim 1 , wherein the conductive filler comprises a carbon black having a pore volume (DBP) of 480-510 ml/100 g and an iodine adsorption of 1000-1100 mg/g.
6. A method of forming a single conductive fiber reinforced pellet comprising the steps of:
a) extruding from 30 to 70 wt % of a thermoplastic resin with 0.1 to 10 wt % of a conductive filler comprising carbon black having a pore volume (DBP) equal to or greater than 480 ml/100g and an iodine absorption equal or greater than 1000 mg/g to disperse the conductive filler in the thermoplastic resin and form a resin mixture;
b) pulling from 20 to 60 wt % of reinforcing fibers through the resin mixture and into a heated die; and
c) pelletizing the fiber reinforced resin mixture to form the single conductive fiber reinforced pellets such that the reinforcing fibers have a length of at least 0.4 mm.
7. The method of claim 6 , wherein the thermoplastic resin comprises a polyamide resin.
8. The method of claim 7 , wherein the thermoplastic resin comprises nylon 66.
9. The method of claim 6 , wherein the long reinforcing fibers comprise glass fibers.
10. The method of claim 6 , wherein the conductive filler comprises a carbon black having a pore volume (DBP) of 480-510 ml/100 g and an iodine absorption of 1000-1100 mg/g and an iodine adsorption equal or greater than 1000 mg/g.