Liquid Crystal composition and liquid crystal display device
View Patent ↗The subject is to provide a liquid crystal composition that satisfies at least one characteristic among characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a low viscosity, a suitable optical anisotropy, a negatively large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat, or that is suitably balanced regarding two or more characteristics. The subject is to provide an AM device that has a short response time, a high voltage holding ratio, a high contrast ratio, a long service life and so forth. The invention provides a liquid crystal composition having a negative dielectric anisotropy that contains a specific compound having a negatively large dielectric anisotropy as a first component, and a specific two-ring compound having a low viscosity as a second component, and provides a liquid crystal display device containing the composition.
1. A liquid crystal composition having a negative dielectric anisotropy that comprises at least one compound selected from the group of compounds represented by formula (1) as a first component and at least one compound selected from the group of compounds represented by formula (2) as a second component:
wherein R 1 and R 2 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; R 3 is independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring A is independently 1,4-cyclohexylene or 1,4-phenylene; Z 1 is independently a single bond, ethylene, methyleneoxy or carbonyloxy; X 1 and X 2 are each independently fluorine or chlorine; m is 1, 2 or 3.
2. The liquid crystal composition according to claim 1 , wherein the first component is at least one compound selected from the group of compounds represented by formulas (1-1) and (1-7):
wherein R 1 and R 2 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
3. The liquid crystal composition according to claim 2 , wherein the first component is at least one compound selected from the group of compounds represented by formulas (1-1).
4. The liquid crystal composition according to claim 2 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-4).
5. The liquid crystal composition according to claim 2 , wherein the first component is at least one compound selected from the group of compounds represented by formulas (1-7).
6. The liquid crystal composition according to claim 2 , wherein the first component is a mixture of at least one compound selected from the group of compounds represented by formula (1-1) and at least one compound selected from the group of compounds represented by formula (1-4).
7. The liquid crystal composition according to claim 2 , wherein the first component is a mixture of at least one compound selected from the group of compounds represented by formula (1-1) and at least one compound selected from the group of compounds represented by formula (1-7).
8. The liquid crystal composition according to claim 1 , wherein the ratio of the first component is in the range of approximately 5% to approximately 60% by weight and the ratio of the second component is in the range of approximately 5% to approximately 40% by weight, based on the total weight of the liquid crystal composition.
9. The liquid crystal composition according to claim 1 that further comprises at least one compound selected from the group of compounds represented by formula (3-1) and formula (3-2) as a third component:
wherein R 4 and R 5 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring B, ring C, ring D and ring E are each independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene; Z 2 is independently a single bond, ethylene, or carbonyloxy; and j is 1 or 2.
10. The liquid crystal composition according to claim 9 , wherein the third component is at least one compound selected from the group of compounds represented by formulas (3-1-1) to (3-1-2) and formulas (3-2-1) to (3-2-9):
wherein R 4 and R 5 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
11. The liquid crystal composition according to claim 9 , wherein the ratio of the third component is in the range of approximately 5% to approximately 40% by weight based on the total weight of the liquid crystal composition.
12. The liquid crystal composition according to claim 1 that further comprises at least one compound selected from the group of compounds represented by formulas (4-1) and (4-2) as a fourth component:
wherein R 1 and R 2 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring F is independently tetrahydropyran-2,5-diyl, 1,4-cyclohexylene, or 1,4-phenylene; at least one ring-D F is tetrahydropyran-2,5-diyl, ring G and ring I are each independently 1,4-cyclohexylene or 1,4-phenylene; Z 1 and Z 3 are each independently a single bond, ethylene, methyleneoxy or carbonyloxy; k is 1, 2 or 3; p and q are 0, 1, 2 or 3; and the sum of p and q is 3 or less.
13. The liquid crystal composition according to claim 9 that further comprises at least one compound selected from the group of compounds represented by formulas (4-1) and (4-2) as a fourth component:
wherein R 1 and R 2 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring F is independently tetrahydropyran-2,5-diyl, 1,4-cyclohexylene, or 1,4-phenylene; at least one ring-D F is tetrahydropyran-2,5-diyl, ring G and ring I are each independently 1,4-cyclohexylene or 1,4-phenylene; Z 1 and Z 3 are each independently a single bond, ethylene, methyleneoxy or carbonyloxy; k is 1, 2 or 3; p and q are 0, 1, 2 or 3; and the sum of p and q is 3 or less.
14. The liquid crystal composition according to claim 12 , wherein the fourth component is at least one compound selected from the group of compounds represented by formulas (4-1-1) to (4-1-7) and formulas (4-2-1) to (4-2-4):
wherein R 1 and R 2 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring E1, ring E 2 , ring F 1 , ring F 2 are each independently 1,4-cyclohexylene or 1,4-phenylene; Z 1 and Z 3 are each independently a single bond, ethylene, methyleneoxy or carbonyloxy.
15. The liquid crystal composition according to claim 13 , wherein the fourth component is at least one compound selected from the group of compounds represented by formulas (4-1-1) to (4-1-7) and formulas (4-2-1) to (4-2-4):
wherein R 1 and R 2 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring E1, ring E 2 , ring F 1 , ring F 2 are each independently 1,4-cyclohexylene or 1,4-phenylene; Z 1 and Z 3 are each independently a single bond, ethylene, methyleneoxy or carbonyloxy.
16. The liquid crystal composition according to claim 12 , wherein the ratio of the fourth component is in the range of approximately 5% to approximately 50% by weight based on the total weight of the liquid crystal composition.
17. The liquid crystal composition according to claim 13 , wherein the ratio of the fourth component is in the range of approximately 5% to approximately 50% by weight based on the total weight of the liquid crystal composition.
18. The liquid crystal composition according to claim 1 , wherein the maximum temperature of a nematic phase is approximately 70° C. or higher, the optical anisotropy (25° C.) at a wavelength of 589 nm is approximately 0.08 or more, and the dielectric anisotropy (25° C.) at a frequency of 1 kHz is approximately −2 or less.
19. A liquid crystal display device that comprises the liquid crystal composition according to any one of claim 1 .
20. The liquid crystal display device according to claim 19 wherein an operating mode of the liquid crystal display device is a VA mode, an IPS mode or a PSA mode, and a driving mode of the liquid crystal display device is an active matrix mode.