IP Library Granted Patent US 11,111,562
Granted Patent B2
US 11,111,562 · App. 12/820,495 · Granted Sep 7, 2021

Aluminum-copper-lithium alloy with improved mechanical strength and toughness

Inventors: Timothy Warner (Voreppe, FR); Christophe Sigli (Grenoble, FR); Cedric Gasqueres (Bourgoin-Jallieu, FR); Armelle Danielou (Les Echelles, FR)
Assignee: CONSTELLIUM ISSOIRE
C22C21/00C22C21/16C22F1/04C22F1/057
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Quick Facts
Patent No.
US 11,111,562
App. No.
12/820,495
Granted
Sep 7, 2021
Kind
B2
Abstract

The invention relates to a wrought product such as an extruded, rolled and/or forged aluminum alloy-based product, comprising, in weight %: Cu: 3.0-3.9; Li: 0.8-1.3; Mg: 0.6-1.0; Zr: 0.05-0.18; Ag: 0.0-0.5; Mn: 0.0-0.5; Fe+Si≤0.20; Zn≤0.15; at least one element from among: Ti: 0.01-0.15; Sc: 0.05-0.3; Cr: 0.05-0.3; Hf: 0.05-0.5; other elements ≤0.05 each and ≤0.15 total, remainder aluminum. The invention also relates to the process for producing said product. The products according to the invention are particularly useful in the production of thick aluminum products intended for producing structural elements in the aeronautical industry.

Claims (31)

1. An aluminum-based wrought product that is rolled and has a thickness from 10-130 mm, said product comprising, in weight %:

Cu: 3.5-3.7;

Li: 0.9-1.2;

Mg: 0.6-0.8;

Zr: 0.05-0.18;

Ag: 0.0-0.5;

Mn: 0.0-0.5;

Fe+Si≤0.20;

Zn≤0.15;

at least one element selected from the group consisting of: Ti: 0.01-0.15; Sc: 0.05-0.3; Cr: 0.05-0.3; Hf: 0.05-0.5;

other elements ≤0.05 each and ≤0.15 total, remainder aluminum;

wherein the composition is selected so as to obtain a density that is not more than 2.71 g/cm3,

which in a rolled state, solution treated, quenched and aged so as to obtain a near-peak yield strength, has, at half-thickness, at least one of the following pairs of properties:

for thicknesses from 10 to <30 mm: a yield strength Rp0.2(L)≥525 MPa and a toughness K1C (L−T)≥45 MPa√m,

for thicknesses of 30 to <60 mm: a yield strength Rp0.2(L)≥525 MPa and a toughness K1C (L−T)≥43 MPa√m,

for thicknesses of 60 to <100 mm: a yield strength Rp0.2(L)≥520 MPa and a toughness K1C (L−T)≥40 MPa√m, or

for thicknesses of 100 to 130 mm, at half-thickness, a yield strength Rp0.2(L)≥510 MPa and a toughness K1C (L−T)≥37 MPa√m,

and wherein at least two properties of the product do not change more than 5% after thermal exposure of 1000 hours at 85° C., the at least two properties selected from the group consisting of: tensile yield strength Rp0.2 (L), ultimate tensile stress UTS (Rm L), and an elongation at rupture A % (L).

2. A product according to claim 1 , wherein the magnesium content is from 0.65 to 0.8% by weight.

3. A product according to claim 1 , wherein the manganese content is from 0.2 to 0.4% by weight.

4. A product according to claim 1 , wherein the silver content is from 0.15 to 0.35% by weight.

5. A product according to claim 1 , wherein the iron and silicon contents are each at most 0.08% by weight and/or in wherein the zinc content is ≤0.05% by weight.

6. A product according to claim 1 , wherein the thickness is equal to at least 30 mm.

7. A structural element comprising a product according to claim 1 .

8. An aeronautical construction comprising a structural element of claim 7 .

9. An aeronautical construction according to claim 8 in which the structural element is an underwing or upper wing element of which skin and/or stringers can be obtained from the same starting product, a spar and/or a rib.

10. A product according to claim 1 , which in a rolled state, solution treated, quenched and aged so as to obtain a near-peak yield strength, has, at half-thickness, at least one of the following pairs of properties:

for thicknesses from 10 to <30 mm: a yield strength Rp0.2(L)≥545 MPa and a toughness K1C (L−T)≥45 MPa√m,

for thicknesses of 30 to <60 mm: a yield strength Rp0.2(L)≥545 MPa and a toughness K1C (L−T)≥43 MPa√m,

for thicknesses of 60 to <100 mm: a yield strength Rp0.2(L)≥535 MPa and a toughness K1C (L−T)≥40 MPa√m, or

for thicknesses of 100 to 130 mm, at half-thickness, a yield strength Rp0.2(L)≥525 MPa and a toughness K1C (L−T)≥37 MPa√m.

Assignments (4)
CORRECTIVE ASSIGNMENT TO CORRECT THE CONVEYING PARTY PREVIOUSLY RECORDED AT REEL: 040423 FRAME: 0118. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded Jan 8, 2018
From: CONSTELLIUM FRANCE
To: CONSTELLIUM ISSOIRE
Reel/Frame 045948/0577 →
CHANGE OF NAME Recorded Oct 19, 2016
From: CONSTELLIUM FRANCE SAS
To: CONSTELLIUM ISSOIRE
Reel/Frame 040423/0118 →
CHANGE OF NAME Recorded Jan 5, 2012
From: ALCAN RHENALU
To: CONSTELLIUM FRANCE
Reel/Frame 027489/0240 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 27, 2010
From: WARNER, TIMOTHY; SIGLI, CHRISTOPHER; GASQUERES, CEDRIC; DANIELOU, ARMELLE
To: ALCAN RHENALU
Reel/Frame 024748/0351 →