Article comprising light absorbent composition to mask visual haze and related methods
A transparent article includes a continuous polyester matrix having at least one incompatible filler dispersed therein. The incompatible filler provides domains in the polyester matrix, each domain having a particular dimension, thus providing a range of dimensions for the domains in the article. To create haze, the dimensions are within the range of from about 380 nm to about 720 nm. Once the range of dimensions is determined, a light absorbent composition can be found which absorbs light at a range of wavelengths that at least substantially covers the range of dimensions of the domains. In doing so, it has been found that the haze of the article can be substantially masked. Method for producing the article and for masking the haze are also provided.
1. A colored article having visual haze in the absence of an effective amount of one or more light absorbing compositions;
the colored article comprising a thermoplastic polymer matrix;
a plurality of domains in a single continuous portion of the colored article wherein said domains are dispersed in the polymer matrix and encompass at least one incompatible filler; and
the effective amount of one or more light absorbing compositions;
with said domains having a range of dimensions in an axial plane of the colored article, wherein said dimensions of at least some of said domains in said axial plane of the colored article fall within a range of from about 400 nm to about 700 nm; and
wherein the colored article is of a single-layer construction; and
said effective amount of one or more light absorbing compositions absorbs light in a region of the visible spectrum at wavelengths that at least substantially correlates to the dimensions of said domains in the range of 400 to 700 nm thereby substantially masking the visual haze that is present in the absence of the effective amount of one or more light absorbing compositions at said single continuos portion when the colored article is viewed in a line of sight perpendicular to said single continuous portion of the colored article.
2. The colored article of claim 1 , wherein said colored article is an oriented container and wherein the single continuous portion of the colored article is a sidewall of the container.
3. The colored article of claim 1 , wherein said colored article is a plastic bottle and wherein the single continuous portion of the colored article is a sidewall of the bottle.
4. The colored article of claim 1 , wherein the thermoplastic polymer matrix is selected from the group consisting of linear polyesters, branched polyesters, polyamides, polystyrenes, polycarbonates, polyvinylchlorides, polyvinylidene dichlorides, polyacrylamides, polyacrylonitrites, polyvinylacetate, polyvinyl methyl ether, ethylene vinyl acetate copolymer, ethylene methyl acrylate copolymer, low molecular weight polyolefins having 2 to 8 carbon atoms, and copolymers, terpolymers, and blends thereof.
5. The colored article of claim 1 , wherein said thermoplastic polymer matrix is a linear polyester matrix selected from the group consisting of polyethylene terephthalate, polyethylene naphthalate, and polybutylene terephthalate, polytrimethylene terephthalate, polyethylene isophthalate and copolymers, terpolymers, and blends thereof.
6. The colored article of claim 5 , wherein said linear polyester matrix is polyethylene terephthalate or a copolymer thereof.
7. The colored article of claim 1 , wherein said incompatible filler is a polyamide.
8. The colored article of claim 1 , wherein said incompatible filler is poly(m-xylylene adipamide).
9. The colored article of claim 1 , wherein said incompatible filler is a gas barrier strengthening filler.
10. The colored article of claim 1 , wherein the article comprises from about 99.5 to about 50 percent by weight thermoplastic polymer and from about 0.5 to about 50 percent by weight incompatible filler.
11. The colored article of claim 1 , wherein said article comprises from about 99.5 to about 50 percent by weight polyethylene terephthalate and from about 0.5 to about 50 percent by weight poly(m-xylylene adipamide).
12. The colored article of claim 1 , wherein said light absorbent composition is a colorant.
13. The colored article of claim 1 , wherein said incompatible filler is nylon 6.
14. The colored article of claim 5 , wherein said linear polyester matrix is polyethylene terephthalate modified with isophthalic acid.
15. The colored article of claim 5 , wherein said incompatible filler is selected from the group consisting of thermoplastic polymers other than polyesters and clays.
16. The colored article of claim 5 , wherein said incompatible filler is a polyamide.
17. The colored article of claim 6 , wherein said incompatible filler is poly(m-xylylene adipamide).
18. The colored article of claim 6 , wherein said incompatible filler is nylon 6.
19. The colored article of claim 1 , wherein at least one of the light absorbing compositions is a red colorant.
20. The colored article of claim 19 , wherein said colored article is an oriented container and wherein the single continuous portion of the colored article is a sidewall of the container.
21. The colored article of claim 19 , wherein said colored article is a plastic bottle and wherein the single continuous portion of the colored article is a sidewall of the bottle.
22. The colored article of claim 19 , wherein said thermoplastic polymer matrix is polyethylene terephthalate or a copolymer thereof.
23. The colored article of claim 19 , wherein said incompatible filler is a polyamide.
24. The colored article of claim 19 , wherein said incompatible filler is poly(m-xylylene adipamide).
25. The colored article of claim 19 , wherein said incompatible filler is nylon 6.
26. The colored article of claim 19 , wherein said incompatible filler is selected from the group consisting of thermoplastic polymers other than polyesters and clays.
27. The colored article of claim 22 , wherein said incompatible filler is a polyamide.
28. The colored article of claim 22 , wherein said incompatible filler is poly(m-xylylene adipamide).
29. The colored article of claim 22 , wherein said incompatible filler is nylon 6.
30. The colored article of claim 1 , wherein at least one of the light absorbing compositions is a yellow colorant.
31. The colored article of claim 30 , wherein said colored article is an oriented container and wherein the single continuous portion of the colored article is a sidewall of the container.
32. The colored article of claim 30 , wherein said colored article is a plastic bottle and wherein the single continuous portion of the colored article is a sidewall of the bottle.
33. The colored article of claim 30 , wherein said thermoplastic polymer matrix is polyethylene terephthalate or a copolymer thereof.
34. The colored article of claim 30 , wherein said incompatible filler is a polyamide.
35. The colored article of claim 30 , wherein said incompatible filler is poly(m-xylylene adipamide).
36. The colored article of claim 30 , wherein said incompatible filler is nylon 6.
37. The colored article of claim 30 , wherein said incompatible filler is selected from the group consisting of thermoplastic polymers other than polyesters and clays.
38. The colored article of claim 33 , wherein said incompatible filler is a polyamide.
39. The colored article of claim 33 , wherein said incompatible filler is poly(m-xylylene adipamide).
40. The colored article of claim 33 , wherein said incompatible filler is nylon 6.
41. The colored article of claim 19 , wherein at least one of the light absorbing compositions is a yellow colorant.
42. The colored article of claim 41 , wherein said colored article is an oriented container and wherein the single continuous portion of the colored article is a sidewall of the container.
43. The colored article of claim 41 , wherein said colored article is a plastic bottle and wherein the single continuous portion of the colored article is a sidewall of the bottle.
44. The colored article of claim 41 , wherein said thermoplastic polymer matrix is polyethylene terephthalate or a copolymer thereof.
45. The colored article of claim 41 , wherein said incompatible filler is a polyamide.
46. The colored article of claim 41 , wherein said incompatible filler is poly(m-xylylene adipamide).
47. The colored article of claim 41 , wherein said incompatible filler is nylon 6.
48. The colored article of claim 41 , wherein said incompatible filler is selected from the group consisting of thermoplastic polymers other than polyesters and clays.
49. The colored article of claim 44 , wherein said incompatible filler is a polyamide.
50. The colored article of claim 44 , wherein said incompatible filler is poly(m-xylylene adipamide).
51. The colored article of claim 44 , wherein said incompatible filler is nylon 6.
52. The colored article of claim 1 , wherein the colored article further comprises a red colorant, a yellow colorant, and a blue colorant.
53. The colored article of claim 52 , wherein the incompatible filler is selected from the group of thermoplastic polymers other than polyesters and clays.
54. The colored article of claim 53 , wherein the incompatible filler is a polyamide.
55. The colored article of claim 1 , wherein the light absorbing composition absorbs light in the region of 450 to 600 nm.
56. The colored article of claim 55 , wherein the incompatible filler is selected from the group of thermoplastic polymers other than polyesters and clays.
57. The colored article of claim 56 , wherein the incompatible filler is a polyamide.
58. The colored article of claim 1 , wherein the thermoplastic polymer matrix is a polyester and the at least one light absorbing composition is the polyester.
59. The colored article of claim 58 , wherein the incompatible filler is selected from the group of thermoplastic polymers other than polyesters and clays.
60. The colored article of claim 59 , wherein the incompatible filler is a polyamide.