IP Library Granted Patent US 8,758,529
Granted Patent B2
US 8,758,529 · App. 12/827,564 · Granted Jun 24, 2014

Cast aluminum alloys

Inventors: Qigui Wang (Rochester Hills, MI); Wenying Yang (Windsor, CA); Yucong Wang (West Bloomfield, MI); Patricia E. Shaw (Clarkston, MI)
Assignee: GM Global Technology Operations LLC
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Quick Facts
Patent No.
US 8,758,529
App. No.
12/827,564
Granted
Jun 24, 2014
Kind
B2
Abstract

Aluminum alloys having improved properties are provided. The alloy includes about 0 to 2 wt % rare earth elements, about 0.5 to about 14 wt % silicon, about 0.25 to about 2.0 wt % copper, about 0.1 to about 3.0 wt % nickel, approximately 0.1 to 1.0% iron, about 0.1 to about 2.0 wt % zinc, about 0.1 to about 1.0 wt % magnesium, 0 to about 1.0 wt % silver, about 0.01 to about 0.2 wt % strontium, 0 to about 1.0 wt % scandium, 0 to about 1.0 wt % manganese, 0 to about 0.5 wt % calcium, 0 to about 0.5 wt % germanium, 0 to about 0.5 wt % tin, 0 to about 0.5 wt % cobalt, 0 to about 0.2 wt % titanium, 0 to about 0.1 wt % boron, 0 to about 0.2 wt % zirconium, 0 to 0.5% yttrium, 0 to about 0.3 wt % cadmium, 0 to about 0.3 wt % chromium, 0 to about 0.5 wt % indium, and the balance aluminum. Methods of making cast aluminum parts are also described.

Claims (15)

1. A high-temperature aluminum alloy with trialuminide compounds that form a crystallized structure selected from the group consisting of L1 2 , D0 22 and D0 23 , the alloy consisting essentially of 0 to about 2.0 wt % of at least one rare earth element, about 0.5 to about 14 wt % silicon, about 0.25 to about 2.0 wt % copper, about 0.1 to about 3.0 wt % nickel, about 0.1 to about 1.0 wt % iron, about 0.1 to about 2.0 wt % zinc, about 0.1 to about 1.0 wt % magnesium, 0 to about 1.0 wt % silver, about 0.01 to about 0.2 wt % strontium, 0 to about 1.0 wt % manganese, 0 to about 0.5 wt % calcium, about 0.5 wt % germanium, 0 to about 0.5 wt % tin, 0 to about 0.5 wt % cobalt, 0 to about 0.2 wt % titanium, 0 to about 0.1 wt % boron, 0 to about 0.3 wt % cadmium, 0 to about 0.3 wt % chromium, 0 to about 0.5 wt % indium, at least one selected from the group consisting of: about 0.1 to about 1 wt % Sc, about 0.1 to about 0.2 wt % Zr, and about 0.25 to about 0.5 wt % Y, and the balance aluminum.

2. The aluminum alloy of claim 1 consisting essentially of 0 to about 1.0 wt % of at least one rare earth element, about 6 to about 13 wt % silicon, about 0.25 to about 1.5 wt % copper, about 0.5 to about 2 wt % nickel, about 0.1 to about 0.5 wt % iron, about 0.1 to about 1.5 wt % zinc, about 0.3 to about 0.6 wt % magnesium, 0 to about 0.5 wt % silver, about 0.01 to 0.1 wt % strontium, about 0.5 to about 1.0 wt % manganese, 0 to about 0.5 wt % calcium, up to about 0.5 wt % germanium, 0 to about 0.5 wt % tin, 0 to about 0.5 wt % cobalt, 0 to about 0.2 wt % titanium, 0 to about 0.1 wt % boron, 0 to about 0.3 wt % cadmium, 0 to about 0.3 wt % chromium, 0 to about 0.5 wt % indium, at least one selected from the group consisting of: about 0.1 to about 1 wt % Sc, about 0.1 to about 0.2 wt % Zr, and about 0.25 to about 0.5 wt % Y, and the balance aluminum.

3. The aluminum alloy of claim 1 consisting essentially of about 0.5 to about 1.0 wt % of at least one rare earth element, about 8 to about 10 wt % silicon, about 0.25 to about 0.5 wt % copper, about 1.0 to about 2.5 wt % nickel, about 0.1 to about 0.5 wt % iron, about 0.5 to about 1.5 wt % zinc, about 0.1 to about 0.3 wt % magnesium, 0 to about 0.5 wt % silver, about 0.01 to about 0.1 wt % strontium, about 0.5 to about 1.0 wt % manganese, 0 to about 0.5 wt % calcium, up to about 0.5 wt % germanium, 0 to about 0.5 wt % tin, 0 to about 0.5 wt % cobalt, 0 to about 0.2 wt % titanium, 0 to about 0.1 wt % boron, 0 to about 0.3 wt % cadmium, 0 to about 0.3 wt % chromium, 0 to about 0.5 wt % indium, at least one selected from the group consisting of: about 0.1 to about 1 wt % Sc, about 0.1 to about 0.2 wt % Zr, and about 0.25 to about 0.5 wt % Y, and the balance aluminum.

4. The aluminum alloy of claim 1 consisting essentially of 0 to about 1 wt % of at least one rare earth element, about 8 to about 10 wt % silicon, about 0.25 to about 0.5 wt % copper, about 0.5 to about 2.5 wt % nickel, about 0.1 to about 0.5 wt % iron, about 0.5 to about 1.0 wt % zinc, about 0.2 to about 0.4 wt % magnesium, 0 to about 0.5 wt % silver, about 0.01 to about 0.1 wt % strontium, 0 to about 0.5 to about 1.0 wt % manganese, 0 to about 0.5 wt % calcium, up to about 0.5 wt % germanium, 0 to about 0.5 wt % tin, 0 to about 0.5 wt % cobalt, 0 to about 0.2 wt % titanium, 0 to about 0.1 wt % boron, 0 to about 0.3 wt % cadmium, 0 to about 0.3 wt % chromium, 0 to about 0.5 wt % indium, at least one selected from the group consisting of: about 0.1 to about 1 wt % Sc, about 0.1 to about 0.2 wt % Zr, and about 0.25 to about 0.5 wt % Y, and the balance aluminum.

5. The aluminum alloy of claim 1 consisting essentially of 0 to about 1 wt % of at least one rare earth element, about 8 to about 12 wt % silicon, about 0.25 to about 1.5 wt % copper, about 0.5 to about 2.5 wt % nickel, about 0.1 to about 0.5 wt % iron, about 0.5 to about 1.0 wt % zinc, about 0.3 to about 0.6 wt % magnesium, 0 to about 0.5 wt % silver, about 0.01 to about 0.1 wt % strontium, 0 to about 0.5 wt % scandium, about 0.5 to about 1.0 wt % manganese, 0 to about 0.5 wt % calcium, up to about 0.5 wt % germanium, 0 to about 0.5 wt % tin, 0 to about 0.5 wt % cobalt, 0 to about 0.2 wt % titanium, 0 to about 0.1 wt % boron, 0 to about 0.2 wt % zirconium, 0 to 0.5% yttrium, 0 to about 0.3 wt % cadmium, 0 to about 0.3 wt % chromium, 0 to about 0.5 wt % indium, and the balance aluminum.

6. The aluminum alloy of claim 1 wherein the rare earth element is lanthanum, ytterbium, gadolinium, neodymium, erbium, holmium, thuliam, cerium, or combinations thereof.

7. The aluminum alloy of claim 1 wherein a sum of an amount of copper and an amount of nickel is less than about 4.0 wt %.

8. The aluminum alloy of claim 1 wherein a ratio of an amount of copper to an amount of nickel is greater than about 1.5.

9. The aluminum alloy of claim 1 wherein a sum of an amount of copper and an amount of nickel is less than about 4.0 wt % and a ratio of an amount of copper to an amount of nickel is greater than about 1.5.

10. The aluminum alloy of claim 1 wherein a microstructure of the aluminum alloy includes at least one insoluble solidified particle, precipitated particle, or both.

11. The aluminum alloy of claim 1 wherein when the alloy contains about 7 to about 14 wt % silicon, the alloy contains about 0.01 to about 0.015 wt % strontium, about 0.15 to about 0.2 wt % titanium, and about 0.005 to about 0.1 wt % boron.

12. The aluminum alloy of claim 1 wherein a sum of an amount of iron and an amount of manganese is between about 0.5 and 1.5 wt %.

13. The aluminum alloy of claim 1 wherein a ratio of an amount of manganese to an amount of iron is at least about 0.5.

14. The aluminum alloy of claim 1 wherein there is at least about 0.5 wt % zinc.

15. The aluminum alloy of claim 1 wherein the aluminum alloy contains about 12 to about 14 wt % silicon and about 0.45 to about 1.0 wt % magnesium.

Assignments (4)
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2014
From: WILMINGTON TRUST COMPANY
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 034287/0001 →
CHANGE OF NAME Recorded Feb 10, 2011
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 025781/0333 →
SECURITY AGREEMENT Recorded Nov 8, 2010
From: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
To: WILMINGTON TRUST COMPANY
Reel/Frame 025327/0156 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 30, 2010
From: WANG, QIGUI; YANG, WENYING; WANG, YUCONG; SHAW, PATRICIA E.
To: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
Reel/Frame 024619/0052 →
Continuity (1)
Related Publication 20120000578A1 · Jan 5, 2012