Treatment and kits for creating transparent renewable surface protective coatings
View Patent ↗Methods, treatment compositions and treatment systems are disclosed for forming a detachable and renewable coating on a receptive surface by a process of applying a treatment composition comprising a plurality of hydrophobically modified fumed silica particles colloidally dispersed in a volatile solvent; allowing the volatile solvent to evaporate; and thereby depositing a protective coating on the receptive surface consisting of a layer of the hydrophobically modified particles, which provide a substantially transparent coating with dirt- and water-repellency properties that effectively shed dry particulate soils as well as water from the treated surface or treated article bearing a receptive surface. The methods, treatment compositions and treatment systems employing the hydrophobically modified fumed silica particle are particularly useful in providing nearly invisible detachable coatings and treated articles featuring surface protective benefits including dirt- and water-repellency, self-cleaning with water, and easier cleaning benefits when applied to a variety of automotive and home surfaces, both interior and exterior, including articles and materials such as metals, painted materials, sealed materials, plastics and polymeric articles, wood, textiles and the like.
1. A method of forming a detachable and renewable protective coating on a receptive surface comprising the steps of:
A. applying a treatment composition to said receptive surface, said treatment composition comprising a plurality of hydrophobically modified fumed silica particles colloidally dispersed in a volatile solvent;
wherein the treatment composition is obtained by a process comprising the steps of:
(a) providing a pre-dispersion of silica particles comprising hydrophobically modified fumed silica particles by stirring said silica particles into a solution comprising:
(i) at least one compound of general formula (I) or (II):
(R1R2R3Si)2NR4 (I)
—(R1R2SiNR4)m-(cyclo) (II)
wherein R1, R2 and R3 can be the same or different, and are independently selected from hydrogen, straight or branched, saturated or unsaturated alkyl chain groups of from 1 to 8 carbon atoms, or aromatic groups of from 6 to 12 carbon atoms, R4 is hydrogen or a methyl group, and m is from 3 to 8; and
(ii) a first volatile solvent or solvent mixture selected from straight or branched, linear or cyclic aliphatic, or aromatic hydrocarbons with 2 to 14 carbon atoms, monovalent linear or branched alcohols with 1 to 6 carbon atoms, ketones or aldehydes with 1 to 6 carbon atoms, ethers or esters with 2 to 8 carbon atoms, or linear or cyclic polydimethylsiloxanes with 2 to 10 dimethylsiloxy units, wherein the concentration of the hydrophobically modified fumed silica particles in the pre-dispersion results in from 10 percent to about 30 percent by weight of the total weight of the pre-dispersion, and wherein the concentration of any one of compounds (I) and/or (II) is between 0.1 and 10 percent by weight of the total weight of the pre-dispersion; and
(b) mixing with a disperser said pre-dispersion to provide a process composition while reducing said silica particles to a median particle size in the range between 100 and 4000 nanometers;
B. allowing said volatile solvent to evaporate from said receptive surface; and
C. thereby depositing said protective coating on said receptive surface, wherein said protective coating provides dirt- and water-repellency to said receptive surface, wherein said detachable coating is substantially transparent and results in a change of less than 250 Delta Haze units to said receptive surface measured before and after deposition of said coating, as measured by the Chrome Test.
2. A method of forming a detachable and renewable protective coating on a receptive surface comprising the steps of:
A. applying a treatment composition to said receptive surface, said treatment composition comprising a plurality of hydrophobically modified fumed silica particles colloidally dispersed in a volatile solvent;
wherein the treatment composition is obtained by a process comprising the steps of:
(a) providing a pre-dispersion of silica particles comprising hydrophobically modified fumed silica particles by stirring said silica particles into a solution comprising:
(i) at least one compound of general formula (I) or (II):
(R1R2R3Si)2NR4 (I)
—(R1R2SiNR4)m-(cyclo) (II)
wherein R1, R2 and R3 can be the same or different, and are independently selected from hydrogen, straight or branched, saturated or unsaturated alkyl chain groups of from 1 to 8 carbon atoms, or aromatic groups of from 6 to 12 carbon atoms, R4 is hydrogen or a methyl group, and m is from 3 to 8; and
(ii) a first volatile solvent or solvent mixture selected from straight or branched, linear or cyclic aliphatic, or aromatic hydrocarbons with 2 to 14 carbon atoms, monovalent linear or branched alcohols with 1 to 6 carbon atoms, ketones or aldehydes with 1 to 6 carbon atoms, ethers or esters with 2 to 8 carbon atoms, or linear or cyclic polydimethylsiloxanes with 2 to 10 dimethylsiloxy units, wherein the concentration of the hydrophobically modified fumed silica particles in the pre-dispersion results in from 10 percent to about 30 percent by weight of the total weight of the pre-dispersion, and wherein the concentration of any one of compounds (I) and/or (II) is between 0.1 and 10 percent by weight of the total weight of the pre-dispersion;
(b) mixing with a disperser said pre-dispersion to provide a process composition while reducing said silica particles to a median particle size in the range between 100 and 4000 nanometers; and
(c) optionally, adding one or more of the following components to the treatment composition: a suspending agent, a functional adjunct and a propellant;
B. allowing said volatile solvent to evaporate from said receptive surface; and
C. thereby depositing said protective coating on said receptive surface, wherein said protective coating provides dirt- and water-repellency to said receptive surface, wherein said detachable coating is substantially transparent and results in a change of less than 3.0 Delta E units to said receptive surface measured before and after deposition of said coating.
3. The method of claim 2 wherein said solution further comprises at least one durability agent selected from alkoxysilanes of general formula (III)
R5aSi(OR6)4-a (III)
wherein R5 is a straight or branched, saturated or unsaturated alkyl chain group of from 1 to 16 carbon atoms, optionally substituted with fluorine atoms, hydroxyl, amino, mercapto, or epoxy groups, R6 is an alkyl chain of 1 to 2 carbon atoms, and a is 1 or 2; or alkyl-modified linear or cyclic polydimethylsiloxanes of general formula (IV) or (V)
(CH3)3SiO[(CH3)2SiO]n[(CH3)R7SiO]oSi(CH3)3 (IV)
—[(CH3)2SiO]p[(CH3)R7SiO]q— (cyclo) (V)
wherein R7 is an alkyl chain group of from 6 to 24 carbon atoms, n is from 1 to 100, o is from 1 to 40, p from 0 to 7, and q is from 1 to 7, provided that the sum (p+q) is at least 3; whereby the concentration of any one of the durability agents (III) and/or (IV) and/or (V) is between 0.1 and 10 percent by weight of the total weight of the pre-dispersion.
4. The method of claim 3 further comprising (c) diluting the process composition with a second volatile solvent or solvent mixture selected from straight or branched, linear or cyclic aliphatic, or aromatic hydrocarbons with 2 to 14 carbon atoms, optionally substituted with fluorine or chlorine atoms, monovalent linear or branched alcohols with 1 to 6 carbon atoms, ketones or aldehydes with 1 to 6 carbon atoms, ethers or esters with 2 to 8 carbon atoms, or linear or cyclic polydimethylsiloxanes with 2 to 10 dimethylsiloxy units to a final concentration of the hydrophobically modified fumed silica particles of minimum 5 percent by weight of the total weight of the process composition.
5. The method of claim 4 , further comprising (d) adding a durability agent selected from alkoxysilanes of general formula (III)
R5aSi(OR6)4-a (III)
wherein R5 is a straight or branched, saturated or unsaturated alkyl chain group of from 1 to 16 carbon atoms, optionally substituted with fluorine atoms, hydroxyl, amino, mercapto, or epoxy groups, R6 is an alkyl chain of 1 to 2 carbon atoms, and a is 1 or 2; or alkyl-modified linear or cyclic polydimethylsiloxanes of general formulas (IV) or (V)
(CH3)3SiO[(CH3)2SiO]n[(CH3)R7SiO]oSi(CH3)3 (IV)
—[(CH3)2SiO]p[(CH3)R7SiO]q— (cyclo) (V)
wherein R7 is an alkyl chain group of from 6 to 24 carbon atoms, n is from 1 to 100, o is from 1 to 40, p from 0 to 7, and q is from 1 to 7, provided that the sum (p+q) is at least 3, to the dispersion as obtained in step (b) or step (c), whereby the concentration of any one of the durability agents (III) and/or (IV) and/or (V) is between 0.01 and 10 percent by weight of the total weight of the process composition.
6. The method of claim 2 , wherein said hydrophobically modified fumed silica particles have a median particle size of between 100 and 4,000 nanometers.
7. The method of claim 2 , wherein said hydrophobically modified fumed silica particles have a median particle size of between 100 and 3,000 nanometers.
8. The method of claim 2 , wherein said hydrophobically modified fumed silica particles have a median particle size of between 100 and 1,000 nanometers.
9. The method of claim 2 , wherein said receptive surface comprises a non-porous substrate, porous substrate, and combinations thereof.
10. The method of claim 9 , wherein said receptive surface is selected from the group consisting of automotive surfaces, household interior surfaces, household exterior surfaces, articles of construction, and combinations thereof.
11. The method of claim 9 , wherein said non-porous substrate is selected from the group consisting of metal, metal oxides, aluminum, anodized aluminum, painted substrates, stainless steel, chrome, clear-coated automotive surfaces, ellastomers, vinyl, plastics, polymers, sealed wood, laminates, composites, and combinations thereof.
12. The method of claim 11 , wherein said protective coating on said non-porous substrate is substantially transparent and results in a change of less than 3.0 Delta E units of said non-porous substrate after application of said coating.
13. The method of claim 9 , wherein said porous substrate is selected from the group consisting of fibers, textiles, non-wovens, foam substrates, cloth, clothing, leather, upholstery, carpet, curtains, marble, granite, grout, mortar, concrete, spackling, plaster, adobe, stucco, brick, unglazed tile, tile, unglazed porcelain, porcelain, clay, wallpaper, cardboard, paper, wood, and combinations thereof.
14. The method of claim 13 , wherein said protective coating on said porous surface is substantially transparent and results in a change of less than 3.0 Delta L units of said porous substrate after application of said coating.
15. The method of claim 2 , wherein said coating further exhibits a Durability Duration value of greater than or equal to 15 seconds.