Cathode active material for lithium secondary battery
View Patent ↗Disclosed herein is a cathode active material based on lithium nickel-manganese-cobalt oxide represented by Formula 1, wherein an ion-conductive solid compound and conductive carbon are applied to a surface of the lithium nickel-manganese-cobalt oxide. A lithium secondary battery having the disclosed cathode active material has improved rate properties and high temperature stability, in turn embodying excellent cell performance.
1. A cathode active material, comprising:
cathode active material particles comprising lithium nickel-manganese-cobalt oxide represented by Formula (1), wherein a content of nickel is relatively higher than a content of manganese and cobalt, wherein the lithium nickel-manganese-cobalt oxide comprises a particle with an agglomerated structure consisting of an aggregate of microfine particles, and
wherein an ion-conductive solid compound and conductive carbon are present as a coating on a surface of the particles by dry coating:
Li x M y O 2 (1)
wherein M is Ni 1-a-b Mn a CO b (0.05≦a≦0.4, 0.1≦b≦0.4, 0.4≦(1-a-b)≦0.9), x+y is about 2 and 0.95≦x≦1.15.
2. The cathode active material according to claim 1 , wherein the lithium nickel-manganese-cobalt oxide has an average particle diameter D50 of not more than 8μm.
3. The cathode active material according to claim 1 , wherein the lithium nickel-manganese-cobalt oxide comprises an aggregate of microfine particles having an average particle diameter D90 of 0.01 to 5 μm.
4. The cathode active material according to claim 1 , wherein the conductive carbon is at least one selected from a group consisting of natural graphite, artificial graphite, carbon black, acetylene black, ketchen black, furnace black, lamp black, summer black and carbon fiber.
5. The cathode active material according to claim 1 , wherein the conductive carbon has a particle diameter of 0.01 to 1 μm.
6. The cathode active material according to claim 1 , wherein the ion-conductive solid compound is at least one selected from a group consisting of lithium phosphate, lithium sulfide and lithium lanthanum titanate.
7. The cathode active material according to claim 1 , wherein a content ratio of conductive carbon to ion-conductive solid compound ranges from 90:10 to 10:90% by weight.
8. The cathode active material according to claim 1 , wherein the ion-conductive solid compound and the conductive carbon are present as a thorough or partial coating on a surface of the particles.
9. The cathode active material according to claim 1 , wherein 20 to 80% of an overall surface of the lithium nickel-manganese-cobalt oxide is coated with the ion-conductive solid compound and the conductive carbon.
10. The cathode active material according to claim 1 , wherein a coating amount ranges from 0.5 to 10% by weight relative to a total weight of the active material.
11. The cathode active material according to claim 1 , wherein the ion-conductive solid compound and the conductive carbon are present in the coating in independent phases.
12. The cathode active material according to claim 1 , wherein the ion-conductive solid compound and the conductive carbon are present in the coating in a composite form such that the conductive carbon is entrapped inside the ion-conductive solid compound.
13. A lithium secondary battery including the cathode active material as set forth in claim 1 .
14. The lithium secondary battery according to claim 13 , wherein the lithium secondary battery is used as a power supply for a power tool, an electric vehicle, an electric two-wheel vehicle and/or an electric golf cart.
15. A cathode composition, comprising:
the cathode active material as set forth in claim 1 ;
a conductive material; and
a binder.