Biodegradable blends and films having nano-structural features
View Patent ↗A thermoplastic polymer composition with a tertiary blend of a carbon dioxide-derived polymer, a thermoplastic cellulose derivative, and a thermoplastic compatibilizer is described. The composition can be melt-processed into flexible, thin films that have fine nano-scale structural features in both the cross-directional and machine-directional orientations, for use in various products. The films, which are made from relatively brittle materials, exhibit a greater degree of ductility, elongation capacity, and strength than the primary, original component materials as binary-blends from which the film is made.
1. A flexible thermoplastic film comprising:
a tertiary blend of 1) about 1 wt. % to about 95 wt. % of a polyalkylene carbonate and 2) about 95 wt. % to about 1 wt. % of a thermoplastic cellulose derivative, respectively forming a either a major or minor component of said film, and 3) 5 wt. % to 17 wt. % of a polyhydroxyalkanoate (PHA) compatibilizer; wherein said film exhibits nanostructural features that are at least ⅓ to 1/10 of the size of corresponding structural morphology in a film formed from a binary blend of a precursor thermoplastic material of said polyalkylene carbonate and said thermoplastic cellulose derivative, absent said polyhydroxyalkanoate (PHA) compatibilizer, wherein said nanostructure features have a nano-dispersed fiber morphology and form one of two phases composed of either said polyalkylene carbonate or said thermoplastic cellulose derivative, whichever one of the two is present as a minority species in said majority component, wherein said film exhibits an elongation percent-at-break value that is increased by at least 150% to about 500% of a film formed from a binary blend of a polyalkylene carbonate and a thermoplastic cellulose derivative absent said polyhydroxyalkanoate (PHA) compatibilizer.
2. The film according to claim 1 , wherein said nanostructural features are evenly distributed like islands-in-a-sea throughout a material body of said film.
3. The film according to claim 1 , wherein said film exhibits an islands-in-a-sea type morphology of nanostructural features of polyalkylene carbonate dispersed in a matrix of thermoplastic cellulose derivative material, when said polyalkylene carbonate is a minority species; wherein said nanostructural features have an average length dimension from about ⅛ to about ¾ of a micrometer.
4. The film according to claim 1 , wherein said film exhibits an elongation percent-at-break value increase of about 150% to about 700% relative to a film formed from said binary blend in a machine-direction orientation.
5. The film according to claim 1 , wherein said film exhibits an elongation percent-at-break value increase of about 200% to about 500% relative to a film formed from said binary blend along a cross-direction orientation.
6. The film according to claim 1 , wherein said tertiary blend film exhibits an energy-at-break improvement of about 200% to about 800% relative to said binary blend film.
7. An absorbent article or health care product comprising the film of claim 1 .
8. The absorbent article according to claim 7 , wherein said film is part of an inner baffle or an outer cover.
9. The absorbent article according to claim 7 , wherein said article is a personal hygiene product, a feminine care product, a diaper, a training pant, or an adult incontinence product.
10. A packaging film comprising the film according to claim 1 .
11. The film according to claim 1 , wherein said film exhibits an islands-in-a-sea type morphology of nanostructural features of thermoplastic cellulose derivative dispersed in a matrix of polyalkylene carbonate material, when said thermoplastic cellulose derivative is a minority species; wherein said nanostructural features have an average length dimension from about ⅛ to about ¾ of a micrometer.
12. The film according to claim 1 , wherein said film exhibits a modulus in the machine direction ranging from 1100 megapascals to 1400 megapascals and exhibits a modulus in the cross direction ranging from 875 megapascals to 1200 megapascals.