Garnet material, method for its manufacturing and radiation-emitting component comprising the garnet material
A material, comprising a garnet having the composition represented by the formula A 3-x B 5 O 12 :D x and a barium-containing oxide. In the garnet A 3-x B 5 O 12 :D x , A is selected from lutetium, yttrium, gadolinium, terbium, scandium, another rare earth metal or mixtures thereof. B is selected from aluminum, scandium, gallium, indium, boron or mixtures thereof. D is at least one dopant selected from chromium, manganese and rare earth metals, particularly cerium, praseodymium or gadolinium. The dopant is present with x is 0≦x≦2.
1. A ceramic material, comprising a garnet having the composition represented by the formula A 3-x B 5 O 12 :D x and a barium-aluminum oxide of the formula Ba z Al 2y O z+3y , wherein in the garnet A 3-x B 5 O 12 :D x :
A is selected from lutetium, yttrium, gadolinium, terbium, scandium, another rare earth metal or mixtures thereof,
B is selected from aluminum, scandium, gallium, indium, boron or mixtures thereof,
D is at least one dopant selected from chromium, manganese and rare earth metals, and
0≦x≦2,
wherein in the barium aluminum oxide Ba z Al 2y O z+3y , z and y are integers >0, and wherein in the ceramic material, the amount of barium is 0.01 to 2.5 wt % and the garnet material shows a porosity of 0.001 to 0.1 vol % of the entire volume of the material, and
wherein the barium aluminium oxide is present as separate phases different from the phase of the A 3-x B 5 O 12 :D x and wherein at least 99 wt % of the total amount of barium is present in the separate phases.
2. The ceramic material according to claim 1 , wherein in the garnet A 3-x B 5 O 12 :D x
A is selected from lutetium, yttrium, gadolinium, terbium, scandium or a mixture thereof,
B is selected from aluminum or a mixture of aluminum and gallium or scandium,
D is selected from cerium, praseodymium or mixtures thereof, and
x is 0<x≦0.15.
3. The ceramic material according to claim 1 , wherein at least a part of the barium aluminum oxide forms a separate phase.
4. The ceramic material according to claim 1 , wherein the material comprises an amount of at least one additional metal oxide, wherein the at least one additional metal oxide is selected from oxides of calcium, magnesium, strontium, boron, silicon, zirconium, aluminum, scandium or mixtures thereof.
5. The ceramic material according to claim 1 , wherein the material is transparent, and the total forward transmittance at a wavelength of 2000 nm is at least 66%.
6. The ceramic material according to claim 1 , wherein the material absorbs light with a wavelength of 400 to 490 nm, and wherein the material emits light with a wavelength of 460 to 700 nm.
7. The ceramic material according to claim 1 , having a luminous efficacy of better than 290 lm/W.
8. A method of manufacturing the material according to claim 1 , comprising the steps of:
forming a slurry from a starting material comprising a sintering aid, an organic binder and starting material for the garnet, wherein the sintering aid comprises BaAl 2 O 4 and/or BaAl 12 O 19 ;
forming a green body from the slurry;
prefiring the green body; and
sintering of the prefired green body.
9. The method according to claim 8 , wherein the prefiring is performed at 800° C. to 1400° C., and wherein the sintering is performed at 1650° C. to 1900° C.
10. A radiation-emitting component comprising a converter chip or a converter plate formed from a green body tape which consists of a ceramic material, comprising a garnet having the composition represented by the formula A 3-x B 5 O 12 :D x and a barium aluminum oxide of the formula Ba z Al 2y O z+3y , wherein in the garnet A 3-x B 5 O 12 :D x :
A is selected from lutetium, yttrium, gadolinium, terbium, scandium, another rare earth metal or mixtures thereof,
B is selected from aluminum, scandium, gallium, indium, boron, or mixtures thereof,
D is at least one dopant selected from chromium, manganese, and rare earth metals, and 0<x≦2,
wherein in the barium aluminum oxide Ba z Al 2y O z+3y , z and y are integers >0, and wherein in the ceramic material, the amount of barium is 0.01 to 2.5 wt % and the garnet material shows a porosity of 0.001 to 0.1 vol % of the entire volume of the ceramic material wherein the barium aluminium oxide is present as separate phases different from the phase of the A 3-x B 5 O 12 :D x , at least 99 wt % of the total amount of barium is present in the separate phases, and the ceramic material converts at least partially a primary radiation of a first wavelength in a secondary radiation of a second wavelength that is longer than the first wavelength.
11. The radiation-emitting component according to claim 10 , wherein the maximum of the primary radiation is between 420 to 470 nm, and wherein the maximum of the secondary radiation is between 500 to 580 nm.
12. The method according to claim 9 , wherein the prefiring is performed at 1050° C. to 1250° C., and wherein the sintering is performed at 1700° C. to 1800° C.
13. The ceramic material according to claim 1 , wherein D is at least one dopant selected from cerium, praseodymium or gadolinium.
14. The ceramic material according to claim 2 , wherein x is 0<x≦0.07.
15. The ceramic material according to claim 1 , wherein in the material the amount of barium is 0.04 to 1.5 wt %.
16. The ceramic material according to claim 3 , wherein at least a part of the barium aluminum oxide forms a separate phase of BaAl 2 O 4 or BaAl 12 O 19 .
17. The ceramic material according to claim 5 , wherein the total forward transmittance at a wavelength of 2000 nm is at least 71%.
18. The ceramic material according to claim 17 , wherein the total forward transmittance at a wavelength of 2000 nm is higher than 75%.
19. The ceramic material according to claim 6 , wherein the material absorbs light with a wavelength maximum of 420 to 470 nm, and wherein the material emits light with a wavelength maximum of 500 to 580 nm.
20. The ceramic material according to claim 7 , having a luminous efficacy higher than 295 lm/W.
21. The radiation-emitting component according to claim 10 , wherein the converter chip has a size of 1 mm*1 mm.
22. The radiation-emitting component according to claim 21 , wherein the converter chip has a thickness of 90 μm, 100 μm, 120 μm, or 130 μm.
23. A ceramic material, comprising a garnet having the composition represented by the formula A 3-x B 5 O 12 :D x and a barium-aluminum oxide of the formula Ba z Al 2y O z+3y , wherein in the garnet A 3-x B 5 O 12 :D x :
A is selected from lutetium, yttrium, gadolinium, terbium, scandium, another rare earth metal or mixtures thereof,
B is selected from aluminum, scandium, gallium, indium, boron or mixtures thereof,
D is at least one dopant selected from chromium, manganese and rare earth metals, and
0≦x≦2,
in the barium aluminum oxide Ba z Al 2y O z+3y , z and y are integers >0,
in the ceramic material, the amount of barium is 0.01 to 2.5 wt %,
the garnet material shows a porosity of 0.001 to 1 vol % of the entire volume of the material,
the barium aluminium oxide is present as separate phases different from the phase of the A 3-x B 5 O 12 :D x and at least 99 wt % of the total amount of barium is present in the separate phases,
the grain size of the garnet is 10 to 20 μm,
over 95% of the barium containing phases have a diameter smaller than 5 μm, and
the ceramic material is transparent, and the total forward transmittance at a wavelength of 2000 nm is at least 66%.