Polyamide/poly(arylene ether) composition, article, and method
View Patent ↗A polyamide-poly(arylene ether) composition is prepared by melt blending specific amounts of components including a polyamide, a poly(arylene ether), a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene, a compatibilizing agent, and partially saponified ester of a C 16 -C 36 aliphatic carboxylic acid and a C 2 -C 12 aliphatic alcohol. The composition is useful for molding articles that have a significantly reduced incidence of the cosmetic defect known as “silver streaks”.
1. A compatibilized polyamide-poly(arylene ether) composition, comprising the product of melt blending components comprising:
about 40 to about 75 weight percent of a polyamide;
about 25 to about 55 weight percent of a poly(arylene ether);
about 2 to about 10 weight percent of a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene;
about 0.2 to about 2 weight percent of a compatibilizing agent; and
about 0.1 to about 1 weight percent of a partially saponified ester of a C 16 -C 36 aliphatic carboxylic acid and a C 2 -C 12 aliphatic alcohol;
wherein all weight percents are based on the total weight of the compatibilized polyamide-poly(arylene ether) composition; and
wherein the composition excludes filler.
2. The compatibilized polyamide-poly(arylene ether) composition of claim 1 , wherein the C 16 -C 36 aliphatic carboxylic acid comprises a C 16 -C 24 aliphatic carboxylic acid.
3. The compatibilized polyamide-poly(arylene ether) composition of claim 1 , wherein the C 16 -C 36 aliphatic carboxylic acid comprises stearic acid.
4. The compatibilized polyamide-poly(arylene ether) composition of claim 1 , wherein the C 16 -C 36 aliphatic carboxylic acid comprises a C 24 -C 36 aliphatic carboxylic acid.
5. The compatibilized polyamide-poly(arylene ether) composition of claim 1 , wherein the C 16 -C 36 aliphatic carboxylic acid comprises montanic acid.
6. The compatibilized polyamide-poly(arylene ether) composition of claim 1 , wherein the C 2 -C 12 aliphatic alcohol comprises a C 2 -C 12 aliphatic diol.
7. The compatibilized polyamide-poly(arylene ether) composition of claim 1 , wherein the C 2 -C 12 aliphatic alcohol is selected from the group consisting of ethylene glycol, 1-methyl-1,3-propanediol, and mixtures thereof.
8. The compatibilized polyamide-poly(arylene ether) composition of claim 1 , wherein the partially saponified ester comprises a fatty acid salt selected from the group consisting of a calcium salt of the C 16 -C 36 aliphatic carboxylic acid, a sodium salt of the C 16 -C 36 aliphatic carboxylic acid, a potassium salt of the C 16 -C 36 aliphatic carboxylic acid, a zinc salt of the C 16 -C 36 aliphatic carboxylic acid, a magnesium salt of the C 16 -C 36 aliphatic carboxylic acid, an aluminum salt of the C 16 -C 36 aliphatic carboxylic acid, and combinations thereof.
9. The compatibilized polyamide-poly(arylene ether) composition of claim 8 , wherein the partially saponified ester comprises about 5 to about 60 weight percent of the fatty acid salt, based on the weight of the partially saponified ester.
10. The compatibilized polyamide-poly(arylene ether) composition of claim 1 , wherein thermogravimetric analysis of the partially saponified ester in air over a temperature range of 25 to 700° C. yields a residue of about 1 to about 6 weight percent, based on the initial weight of the partially saponified ester.
11. The compatibilized polyamide-poly(arylene ether) composition of claim 1 , wherein the polyamide has an amine end group concentration of about 40 to about 70 microequivalents per gram and a relative viscosity of about 30 to about 60.
12. The compatibilized polyamide-poly(arylene ether) composition of claim 1 , wherein the hydrogenated block copolymer has an alkenyl aromatic content of about 20 to about 40 weight percent, based on the weight of the hydrogenated block copolymer.
13. The compatibilized polyamide-poly(arylene ether) composition of claim 1 ,
wherein the composition is the product of melt blending components comprising
about 55 to about 65 weight percent of the polyamide;
about 25 to about 35 weight percent of the poly(arylene ether);
about 4 to about 8 weight percent of the hydrogenated block copolymer;
about 0.4 to about 1 weight percent of the compatibilizing agent; and
about 0.2 to about 0.4 weight percent of the partially saponified ester;
wherein the polyamide comprises polyamide-6,6;
wherein the poly(arylene ether) comprises poly(2,6-dimethyl-1,4-phenylene ether);
wherein the hydrogenated block copolymer comprises a polystyrene-poly(ethylene-butylene)-polystyrene having a polystyrene content of about 20 to about 40 weight percent, based on the weight of the polystyrene-poly(ethylene-butylene)-polystyrene;
wherein the compatibilizing agent comprises citric acid;
wherein the C 16 -C 36 aliphatic carboxylic acid comprises montanic acid;
wherein the C 2 -C 12 aliphatic alcohol is selected from the group consisting of ethylene glycol, 1-methyl-1,3-propanediol, and mixtures thereof; and
wherein the partially saponified ester comprises a calcium salt of the C 16 -C 36 aliphatic carboxylic acid.
14. A compatibilized polyamide-poly(arylene ether) composition, obtainable by a process comprising melt blending:
about 40 to about 75 weight percent of a polyamide;
about 25 to about 55 weight percent of a poly(arylene ether);
about 2 to about 10 weight percent of a hydrogenated block copolymer;
about 0.2 to about 2 weight percent of a compatibilizing agent; and
about 0.1 to about 0.5 weight percent of a partially saponified ester of a C 16 -C 36 aliphatic carboxylic acid and a C 2 -C 12 aliphatic alcohol;
wherein all weight percents are based on the total weight of the compatibilized polyamide-poly(arylene ether) composition; and
wherein the composition excludes filler.
15. An article comprising the compatibilized polyamide-poly(arylene ether) composition of claim 1 .
16. An automotive under-the-hood component comprising the compatibilized polyamide-poly(arylene ether) composition of claim 11 .
17. A method of reducing cosmetic imperfections in a surface of an injection molded article comprising a compatibilized polyamide-poly(arylene ether) composition, the method comprising:
injection molding a compatibilized polyamide-poly(arylene ether) composition to form an injection molded article; wherein the compatibilized polyamide-poly(arylene ether) composition is the product of melt blending components comprising
about 40 to about 75 weight percent of a polyamide;
about 25 to about 55 weight percent of a poly(arylene ether);
about 2 to about 10 weight percent of a hydrogenated block copolymer of an alkenyl aromatic monomer and a conjugated diene;
about 0.2 to about 2 weight percent of a compatibilizing agent; and
about 0.1 to about 1 weight percent of a partially saponified ester of a
C 16 -C 36 aliphatic carboxylic acid and a C 2 -C 12 aliphatic alcohol;
wherein all weight percents are based on the total weight of the compatibilized polyamide-poly(arylene ether) composition; and wherein the composition excludes filler.
18. The method of claim 17 , wherein the polyamide has an amine end group concentration of about 40 to about 70 microequivalents per gram and a relative viscosity of about 30 to about 60.
19. The method of claim 17 , wherein the hydrogenated block copolymer has an alkenyl aromatic content of about 20 to about 40 weight percent, based on the weight of the hydrogenated block copolymer.
20. The method of claim 17 ,
wherein the composition is the product of melt blending components comprising
about 55 to about 65 weight percent of the polyamide;
about 25 to about 35 weight percent of the poly(arylene ether);
about 4 to about 8 weight percent of the hydrogenated block copolymer;
about 0.4 to about 1 weight percent of the compatibilizing agent; and
about 0.2 to about 0.4 weight percent of the partially saponified ester;
wherein the polyamide comprises polyamide-6,6;
wherein the poly(arylene ether) comprises poly(2,6-dimethyl-1,4-phenylene ether);
wherein the hydrogenated block copolymer comprises a polystyrene-poly(ethylene-butylene)-polystyrene having a polystyrene content of about 20 to about 40 weight percent, based on the weight of the polystyrene-poly(ethylene-butylene)-polystyrene;
wherein the compatibilizing agent comprises citric acid;
wherein the C 16 -C 36 aliphatic carboxylic acid comprises montanic acid;
wherein the C 2 -C 12 aliphatic alcohol is selected from the group consisting of ethylene glycol, 1-methyl-1,3-propanediol, and mixtures thereof; and
wherein the partially saponified ester comprises a calcium salt of the C 16 -C 36 aliphatic carboxylic acid.