Sintered compact
View Patent ↗A sintered cubic boron nitride (cBN) compact for use in a tool is obtained by sintering a mixture of (i) cubic boron nitride, (ii) aluminum oxide, (iii) one or more refractory metal compounds, and (iv) aluminum and/or one or more non-oxide aluminum compounds. The sintered bodies may have sufficient strength and toughness to be used as a tool material in solid, i.e. not carbide supported, form, and may be useful in heavy machining of cast irons.
1. A compact with a cubic boron nitride (cBN) portion and a non cBN portion, the compact comprising:
(a) between about 71 and about 93 volume-% cBN;
(b) between about 1 and less than about 20 volume-% of aluminum oxide;
(c) between about 3 and about 26 volume-% of one or more refractory metal compounds selected from the group consisting of:
i. a compound having the general formula MZ (1-x) ;
ii. a compound having the general formula MC (1-x) N x ; and
iii. a combination or solid solutions of two or more compounds each having the general formula MZ or MZ 2 ; wherein:
Z is selected from the group consisting of C, B, N and combination thereof, M is a metal from any of groups IV-VI of the periodic table, and x is a number between 0.01 and 0.99; and
(d) between greater than 6 and about 20 volume-% of a source of one or more non-oxide aluminum compounds;
wherein the total aluminum content in the non cBN portion of the sintered compact exceeds about 30 weight-% and wherein the total tungsten content is greater than 0 and less than 1 weight-%.
2. The compact of claim 1 , wherein the one or more refractory metal compounds comprise at least one of TiC (1-x) N x , or a mixture of at least two materials selected from the group of TiC, TiN, TiB 2 , TiN (1-x) and TiC (1-x) N x , wherein x is a number between 0.01 and 0.99.
3. The compact of claim 1 , wherein the cBN has a grain size distribution that is at least bimodal.
4. The compact of claim 3 , wherein the grain size distribution comprises:
i) about 20 to about 40 volume % of about 1 to about 3 micron-sized particles;
ii) about 10 to about 30 volume % of about 4 to about 6 micron-sized particles;
iii) about 10 to about 30 volume % of about 7 to about 9 micron-sized particles; and
iv) about 20 to about 40 volume % of about 10 to about 20 micron-sized particles.
5. The compact of claim 3 , having a coarse portion comprising about 40% to about 80% of the cBN and a fine portion comprising about 20 to about 60% of the cBN;
wherein the coarse portion has an average grain size of about 5 to about 30 μm and the fine portion has an average grain size of about 0 to about 10 μm; and
wherein the ratio of the average grain size of the coarse portion to the average grain size of the fine portion is about 2:1 or greater.
6. The compact of claim 1 , wherein the compact is in an unsupported form.
7. The compact of claim 1 , wherein at least a portion of aluminum that forms the one or more non-oxide aluminum compounds originates from a foil or other solid form of metallic aluminum placed in contact with a powder mixture during sintering.
8. A compact with a cubic boron nitride (cBN) portion and a non cBN portion, the compact comprising:
(a) between about 50 and about 93 weight-% of cBN with at least a bimodal grain size distribution;
(b) between about 1 and about 30 weight-% of aluminum oxide;
(c) between about 3 and about 46 weight-% of one or more compounds selected from the group consisting of carbides, nitrides, borides, and carbonitrides, all of groups IV-VI of the periodic table, and mixtures and solid solutions thereof; and
(d) between greater than 3 and about 30 weight-% of one or more non-oxide aluminum compounds;
wherein the total aluminum content in the non cBN portion of the sintered compact exceeds about 10 weight-% of the compact and wherein the total tungsten content is greater than 0 and less than 1 weight-%.
9. The compact of claim 8 , wherein the one or more compounds selected from the group consisting of carbides, nitrides, borides, and carbonitrides, are carbonitrides of the formula TiC (1-x) N x , or a mixture of at least two materials selected from the group of TiC, TiN, TiB 2 , TiN (1-x) and TiC (1-x) N x , wherein x is any value between 0.01 and 0.99.
10. The compact of claim 8 , further comprising:
a coarse portion of about 40% to about 80% of the cBN; and
a fine portion of about 20 to about 60% of the cBN;
wherein the coarse portion has an average grain size of about 5 to about 30 μm;
wherein the fine portion has an average grain size of about 0 to about 10 μm; and
wherein the ratio of the average grain size of the coarse portion to the average grain size of the fine portion is about 2:1 or greater.
11. The compact of claim 8 , wherein the compact is in an unsupported form.
12. The compact of claim 8 , wherein at least a portion of aluminum that forms non-oxide aluminum compounds originates from a foil or other solid form of metallic aluminum placed in contact with the powder mixture during sintering.
13. A compact with a cubic boron nitride (cBN) portion and a non cBN portion, the compact comprising:
(a) between about 71 and about 93 volume-% cBN, wherein the cBN has a grain size distribution comprising:
i) about 20 to about 40 volume % of about 1 to about 3 micron-sized particles;
ii) about 10 to about 30 volume % of about 4 to about 6 micron-sized particles;
iii) about 10 to about 30 volume % of about 7 to about 9 micron-sized particles; and
iv) about 20 to about 40 volume % of about 10 to about 20 micron-sized particles;
(b) between about 1 and less than about 20 volume-% of aluminum oxide;
(c) between about 3 and about 26 volume-% of one or more refractory metal compounds selected from the group consisting of:
i. a compound having the general formula MZ (1-x) ;
ii. a compound having the general formula MC (1-x) N x ; and
iii. a combination or solid solutions of two or more compounds each having the general formula MZ or MZ 2 ; wherein:
Z is selected from the group consisting of C, B, N and combination thereof, M is a metal from any of groups IV-VI of the periodic table, and x is a number between 0.01 and 0.99; and
(d) between greater than 3 and about 20 volume-% of a source of one or more non-oxide aluminum compounds;
wherein the total aluminum content in the non cBN portion of the sintered compact exceeds about 30 weight-% and wherein the total tungsten content is less than about 3 weight-%.
14. A compact with a cubic boron nitride (cBN) portion and a non cBN portion, the compact comprising:
(a) between about 71 and about 93 volume-% cBN, wherein the cBN has a grain size distribution comprising:
i) about 20 to about 40 volume % of about 1 to about 3 micron-sized particles;
ii) about 10 to about 30 volume % of about 4 to about 6 micron-sized particles;
iii) about 10 to about 30 volume % of about 7 to about 9 micron-sized particles; and
iv) about 20 to about 40 volume % of about 10 to about 20 micron-sized particles;
(b) between about 1 and less than about 20 volume-% of aluminum oxide;
(c) between about 3 and about 26 volume-% of one or more refractory metal compounds selected from the group consisting of:
i. a compound having the general formula MZ (1-x) ;
ii. a compound having the general formula MC (1-x) N x ; and
iii. a combination or solid solutions of two or more compounds each having the general formula MZ or MZ 2 ; wherein:
Z is selected from the group consisting of C, B, N and combination thereof, M is a metal from any of groups IV-VI of the periodic table, and x is a number between 0.01 and 0.99; and
(d) between greater than 3 and about 20 volume-% of a source of one or more non-oxide aluminum compounds;
wherein the total aluminum content in the non cBN portion of the sintered compact exceeds about 30 weight-%.