Ink composition, inkjet recording method, printed material, method for producing planographic printing plate, and planographic printing plate
View Patent ↗The invention provides an ink composition having at least (A) a polymerization initiator, (B) an ester or amide of (meth)acrylic acid having a 1,3-dioxolane ring skeleton or a 1,3-dioxane ring skeleton or (B′) an ester or amide of (meth)acrylic acid having a 1,3-diketone structure, and (C) a colorant. The invention further provides an inkjet recording method and a method for producing a planographic printing plate, each of which includes at least (I) ejecting the ink composition onto a hydrophilic support and (II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support. The invention furthermore provides a planographic printing plate formed by the method for producing a planographic printing plate.
1. An inkjet recording composition comprising an ultraviolet ray-curable ink composition, the ultraviolet ray-curable ink composition comprising:
(a) a polymerization initiator;
(b) an ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton;
(c) a colorant; and
(d) a polymerizable compound which is other than the ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton,
wherein the ultraviolet ray-curable ink composition further comprises a polymerization inhibitor,
the ultraviolet ray-curable ink composition contains no solvent or a solvent in an amount of 0.1 to 3% by weight with respect to the total weight of the ultraviolet ray-curable ink composition,
the ink viscosity is from 7 to 25 mPa·s at the temperature at the time of ejection,
the colorant is a pigment dispersed in the ultraviolet ray-curable ink composition with a dispersant,
the ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is represented by the following structural formula (B-14):
and
the polymerizable compound which is other than the ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is a combination of a monoacrylate and either a polyfunctional acrylate monomer or oligomer having a molecular weight of 400 or more.
2. The inkjet recording composition according to claim 1 , wherein the content of the ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is 7% by mass or more on the basis of a total amount of polymerizable compounds.
3. The inkjet recording composition according to claim 1 , wherein the viscosity at 25 to 30° C. of the ink composition is from 35 to 200 mPa·s.
4. The inkjet recording composition according to claim 1 , wherein the polymerization initiator comprises at least 2,4,6-Trimethylbenzoyldiphenylphosphine oxide.
5. The inkjet recording composition according to claim 1 , wherein the polymerization initiator is present in a range of from 0.5 to 30% by mass on the basis of a total amount of polymerizable compounds.
6. The inkjet recording composition according to claim 1 , wherein the ultraviolet ray-curable ink composition has a surface tension of from 20 to 30 mN/m.
7. The inkjet recording composition according to claim 1 , wherein the polymerization initiator comprises an aromatic ketone.
8. The inkjet recording composition according to claim 1 , wherein the ultraviolet ray-curable ink composition further comprises a sensitizing dye.
9. The inkjet recording composition according to claim 1 , wherein the temperature at the time of ejection is 40 to 80° C.