Nylon resins and process
The disclosures herein relate to a polymer such as nylon 66, having low yellowness and excellent whiteness retention for applications in melt extrusion and injection molding where an increase in molecular weight is not desirable. The polymer is prepared with a phosphorus compound content, e.g., a sodium hypophosphite (SHP) content, in an amount of 150 to 300 ppm by weight. The presence of an “end cap” additive such as one selected from acetic acid, propionic acid, benzoic acid, or succinic acid, added at the start of polymerization, effectively mitigates undesired molecular weight gain.
1. A modified polyamide formed from a solution consisting of at least one polyamide-forming reactant, wherein a first additive and a second additive were introduced into the solution before or during polymerization, or after polymerization into a polyamide melt; and
wherein the first additive is provided in an amount sufficient to yield about 150 to about 300 parts per million by weight of the polyamide; and
wherein the second additive is provided in an amount sufficient to yield about 10 to about 50 moles per million grams of the polyamide; and
wherein the first additive is sodium hypophosphite; and
wherein the second additive is selected from the group consisting of: acetic acid, propionic acid, benzoic acid, and succinic acid.
2. The modified polyamide of claim 1 wherein the second additive is provided in an amount sufficient to yield about 10 to about 17 moles per million grams of the polyamide.
3. The modified polyamide of claim 1 comprising polyhexamethylene adipamide.
4. A process for providing a nylon polymer injection molding resin in fluid state to the mold cavity of an injection molding machine, the process consisting of:
a. providing a nylon polymer molding resin containing at least a portion of at least one phosphorus-based polymerization catalyst and at least a portion of at least one lower carboxylic acid end-capping additive, wherein the one phosphorus-based polymerization catalyst is provided in an amount sufficient to yield about 150 to about 300 parts per million by weight of the nylon polymer molding resin, and wherin the one lower carboxylic acid end-capping additive is provided in an amount sufficient to yield about 10 to about 50 moles per million grams of the nylon polymer molding resin;
b. melting the resin by the addition of sufficient heat effect a solid to fluid state transition; and
c. transporting the resin in a fluid state to the mold cavity of an injection molding machine.
5. The process of claim 4 wherein the molding resin is selected from nylon-6,6 resins and wherein the at least one polymerization catalyst is selected from polyamidation catalysts and the at least one end-capping additive is selected from lower mono- and dicarboxylic acids.
6. The process of claim 4 wherein the at least one polymerization catalyst is sodium hypophosphite and the at least one end-capping additive is selected from the group consisting of: acetic acid, propionic acid, benzoic acid, and succinic acid.
7. A process for providing a nylon injection molding resin in fluid state to the mold cavity of an injection molding machine, the process consisting of:
a. providing the nylon resin having a first relative viscosity (RV) measurement and a water content of less than 0.15% by weight and further containing at least a portion of at least one phosphorus-based polyamidation catalyst and at least a portion of at least one lower carboxylic acid end-capping additive, wherein the one phosphorus-based polymerization catalyst is provided in an amount sufficient to yield about 150 to about 300 parts per million by weight of the nylon polymer molding resin, and wherin the one lower carboxylic acid end-capping additive is provided in an amount sufficient to yield about 10 to about 50 moles per million grams of the nylon polymer molding resin;
b. melting the nylon resin by the addition of sufficient heat effect a solid to fluid state transition, wherein the fluid state nylon resin is characterized by a second relative viscosity (RV) increased by less than about 16 RV units from the first relative viscosity (RV) measurements; and
c. transporting the nylon resin in a fluid state to the mold cavity of an injection molding machine.
8. The process of claim 7 wherein the nylon resin having a first relative viscosity (RV) has a water content of less than 0.10% by weight and wherein the fluid state nylon resin is characterized by a second relative viscosity (RV) increased by less than about 10 RV units from the first relative viscosity (RV) measurement.
9. The process of claim 7 wherein the at least one polymerization catalyst is selected from polyamidation catalysts and the at least one end-capping additive is selected from monocarboxylic acids.
10. The process of claim 7 wherein the at least one polymerization catalyst is sodium hypophosphite and the at least one end-capping additive is selected from the group consisting of: acetic acid, propionic acid, benzoic acid, and succinic acid.