Powdery composition of a polymer and a flameproofing agent containing ammonium polyphosphate, method for the production thereof, and moulded body produced from said powder
View Patent ↗A pulverulent composition that is a powder containing at least one polymer, and at least one flame retardant that contains ammonium polyphosphate, the powder having a maximum particle size of ≦150 μm and a median particle size of from 20 to 100 μm.
1. A pulverulent composition, wherein the pulverulent composition is a powder comprising: at least one polymer, and at least one flame retardant that comprises ammonium polyphosphate wherein the powder has a maximum particle size of ≦150 μm and wherein the powder has a median particle size of from 20 to 100 μm, wherein the at least one polymer is at least a polyamide.
2. The pulverulent composition as claimed in claim 1 , wherein the polymer is prepared by at least one of milling, precipitation, anionic polymerization, or by a combination of these, or by subsequent fractionation.
3. The pulverulent composition as claimed in claim 1 , wherein said powder further comprises at least one polymer selected from the group consisting of polyester, polyvinyl chloride, polyacetal, polypropylene, polyethylene, polystyrene, polycarbonate, poly-(N-methylmethacrylimides) (PMMI), polymethyl methacrylate (PMMA), ionomer, copolyester, terpolymers, and acrylonitrile-butadiene-styrene copolymers (ABS), or a copolymer comprising at least two polymers selected from the group consisting of polyester, polyvinyl chloride, polyacetal, polypropylene, polyethylene, polystyrene, polycarbonate, poly-(N-methylmethacrylimides) (PMMI), polymethyl methacrylate (PMMA), ionomer, copolyester, terpolymers, and acrylonitrile-butadiene-styrene copolymers (ABS).
4. The pulverulent composition as claimed in claim 1 , wherein the polymer is polyamide-6,12, polyamide-11, polyamide-12, or a copolymer of these polyamides.
5. The pulverulent composition as claimed in claim 1 , wherein the polymer has a melting point of from 50 to 350° C.
6. The pulverulent composition as claimed in claim 5 , wherein the polymer has a melting point of from 70 to 200° C.
7. The pulverulent composition as claimed in claim 1 , further comprising at least one auxiliary, filler, or pigment.
8. The pulverulent composition as claimed in claim 7 , which comprises a flow aid as an auxiliary.
9. The pulverulent composition as claimed in claim 1 , wherein the ammonium polyphosphate contains from 10 to 35% by weight of phosphorus.
10. The pulverulent composition as claimed in claim 1 , wherein the flame retardant component comprises a synergist with the ammonium polyphosphate.
11. The pulverulent composition as claimed in claim 1 , wherein the flame retardant component is in a pulverulent form with a median particle size of from 1 to 50 μm.
12. The pulverulent composition as claimed in claim 1 , wherein the flame retardant component is in a pulverulent and a coated form.
13. A method for producing moldings by a layer-by-layer process which selectively bonds the powder, the method comprising: adding the pulverulent composition of claim 1 to a molding mixture.
14. The method of claim 13 , wherein the moldings are produced by selective laser sintering, selective inhibition of the bonding of powders, 3D printing, or a microwave process.
15. A molding, produced by a process for the layer-by-layer build-up of three-dimensional objects by selectively bonding portions of a powder to one another, the molding comprising: at least one flame retardant that comprises ammonium polyphosphate, and at least one polymer, wherein the powder has a maximum particle size of ≦150 μm and wherein the powder has a median particle size of from 20 to 100 μm, wherein the at least one polymer is at least a polyamide.
16. The molding as claimed in claim 15 , wherein said polyamide contains at least 8 carbon atoms per carboxamide group.
17. The molding as claimed in claim 15 , wherein the polymer is polyamide-6,12, polyamide-11, polyamide-12, or a copolymer of these polyamides.
18. The molding as claimed in claim 15 , wherein the flame retardant is present in an amount of from 5 to 50% by weight, based on the total amount of components present, and wherein the flame retardant comprises ammonium polyphosphate.
19. The molding as claimed in claim 15 , which, wherein the flame retardant is present in an amount of from 30 to 35% by weight, based on the total amount of the polymers present, and wherein the flame retardant comprises ammonium polyphosphate.
20. The molding as claimed in claim 15 , further comprising fillers and/or pigments.