IP Library Granted Patent US 8,431,193
Granted Patent B2
US 8,431,193 · App. 12/855,135 · Granted Apr 30, 2013

Inkjet recording medium

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Quick Facts
Patent No.
US 8,431,193
App. No.
12/855,135
Granted
Apr 30, 2013
Kind
B2
Abstract

An inkjet recording medium and a coating composition for forming an inkjet recording medium. In accordance with one aspect of the present invention, an inkjet recording medium is disclosed comprising an inkjet-receptive coating on a paper substrate. The inkjet-receptive coating contains a synergistic combination of pigments and binder such that the inkjet recording medium exhibits improved inkjet print properties, particularly when printed with a high speed inkjet printer using pigmented inks. In accordance with certain aspects of the present invention, the inkjet recording medium further comprises a top coat of a multivalent metal salt which further enhances image quality of the inkjet printing.

Claims (35)

1. An inkjet recording medium comprising:

a paper substrate; and

an inkjet-receptive coating comprising a primary pigment, wherein the primary pigment is a needle-shaped aragonite having a particle size distribution where at least 96% of the particles by weight have a particle size less than 2 microns;

a secondary pigment having an average particle size of 3 microns or less;

from about 2 to 8 parts by weight of an anionic binder based on 100 parts total pigments and a co-binder wherein the binder and co-binder are present at a ratio of less than 2.5:1 (binder:co-binder by weight).

2. The inkjet recording medium of claim 1 wherein said medium has a mottle value of less than 2.0 when printed with a pigmented inkjet ink.

3. The inkjet recording medium of claim 1 wherein said coating is free of titanium dioxide.

4. The inkjet recording medium of claim 1 wherein said binder is an anionic hydrophilic styrene butadiene/acrylonitrile (SBA) copolymer latex.

5. The inkjet recording medium of claim 1 wherein said co-binder is selected from the group consisting of protein binders, polyvinyl alcohol, starch and mixtures thereof.

6. The inkjet recording medium of claim 1 wherein said primary pigment is present in an amount of about 65 to 85 parts based on 100 parts total pigments.

7. The inkjet recording medium of claim 1 wherein said coating further comprises a plastic pigment present in an amount of about 2 to 8 parts per 100 parts total pigments.

8. The inkjet recording medium of claim 1 wherein said coating is present at a coat weight of about 2 to 7 lbs./ream (3,300 ft. 2 ).

9. The inkjet recording medium of claim 1 further comprising a top coat comprising a multivalent metal salt.

10. The inkjet recording medium of claim 1 further comprising a top coat comprising a divalent metal salt.

11. The inkjet recording medium of claim 10 wherein the divalent metal salt comprises calcium chloride.

12. The inkjet recording medium of claim 6 further comprising a top coat comprising a divalent metal salt wherein the top coat is present at a coat weight of from about 0.15 to about 2.5 gsm.

13. The inkjet recording medium of claim 12 wherein the binder is present in an amount of about 3.5 to 5 parts by weight based on 100 parts total pigments.

14. The inkjet recording medium of claim 1 wherein the binder comprises an anionic hydrophilic styrene butadiene/acrylonitrile (SBA) copolymer latex and the co-binder is starch.

15. The inkjet recording medium of claim 14 wherein said latex and starch are present in a ratio of less than 2:1 (latex:starch by weight).

16. An inkjet recording medium comprising:

a paper substrate; and

an inkjet-receptive coating comprising:

a primary pigment comprising needle-shaped aragonite having a particle size distribution where at least 96% of the particles by weight have a particle size less than 2 microns;

a secondary pigment having an average particle size of 3 microns or less; and

a binder; and

a top coat comprising a multivalent metal salt.

17. The inkjet recording medium of claim 16 wherein said medium has a mottle value of less than 2.0 when printed with a pigmented inkjet ink.

18. The inkjet recording medium of claim 16 wherein said binder is an anionic hydrophilic styrene butadiene/acrylonitrile (SBA) copolymer latex.

19. The inkjet recording medium of claim 16 wherein said coating further comprises a co-binder selected from the group consisting of protein binders, polyvinyl alcohol, starch and mixtures thereof.

20. The inkjet recording medium of claim 16 wherein said primary pigment is present in an amount of about 65 to 85 parts based on 100 parts total pigments.

21. The inkjet recording medium of claim 16 wherein said coating further comprises a plastic pigment present in an amount of about 2 to 8 parts per 100 parts total pigments.

22. The inkjet recording medium of claim 16 wherein said coating is present at a coat weight of about 2 to 7 lbs./ream (3,300 ft. 2 ).

23. The inkjet recording medium of claim 16 wherein the top coat comprises a divalent metal salt.

24. The inkjet recording medium of claim 23 wherein the divalent metal salt comprises calcium chloride.

25. The inkjet recording medium of claim 16 wherein the binder is present in an amount from about 2 to 10 parts by weight of a binder based on 100 parts total pigments.

Assignments (20)
RELEASE OF SECURITY INTEREST Recorded Mar 12, 2019
From: BARCLAYS BANK PLC
To: VERSO PAPER HOLDING LLC; VERSO MINNESOTA WISCONSIN LLC; VERSO PAPER LLC
Reel/Frame 048578/0183 →
RELEASE OF SECURITY INTEREST Recorded Feb 11, 2019
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: VERSO PAPER HOLDING LLC (AS SUCCESSOR IN INTEREST TO EACH OF NEWPAGE CORPORATION AND NEWPAGE CONSOLIDATED PAPERS INC.); VERSO MINNESOTA WISCONSIN LLC (AS SUCCESSOR IN INTEREST TO NEWPAGE WISCONSIN SYSTEM INC.); VERSO PAPER LLC
Reel/Frame 048293/0805 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 27, 2017
From: NEWPAGE CORPORATION
To: VERSO PAPER HOLDING LLC
Reel/Frame 041101/0838 →
RELEASE OF SECURITY INTEREST Recorded Jul 15, 2016
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: NEWPAGE CORPORATION; NEWPAGE WISCONSIN SYSTEM INC.; NEWPAGE CONSOLIDATED PAPERS INC.
Reel/Frame 039357/0700 →
RELEASE OF SECURITY INTEREST Recorded Jul 15, 2016
From: BARCLAYS BANK PLC
To: NEWPAGE CORPORATION; NEWPAGE CONSOLIDATED PAPERS, INC.; NEWPAGE WISCONSIN SYSTEM INC.
Reel/Frame 039166/0294 →
RELEASE OF SECURITY INTEREST Recorded Jul 15, 2016
From: BARCLAYS BANK PLC
To: NEWPAGE CORPORATION; NEWPAGE CONSOLIDATED PAPERS, INC.; NEWPAGE WISCONSIN SYSTEM INC.
Reel/Frame 039166/0501 →
RELEASE OF SECURITY INTEREST Recorded Jul 15, 2016
From: BARCLAYS BANK PLC
To: NEWPAGE CORPORATION; NEWPAGE CONSOLIDATED PAPERS, INC.; NEWPAGE WISCONSIN SYSTEM INC.
Reel/Frame 039355/0278 →
SECURITY INTEREST Recorded Jul 15, 2016
From: NEWPAGE CORPORATION; NEWPAGE WISCONSIN SYSTEM INC.; NEWPAGE CONSOLIDATED PAPERS, INC. (FKA STORA ENSO NORTH AMERICA CORP.); VERSO PAPER LLC
To: BARCLAYS BANK PLC
Reel/Frame 039357/0071 →
SECURITY INTEREST Recorded Jul 15, 2016
From: NEWPAGE CORPORATION; NEWPAGE WISCONSIN SYSTEM INC.; NEWPAGE CONSOLIDATED PAPERS, INC. (FKA STORA ENSO NORTH AMERICA CORP.); VERSO PAPER LLC
To: WELLS FARGO, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039358/0593 →
SECURITY INTEREST Recorded Jan 29, 2016
From: NEWPAGE INVESTMENT COMPANY, LLC; NEWPAGE CORPORATION
To: BARCLAYS BANK PLC
Reel/Frame 037618/0853 →
SECURITY INTEREST Recorded Jan 29, 2016
From: NEWPAGE INVESTMENT COMPANY LLC; NEWPAGE CORPORATION
To: BARCLAYS BANK PLC
Reel/Frame 037618/0877 →
INTELLECTUAL PROPERTY SECURITY INTEREST ASSIGNMENT AGREEMENT Recorded Jan 4, 2016
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 037415/0430 →
SECURITY AGREEMENT Recorded Mar 7, 2014
From: NEWPAGE CORPORATION; NEWPAGE CONSOLIDATED PAPERS INC.; NEWPAGE WISCONSIN SYSTEM INC.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 032410/0273 →
SECURITY AGREEMENT Recorded Mar 7, 2014
From: NEWPAGE CORPORATION; NEWPAGE CONSOLIDATED PAPERS INC.; NEWPAGE WISCONSIN SYSTEM INC.
To: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT AND COLLATERAL AGENT
Reel/Frame 032410/0239 →
SECURITY INTEREST RELEASE 029538/0131 Recorded Feb 27, 2014
From: BARCLAYS BANK PLC, AS COLLATERAL AGENT
To: NEWPAGE CORPORATION
Reel/Frame 032364/0671 →
SECURITY INTEREST RELEASE 029536/0941 Recorded Feb 27, 2014
From: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: NEWPAGE CORPORATION; NEWPAGE WISCONSIN SYSTEM INC.
Reel/Frame 032365/0043 →
SECURITY AGREEMENT Recorded Dec 28, 2012
From: NEWPAGE CORPORATION; NEWPAGE WISCONSIN SYSTEM INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 029536/0941 →
SECURITY AGREEMENT Recorded Dec 22, 2012
From: NEWPAGE CORPORATION
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 029538/0131 →
CORRECTIVE ASSIGNMENT TO CORRECT THE FIRST ASSIGNOR'S NAME PREVIOUSLY RECORDED ON REEL 024869 FRAME 0656. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT OF ASSIGNOR'S INTEREST. Recorded Aug 26, 2010
From: ROMANO, CHARLES E., JR.; SCHLIESMAN, LEONARD J., JR.; NIEMIEC, JAMES P.
To: NEWPAGE CORPORATION
Reel/Frame 024890/0088 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 23, 2010
From: ROMANO, CHARLEES E., JR.; SCHLIESMAN, LEONARD J., JR.; NIEMIEC, JAMES P.
To: NEWPAGE CORPORATION
Reel/Frame 024869/0656 →