Solvent-based and water-based carbon nanotube inks with removable additives
View Patent ↗In accordance with some embodiments, compositions and methods for forming solvent-based and water-based carbon nanotubes inks with removable additives are provided. In some embodiments, the ink composition comprises one or more carbon nanotubes, a solvent, and a removable additive, which may function as a stabilizing agent, a viscosity adjustment agent, or any suitable combination thereof. The removable additive may be removed from articles derived from the ink composition by means of thermal annealing.
1. An ink composition comprising:
a plurality of purified carbon nanotubes;
a solvent; and
a thermally decomposable additive which comprises polypropylene carbonate,
wherein the thermally decomposable additive is completely removed from a solid article formed using the ink composition by thermal annealing at a temperature lower than about 200° C., wherein the thermally decomposable additive is selected to act as a dispersal agent and a stabilization agent.
2. The ink composition of claim 1 , wherein the thermally decomposable additive is also selected to adjust viscosity of the ink based at least in part on molecular weight of the thermally decomposable additive.
3. The ink composition of claim 1 , wherein the solvent is an organic solvent selected from the group consisting of N-methylpyrrolidinone (NMP), propylene glycol monomethyl ether acetate (PGMEA), cyclohexanone, methyl ethyl ketone (MEK), and methyl isopropyl ketone.
4. The ink composition of claim 1 , wherein at least 90% of the plurality of purified carbon nanotubes are single-walled carbon nanotubes.
5. The ink composition of claim 4 , wherein the purified single-walled carbon nanotubes dispersed in the solvent are enriched in semiconducting or metallic carbon nanotubes in comparison to its distribution in initial as-produced single-walled carbon nanotube materials.
6. The ink composition of claim 1 , wherein at least 90% of the plurality of carbon nanotubes are double-walled carbon nanotubes.
7. The ink composition of claim 1 , wherein at least 90% of the plurality of carbon nanotubes are multi-walled carbon nanotubes.
8. The ink composition of claim 4 , wherein the plurality of purified carbon nanotubes are functionalized.
9. The ink composition of claim 1 , wherein the solid article formed using the ink composition is a thin film of the plurality of purified carbon nanotubes formed on a substrate.
10. The ink composition of claim 1 , wherein the solid article formed using the ink composition is a free standing carbon nanotube membrane.
11. The ink composition of claim 1 , wherein the polypropylene carbonate molecules wrap around the surface of the plurality of purified carbon nanotubes.
12. A method of preparing an ink composition according to claim 1 , the method comprising:
providing a plurality of carbon nanotubes;
providing a thermally decomposable additive which comprises polypropylene carbonate to the plurality of carbon nanotubes;
providing a solvent to the plurality of carbon nanotubes and the thermally decomposable additive, wherein the plurality of carbon nanotubes are dispersed within the solvent and wherein the thermally decomposable additive stabilizes the plurality of carbon nanotubes that are suspended in the solvent;
wherein the thermally decomposable additive is completely removed from a solid article formed using the ink composition by thermal annealing at a temperature lower than about 200° C.,
wherein the thermally decomposable additive is selected to act as a dispersal agent and a stabilization agent.
13. The method of claim 12 , further comprising applying the ink composition to a substrate.
14. The method of claim 13 , wherein the thermally decomposable additive is removed after applying the ink composition to the substrate.
15. The method of claim 13 , wherein the substrate is one of a glass substrate, a plastic substrate, and a sapphire substrate.
16. The method of claim 12 , wherein the thermally decomposable additive is also selected to adjust viscosity of the ink based at least in part on molecular weight of the thermally decomposable additive.
17. The method of claim 12 , wherein the solvent is an organic solvent selected from the group consisting of N-methylpyrrolidinone (NMP), propylene glycol monomethyl ether acetate (PGMEA), cyclohexanone, methyl ethyl ketone (MEK), and methyl isopropyl ketone.
18. The method of claim 12 , further comprising mixing the solvent with the thermally decomposable additive prior to dispersing the plurality of carbon nanotubes in the solvent.
19. The method of claim 12 , wherein the thermally decomposable additive is selected such that the plurality of carbon nanotubes are individually suspended within the solvent.
20. The method of claim 12 , wherein the thermally decomposable additive is selected such that the plurality of carbon nanotubes are substantially bundled within the solvent.
21. The method of claim 12 , further comprising depositing the ink composition onto a surface, wherein the ink composition forms an antistatic thin film on the surface.