Dehydration sensors having buffered inks
View Patent ↗A dehydration sensor having a stable, printable, buffered-ink composition that enables one to miniaturize the detection zone and permits both buffer and indicator dye to be applied in the same area of a detection zone, without need for a conventional, large buffer pad region.
1. A dehydration sensor that comprises:
a porous substrate, with a buffered ink system that is directly deposited on a portion of said substrate;
the buffered ink system is composed of 0.5-30 wt. % of a weak polymeric acid, 0.5 -3 wt. % of a polymeric stabilizer which functions as a proton-exchange hydrogen-bonding neutral buffer bridge, and a cationic surfactant; and
a pH-sensitive dye;
wherein said surfactant serves as an immobilization agent of the pH-sensitive dye and buffered ink system.
2. The dehydration sensor according to claim 1 , wherein said polymeric acid is one or a combination of the following: poly(acrylic acid), poly(methylvinylether-alt-maleic acid), poly(4-styrenesulfunic acid-co-maleic acid), or poly(methylvinylether-alt-maleic anhydride).
3. The dehydration sensor according to claim 1 , wherein said polymeric stabilizers is: a polyvinyl alcohol or a polyethylene oxide.
4. The dehydration sensor according to claim 1 , wherein said substrate is a polyester, cellulosic material, or rayon.
5. The dehydration sensor according to claim 1 , wherein buffered ink system is deposited in the same zone on said substrate as said pH-sensitive dye is deposited.
6. The dehydration sensor according to claim 1 , wherein said buffered ink system is deposited in separate zones from said pH-sensitive dye.
7. The dehydration sensor according to claim 1 , wherein said proton-exchange hydrogen bonding neutral buffer bridge that facilitates an exchange of protons between components of said buffer ink system, and protects said sensor from CO 2 -induced degradation.
8. The dehydration sensor according to claim 1 , wherein said proton-exchange hydrogen bonding neutral buffer bridge is a polyvinyl alcohol or a polyethylene oxide.
9. The dehydration sensor according to claim 1 , wherein said pH-sensitive dye exhibits a color transition at a pH from about 5.5 to about 10.5.
10. The dehydration sensor according to claim 1 , wherein said pH-sensitive dye is one of the following: bromocresol green, bromothymol blue, nitrazine yellow, meta-cresol purple, thymol blue, xylenol blue, cresol red, bromophenol blue, congo red, methyl orange, bromochlorophenol blue, ethyl orange, chrysoidin, methyl red, alizarin red S, cochineal, chlorophenol red, bromocresol purple, para-nitrophenol, alizarin, brilliant yellow, neutral red, rosolic acid, phenol red, meta-nitrophenol, or a combination thereof.
11. An absorbent article comprising:
a first, inner layer, an absorbent core, and a second, outer layer;
a lateral flow-based dehydration sensor for measuring the specific gravity of urine, said dehydration sensor has a substrate with a buffer pad;
said dehydration device is situated near an area of said inner layer that will be subjected to insult of urine, and which can be insulted either directly or by means of capillary transport;
said buffer pad has a detection zone in which is a buffered ink system that is directly deposited on said buffer pad;
said buffered ink system is composed of 0.5-30 wt. % of a weak polymeric acid, 0.5-3 wt. % of a polymeric stabilizer that functions as a proton-exchange hydrogen-bonding neutral buffer bridge, and a cationic surfactant; and a pH-sensitive dye; wherein said cationic surfactant serves as an immobilization agent of the pH-sensitive dye and buffered ink system.
12. The absorbent article according to claim 11 , wherein each of said several zones is in fluidic communication with each other either directly or indirectly by an adjacent component.
13. The absorbent article according to claim 11 , wherein said absorbent article is a diaper, adult incontinence product, or personal or feminine hygiene product, or absorbent pad for medical or hospital uses.