FRESHWATER DIATOMACEOUS EARTH PRODUCTS CONTAINING REDUCED SOLUBLE METAL LEVELS, PROCESSES FOR REDUCING SOLUBLE METAL LEVELS IN FRESHWATER DIATOMACEOUS EARTH PRODUCTS, AND METHODS OF USING THE SAME
Disclosed herein are freshwater diatomaceous earth products containing reduced soluble metal levels, processes for reducing soluble metal levels in freshwater diatomaceous earth products, and methods of using the same. In particular, freshwater diatomaceous earth products are disclosed that have been treated with at least one surface metal blocking agent, such as an organic silicone compound with at least one functional group capable of forming a chelating complex with metal ions, to reduce the level of soluble metals associated therewith. Such freshwater diatomaceous earth products containing reduced soluble metal levels may be useful for various applications including as filter aid materials.
1 . A process for decreasing the soluble metal content of at least one freshwater diatomaceous earth material, comprising treating the at least one freshwater diatomaceous earth material with at least one soluble metal blocking agent comprising at least one organic silicon component and at least one chelating functional group.
2 . The process of claim 1 , wherein the at least one chelating functional group is chosen from amino, phenyl, azide, carboxylate, phosphonate, sulfonate, epoxy, glycidoxy, vinyl, methacryl, isocyanato, mercaptan, and hydroxy groups.
3 . The process of claim 1 , wherein the at least one organic silicon component is chosen from silanes, siloxanes, and silicones.
4 . The process of claim 1 , wherein the at least one soluble metal blocking agent is chosen from 3-aminopropyltriethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3,4-epoxycyclohexyl ethyltrimethoxy silane, N-(2-Aminoethyl)-3-aminopropyltrialkoxysilane, N-(Aminoethyl)-3-aminopropylmethyldialkoxysilane, 3-ureidopropyltrialkoxysilane, vinyltrialkoxysilane, vinyldimethoxymethylsilane, vinyltris(2-methoxyethoxy)-silane, vinyltriacetoxysilane, (Methacryloxymethyl)methyldialkoxysilane, Methacryloxymethyltrimethoxysilane, Methacryloxypropyltrialkoxysilane, 3-Methacryloxypropyltrimethoxysilane, 3-Methacryloxypropyltriacetoxysilane, 3-Isocyanatopropyltrimethoxysilane, (Isocyanatomethyl)methyldimethoxysilane, and 3-Glycidoxypropylmethyldiethoxysilane.
5 . The process of claim 4 , wherein the at least one soluble metal blocking agent is chosen from 3-glycidoxypropyltrimethoxysilane and 3-aminopropyltriethoxysilane.
6 . The process of claim 1 , wherein the material is treated with the at least one soluble metal blocking agent in an amount ranging from about 0.2% to about 2%, relative to the weight of the at least one freshwater diatomaceous earth feed material.
7 . The process of claim 6 , wherein the material is treated with the at least one soluble metal blocking agent in an amount ranging from about 0.2% to about 0.6%, relative to the weight of the at least one freshwater diatomaceous earth feed material.
8 . The process of claim 1 , wherein the beer soluble iron content of the freshwater diatomaceous earth material is reduced by at least about 45%, as measured by the EBC method.
9 . The process of claim 8 , wherein the beer soluble iron content of the freshwater diatomaceous earth material is reduced by at least about 70%, as measured by the EBC method.
10 . (canceled)
11 . The process of claim 1 , wherein the beer soluble iron content of the freshwater diatomaceous earth material is reduced by at least about 90%, as measured by the ASBC method.
12 - 25 . (canceled)
26 . A treated freshwater diatomaceous earth product, comprising:
a freshwater diatomaceous earth material; and,
at least one soluble metal blocking agent comprising at least one organic silicon component and at least one chelating functional group.
27 . The product of claim 26 , wherein the at least one chelating functional group is chosen from amino, phenyl, azide, carboxylate, phosphonate, sulfonate, epoxy, glycidoxy, vinyl, methacryl, isocyanato, mercaptan, and hydroxy groups.
28 . The product of claim 26 , wherein the at least one organic silicon component is chosen from silanes, siloxanes, and silicones.
29 . The product of claim 26 , wherein the at least one soluble metal blocking agent is chosen from of 3-aminopropyltriethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3,4-epoxycyclohexyl ethyltrimethoxy silane, N-(2-Aminoethyl)-3-aminopropyltrialkoxysilane, N-(Aminoethyl)-3-aminopropylmethyldialkoxysilane, 3-ureidopropyltrialkoxysilane, vinyltrialkoxysilane, vinyldimethoxymethylsilane, vinyltris(2-methoxyethoxy)-silane, vinyltriacetoxysilane, (Methacryloxymethyl)methyldialkoxysilane, Methacryloxymethyltrimethoxysilane, Methacryloxypropyltrialkoxysilane, 3-Methacryloxypropyltrimethoxysilane, 3-Methacryloxypropyltriacetoxysilane, 3-Isocyanatopropyltrimethoxysilane, (Isocyanatomethyl)methyldimethoxysilane, and 3-Glycidoxypropylmethyldiethoxysilane.
30 . The product of claim 29 , wherein the at least one soluble metal blocking agent is chosen from 3-glycidoxypropyltrimethoxysilane and 3-aminopropyltriethoxysilane.
31 . (canceled)
32 . A method of filtering a liquid, comprising passing the liquid through at least one filter membrane comprising a treated freshwater diatomaceous earth product, comprising:
a freshwater diatomaceous earth material; and,
at least one soluble metal blocking agent comprising at least one organic silicon component and at least one chelating functional group.
33 . The method of claim 32 , wherein the at least one soluble metal blocking agent is present in an amount ranging from about 0.2% to about 2%, relative to the weight of the at least one freshwater diatomaceous earth material.
34 - 36 . (canceled)
37 . The method of claim 32 , wherein the beverage liquid is a beer.
38 . The method of claim 37 , wherein the beer soluble iron content of the beer is reduced by at least about 70%, as measured by the EBC method.
39 . The method of claim 37 , wherein the beer soluble iron content of the beer is reduced by at least about 80%, as measured by the ASBC method.
40 - 42 . (canceled)