IP Library Granted Patent US 9,447,363
Granted Patent B2
US 9,447,363 · App. 12/864,276 · Granted Sep 20, 2016

Composition

Inventors: Judith Preuschen (Ludwigshafen, DE); Ralf Wiedemann (Mira, IT)
Assignee: RECKITT BENCKISER FINISH B.V.
C11D3/3719
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,447,363
App. No.
12/864,276
Granted
Sep 20, 2016
Kind
B2
Abstract

The present invention relates to compositions comprising polyaspartic acid (PAS) derivatives and the use of said compositions in washing processes, especially in automatic dishwashing.

Claims (50)

1. A detergent comprising a compound of formula (I):

wherein:

M is selected from the group H, alkali metals, ammonium, optionally substituted alkyl ammonium or a mixture thereof;

X is selected from the group NR 1 , O and S or a mixture thereof, wherein R 1 is H or C 1-20 hydrocarbyl optionally substituted with hydroxy or C 1-8 alkyl;

Z is R 2 Y n , wherein

R 2 is selected from the group comprising:

linear or branched C 1 -C 20 alkyl, C 5-20 aralkyl, or cyclic C 3-10 alkyl each optionally substituted with C 1-8 alkyl, wherein the aralkyl may contain one or more heteroatoms selected from N, O and S; and

linear and branched —R 3 —(R 3 O) p or —R 5 —(N(R 4 )R 5 ) q wherein R 3 and R 5 are selected from linear or branched C 1 -C 10 alkyl and wherein R 4 is selected from the same group as R 1 and p and q are integers from 1 to 100; and

each Y is independently selected from:

the group of hydrophilic substituents containing PO 3 M; PO 2 M, PO 3 R 11 ; PO 2 R 12 ; OPO 3 M; OPO 2 M, OPO 3 R 11 ; OPO 2 R 12 ; and

the group of hydrophobic substituents containing NR 14 R 15 and NR 14 R 15 R 16 ;

wherein R 10 , R 11 , R 12 , R 13 , R 14 , R 15 and R 16 are each selected independently from each other from the group defined for R 2 ; and

R 8 is H or is selected from the same group as R 2 ;

provided that at least one hydrophobic Y group is present and at least eleven hydrophilic Y groups are present, and that the molar ratio of hydrophobic:hydrophilic substituents is from 1:1.1 to 1:1000;

n is an integer from 1 to 20;

k is an integer from 1 to 860;

l is an integer from 0 to 860;

m is an integer from 1 to 860; and

the total (k+l+m) is at least 40.

2. The detergent composition according to claim 1 wherein X is NR 1 .

3. The detergent composition according to claim 1 wherein:

R 2 is linear or branched —R 3 —(R 3 O) p or —R 5 —(N(R 4 )R 5 ) q ;

R 3 and R 5 are selected from linear or branched C 1 -C 10 alkyl: and,

R 4 is selected from the same group as R 1 and

p and q are integers from 1 to 100.

4. The detergent composition according to claim 1 wherein m/(k+l+m) is at least 0.1.

5. The detergent composition according to claim 1 wherein:

X is NR 1 and R 2 is linear or branched —R 3 —(R 3 O) p ; or,

X is NR 1 , R 2 is N heteroaryl.

6. The detergent composition according to claim 1 which further comprises at least one builder selected from the group consisting of:

citrate, citric acid, alkali carbonate, alkali bicarbonate, alkali hydroxide, methyl glycine-N, N-diacetic acid (MGDA), glutamic diacetic acid (GLDA), sodium iminodisuccinate (IDS), hydroxy-iminodisuccinic acid (H-IDS), silicate, disilicate, gluconates, heptonates and sodium tripolyphosphate (STPP).

7. The detergent composition according to claim 1 comprising

a) 0.1-40 wt.-% of at least one polyaspartic derivative of formula (I);

b) 15-60 wt.-% of at least one builder;

c) 5-25 wt.-% of at least one oxygen based bleaching agent;

d) 1-10 wt.-% of at least one bleach activator; and,

e) 0.1-5 wt.-% of at least one enzyme

based on the detergent composition as a whole.

8. The detergent composition according to claim 1 which is a solid powder, a tablet or a gel.

9. The detergent composition according to claim 8 which is a tablet, and which is enclosed in a pouch made of a soluble polymer.

10. The detergent composition according to claim 8 which is in a gel form, and which is enclosed in a pouch made of a soluble polymer wherein the pouch and gel form of the detergent composition is in the form of a gelpac.

11. A soluble polymer capsule comprising two or more compartments, each compartment independently filled with a detergent composition according to claim 8 wherein the detergent composition is a powder or a gel.

12. The detergent composition according to claim 9 which is a tablet, and which is enclosed in a pouch made of a soluble PVOH polymer.

13. A method of washing in a washing processes selected from hard surface cleaning, manual and automatic dishwashing, and laundry which method comprises the step of: utilizing a detergent composition according to claim 1 in the washing process.

14. The method according to claim 13 , wherein the washing process is automatic dishwashing.

15. A cartridge adapted for insertion into a washing machine or dishwashing machine which contains a detergent composition according to claim 1 .

16. A soluble polymer capsule comprising two or more compartments, each compartment independently filled with a detergent composition according to claim 1 wherein the detergent composition is a powder or a gel.

17. A method of washing in a washing processes selected from hard surface cleaning, manual and automatic dishwashing, and laundry which method comprises the step of: utilizing a detergent composition according to claim 8 in the washing process.

18. The method according to claim 17 , wherein the washing process is automatic dishwashing.

19. A cartridge adapted for insertion into a washing machine or dishwashing machine which contains a detergent composition according to claim 8 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 26, 2015
From: RECKITT BENCKISER N.V.
To: RECKITT BENCKISER FINISH B.V.
Reel/Frame 037160/0868 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2010
From: PREUSCHEN, JUDITH; WIEDEMANN, RALF
To: RECKITT BENCKISER N.V.
Reel/Frame 025199/0640 →
Priority Claims (2)
GB 0801497.9 · Jan 28, 2008 · national
GB 0821849.7 · Nov 29, 2008 · national
Continuity (1)
Related Publication 20110053819A1 · Mar 3, 2011