Separator for providing a uniting force to electrode and electrochemical cell containing the same
View Patent ↗A separator includes a porous substrate having a plurality of pores; a porous coating layer formed on at least one surface of the porous substrate and made of a mixture of a plurality of inorganic particles and a binder polymer; and a dot pattern layer formed on a surface of the porous coating layer and having a plurality of dots made of polymer and arranged at predetermined intervals. The separator may control short-circuit between positive and negative electrodes though an electrochemical device is overheated. Also, a united force to an electrode is enhanced due to the polymer dot pattern layer, thereby preventing the electrode and the separator from being separated. Accordingly, inorganic particles of the porous coating layer formed on the porous substrate are not separated, thereby improving stability of an electrochemical device.
1. A separator for an electrochemical device, comprising:
a porous substrate having a plurality of pores;
a porous coating layer formed on at least one surface of the porous substrate and made of a mixture of a plurality of inorganic particles and a binder polymer; and
a dot pattern layer formed on a surface of the porous coating layer to provide a uniting force between the separator and an electrode of the electrochemical device, the dot pattern having a plurality of dots made of polymer and arranged at predetermined intervals, wherein the dots have an average diameter of about 1 mm to 10 mm.
2. The separator according to claim 1 , wherein the dots are made of rubber.
3. The separator according to claim 2 , wherein the rubber is any one selected from the group consisting of natural rubbers, synthetic rubbers and their mixtures.
4. The separator according to claim 2 , wherein the rubber is a copolymer comprising a styrene unit and a butadiene unit.
5. The separator according to claim 4 , wherein the copolymer further comprises a hydrophilic functional group-containing unit.
6. The separator according to claim 5 , wherein the hydrophilic functional group is any one selected from the group consisting of maleic acid, acrylic acid, acrylate, carboxylic acid, nitrile group, hydroxyl group, mercapto group, ether group, ester group, amide group, amine group, acetate group and halogen group.
7. The separator according to claim 1 , wherein the intervals of the dots are 0.1 to 100 mm.
8. The separator according to claim 1 , wherein the dots have an average thickness of 0.001 to 10 μm.
9. The separator according to claim 1 , wherein the binder polymer has a solubility parameter of 15 to 45 Mpa 1/2 .
10. The separator according to claim 1 , wherein the binder polymer is any one selected from the group consisting of polyvinylidene fluoride-co-hexafluoropropylene, polyvinylidene fluoride-co-trichloroethylene, polymethylmethacrylate, polyacrylonitrile, polyvinylpyrrolidone, polyvinylacetate, polyethylene-co-vinyl acetate, polyethylene oxide, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethylpullulan, cyanoethylpolyvinylalcohol, cyanoethylcellulose, cyanoethylsucrose, pullulan, carboxyl methyl cellulose, acrylonitrile-styrene-butadiene copolymer, polyimide, and their mixtures.
11. The separator according to claim 1 , wherein inorganic particles have a size of 0.001 to 10 μm.
12. The separator according to claim 1 , wherein a weight ratio of the inorganic particles and the binder polymer is 50:50 to 99:1.
13. The separator according to claim 1 , wherein the porous coating layer has a thickness of 0.01 to 20 μm, a pore size of 0.001 to 10 μm, and porosity of 10 to 99%.
14. The separator according to claim 1 , wherein the porous substrate is formed with any one selected from the group consisting of polyethyleneterephthalate, polybutyleneterephthalate, polyester, polyacetal, polyamide, polycarbonate, polyimide, polyetheretherketone, polyethersulfone, polyphenyleneoxide, polyphenylenesulfidro, polyethylenenaphthalene, polyvinylidene fluoride, polyethyleneoxide, polyacrylonitrile, hexofluoropropylene copolymer, polyethylene, polypropylene, and their mixtures.
15. The separator according to claim 1 , wherein the porous substrate has a thickness of 5 to 50 μm, a pore size of 0. 001 to 50 μm, and porosity of 10 to 99%.
16. An electrochemical device, comprising a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode, wherein the separator comprises:
a porous substrate having a plurality of pores;
a porous coating layer formed on at least one surface of the porous substrate and made of a mixture of a plurality of inorganic particles and a binder polymer; and
a dot pattern layer formed on a surface of the porous coating layer to provide a uniting force between the separator and the positive and negative electrodes of the electrochemical device, the dot pattern having a plurality of dots made of polymer and arranged at predetermined intervals, wherein the dots have an average diameter of about 1 mm to 10 mm.
17. The electrochemical device according to claim 16 , wherein the electrochemical device is a lithium secondary battery.