Ceramic material and use thereof

1. A sintered compact of a ceramic material having a formula of Li a La b Zr x O c —Al, wherein a:b:x is approximately 7:3:2 and c is approximately 12, the sintered compact having a garnet-type or garnet-like crystal structure, and a density of not less than 4.0 g/cm 3 , wherein a ratio of a number of moles of Li with respect to La is 2.0 or greater to 2.3 or lower, and wherein the ceramic material contains Al in an amount of 0.1 mass % or more to 2 mass % or less with respect to a total mass of the ceramic material.

2. The sintered compact according to claim 1 , obtained by firing a raw material of the ceramic material having a molar ratio of Li to La that is above 2.1 to 2.3 or lower.

3. The sintered compact according to claim 1 , wherein the ratio of the number of moles of Li with respect to La is 2.0 or greater to 2.1 or lower.

4. The sintered compact according to claim 1 , which is a solid-state electrolyte material.

5. A secondary battery which is an all-solid-state lithium secondary battery, comprising:

a positive electrode;

a negative electrode; and

a solid-state electrolyte comprising a sintered compact of a ceramic material having a formula of Li a La b Zr x O c —Al, wherein a:b:x is approximately 7:3:2 and c is approximately 12, and having a garnet-type or garnet-like crystal structure, and a density of not less than 4.0 g/cm 3 , wherein a ratio of a number of moles of Li with respect to La is 2.0 or greater to 2.3 or lower, and wherein the ceramic material contains Al in an amount of 0.1 mass % or more to 2 mass % or less with respect to a total mass of the ceramic material.

6. An all-solid-state secondary battery using a sintered compact of the ceramic material according to claim 1 .

7. An air secondary battery using a sintered compact of the ceramic material according to claim 1 .

8. A lithium ion secondary battery using a sintered compact of the ceramic material according to claim 1 .

9. A method for producing a ceramic material, the method comprising steps of:

synthesizing the ceramic material having a formula of Li a La b Zr x O c —Al,

wherein a:b:x is approximately 7:3:2 and c is approximately 12, and having a garnet-type or garnet-like crystal structure, and a density of not less than 4.0 g/cm 3 ,

wherein a ratio of a number of moles of Li with respect to La is 2.0 or greater to 2.3 or lower, and

wherein the ceramic material contains Al in an amount of 0.1 mass % or more to 2 mass % or less with respect to a total mass of the ceramic material,

wherein the synthesis step comprises a first heat treatment step of acquiring a primary firing powder containing at least Li, La, Zr and O, and a second heat treatment step of obtaining the ceramic material by firing the primary firing powder in a presence of Al.

10. The method according to claim 9 , wherein the synthesis step comprises a step of preparing and firing a raw material in which Li and La are included with the ratio of the number of moles of Li with respect to La at above 2.1 to 2.3 or lower.

11. The method according to claim 10 , wherein La and Zr are included in the raw material with a ratio of a number of moles of Zr with respect to La at 0.67.

12. The method according to claim 9 , wherein the first heat treatment step is a step of acquiring the primary firing powder comprising Li, La, Zr and O, and the second heat treatment step is a step of firing an Al constituent and the primary firing powder.

13. The method according to claim 9 , wherein the second heat treatment step is a step of firing and sintering a formed compact containing the primary firing powder.

14. The method according to claim 9 , wherein synthesis of the ceramic material is carried out in an inert gas atmosphere.