Liquid crystal display and manufacturing method thereof
View Patent ↗The present invention relates to a liquid crystal display, wherein arrangement of liquid crystal molecules thereof is controlled by using a monomer that is polymerized by ultraviolet rays to provide a pre-tilt. To prevent damage to organic material layers when irradiating ultraviolet rays to the monomer, a blocking film made of an ultraviolet absorbing agent is formed on or over at least one such layer.
1. A liquid crystal display comprising:
a first panel;
a second panel including:
a thin film transistor;
an insulating layer comprising an organic material disposed on the thin film transistor;
a blocking film disposed directly on the insulating layer; and
a pixel electrode disposed on the blocking film; and
a liquid crystal layer between the first panel and the second panel, the liquid crystal layer having liquid crystal with a pre-tilt at least partially maintained by a polymerized polymer,
wherein the blocking film comprises an ultraviolet absorbing agent.
2. The liquid crystal display of claim 1 , wherein
the ultraviolet absorbing agent is amorphous titanium oxide.
3. The liquid crystal display of claim 1 , wherein the polymer includes:
a first polymerized polymer within the liquid crystal layer, and
a second polymer disposed along an inner surface of the first panel and an inner surface of the second panel, the inner surfaces each facing the liquid crystal layer.
4. The liquid crystal display of claim 1 , wherein
the second panel further includes a color filter disposed under the insulating layer.
5. The liquid crystal display of claim 1 ,
wherein the pixel electrode includes a plurality of branch electrodes.
6. The liquid crystal display of claim 5 , wherein
the pixel electrode has a plurality of sub-regions each having ones of the branch electrodes extending in a different direction from the ones of the branch electrodes in the other sub-regions.
7. The liquid crystal display of claim 6 , wherein
intervals between the branch electrodes of one sub-region are different from intervals between branch electrodes of another sub-region.
8. The liquid crystal display of claim 1 , wherein the second panel further comprises:
a first substrate;
a gate line disposed on the first substrate;
a step-down gate line parallel to the gate line;
a storage electrode line parallel to the gate line;
a gate insulating layer covering the gate line, the step-down gate line, and the storage electrode line;
a data line intersecting the gate line;
first and second sub-pixel electrodes disposed on the insulating layer and the blocking film; and
the thin film transistor comprising a first thin film transistor and a second thin film transistor,
wherein the first thin film transistor is connected to the gate line, the data line, and the first sub-pixel electrode; and
wherein the second thin film transistor is connected to the gate line, the data line, and the second sub-pixel electrode.
9. A method for manufacturing a liquid crystal display, comprising:
on a second panel, sequentially forming a thin film transistor, a color filter, an insulating layer comprising an organic material, a blocking film and a pixel electrode, wherein the blocking film is disposed directly on the insulating layer;
forming a liquid crystal layer between an first panel and the second panel;
applying an electric field to the liquid crystal layer; and
irradiating ultraviolet rays onto the liquid crystal.
10. The method of claim 9 , wherein
the liquid crystal layer includes a polymerized monomer.
11. The method of claim 10 , wherein
the monomer is a reactivity mesogen.
12. The method of claim 10 , wherein
the monomer is about 0.1-0.5 wt % of the liquid crystal layer.
13. The method of claim 10 , wherein
the polymerized monomer further comprises:
a first polymer disposed in the liquid crystal layer, and
a second polymer disposed along surfaces of the first panel and the second panel that face each other.
14. The method of claim 9 , wherein
ultraviolet rays irradiated onto the liquid crystal layer have a wavelength of about 300 nm to about 320 nm.
15. The method of claim 9 , further comprising
patterning the pixel electrode to form a plurality of branch electrodes.
16. The method of claim 9 , wherein
the blocking layer comprises an ultraviolet absorbing agent.
17. The method of claim 16 , wherein
the ultraviolet absorbing agent is amorphous titanium oxide.
18. A liquid crystal display comprising:
a first substrate;
a second substrate facing the first substrate;
a field generating electrode disposed on at least one of the first substrate and the second substrate; and
a liquid crystal layer interposed between the first substrate and the second substrate, the liquid crystal layer comprising liquid crystal molecules and a reactive mesogen,
wherein at least one of the first substrate and the second substrate includes an ultraviolet (UV)-blocking layer, the UV-blocking layer includes a UV-absorbing agent, and the UV-absorbing agent is an organic material including a chromophore comprising at least one selected from compounds represented by Formulae 1 and 2:
19. The liquid crystal display of claim 18 , wherein
the reactive mesogen is polymerized to an alignment polymer through a UV light irradiating process.
20. The liquid crystal display of claim 19 , wherein
the UV-blocking layer is disposed on the substrate that is not irradiated by the UV light among the first and second substrates.
21. The liquid crystal display of claim 20 , wherein
the UV-blocking layer is disposed on or under the field generating electrode.
22. The liquid crystal display of claim 21 , wherein
the UV-absorbing agent absorbs light having a wavelength of less than 400 nm.
23. The liquid crystal display of claim 21 , wherein
a thickness of the UV-blocking layer is over 0.05 um.
24. A method for manufacturing a liquid crystal display, comprising:
forming a gate line including a gate electrode on a first substrate;
forming a gate insulating layer on the gate line;
forming a data line including a source electrode and a drain electrode facing the source electrode on the gate insulating layer;
forming a color filter;
forming a leveling layer on the color filter;
forming an ultraviolet (UV)-blocking layer on the leveling layer;
forming a common electrode on a second substrate; and
interposing a mixture comprising liquid crystal molecules and a reactive mesogen between the first substrate and the second substrate,
wherein the UV-blocking layer includes a UV-absorbing agent, and the UV-absorbing agent is an organic material including a chromophore.
25. The method of claim 24 , further comprising
forming a pixel electrode on the UV-blocking layer of the first substrate.
26. The method of claim 24 , further comprising
forming a pixel electrode under the UV-blocking layer of the first substrate.
27. The method of claim 24 , further comprising:
applying a voltage to the pixel electrode and the common electrode; and
irradiating light to the mixture in the state in which the voltage is applied to the pixel electrode and the common electrode to light-polymerize the reactive mesogen.
28. The method of claim 27 , further comprising:
turning off the voltage to the pixel electrode and the common electrode; and
irradiating light to the mixture in the state in which the voltage is not applied to the pixel electrode and the common electrode to light-polymerize the reactive mesogen.
29. The method of claim 24 , wherein
the UV-absorbing agent absorbs light having a wavelength of less than 400 nm.
30. The method of claim 24 , wherein
the chromophore comprises at least one selected from compounds represented by Formulae 1 and 2: