Glass for information recording media substrate, glass substrate for magnetic disk and magnetic disk
View Patent ↗To provide a glass for an information recording media substrate, which is excellent in weather resistance. A glass for an information recording media substrate, which comprises, as represented by mol % based on oxide, from 61 to 66% of SiO 2 , from 11.5 to 17% of Al 2 O 3 , from 8 to 16% of Li 2 O, from 2 to 8% of Na 2 O, from 2.5 to 8% of K 2 O, from 0 to 6% of MgO, from 0 to 4% of TiO 2 and from 0 to 3% of ZrO 2 , provided that Al 2 O 3 +MgO+TiO 2 is at least 12%, and Li 2 O+Na 2 O+K 2 O is from 16 to 23%, wherein in a case of where B 2 O 3 is contained, its content is less than 1%. The above glass for an information recording media substrate, wherein when the glass is left under steam atmosphere at 120° C. at 0.2 MPa for 20 hours, and the amount of Li, the amount of Na and the amount of K, which precipitate on a surface of the glass are represented as C Li , C Na and C K respectively, C Na is at most 0.7 nmol/cm 2 , and C Li +C Na +C K is at most 3.5 nmol/cm 2 .
1. An information recording media, comprising glass substrate for a magnetic disk and a magnetic recording layer formed thereon, wherein said glass substrate comprises, as represented by mol % based on oxide:
from 61 to 66% of SiO 2 ,
from 11.5 to 17% of Al 2 O 3 ,
from 8 to 16% of Li 2 O,
from 2 to 8% of Na 2 O,
from 2.5 to 8% of K 2 O,
from 0 to 6% of MgO,
from 0 to 4% of TiO 2 ,
from 0 to 3% of ZrO 2 , and
from 0 to 1% of at least one alkaline earth metal oxide selected from the group consisting of CaO, SrO and BaO;
provided that Al 2 O 3 +MgO+TiO 2 at least 12%, and Li 2 O+Na 2 O+K 2 O is from 16 to 23%, and said glass comprises less than 1% of B 2 O 3 .
2. The information recording media according to claim 1 , wherein the glass comprises SiO 2 is at least 63.5%, and Al 2 O 3 is at most 14%.
3. The information recording media according to claim 1 , wherein the glass comprises no B 2 O 3 .
4. The information recording media according to claim 1 , wherein the glass has a density of at most 2.50 g/cm 3 .
5. The information recoding media according to claim 1 , wherein the glass has a Young's modulus of at least 80 GPa, and a specific modulus of at least 32 MNm/kg.
6. The information recording media according to claim 1 , wherein the glass has an average linear expansion coefficient of at least 85×10 −7 /° C. in a temperature range of from 50 to 350 ° C.
7. The information recording media according to claim 1 , wherein the glass satisfies (T L −T 4 ) <50° C., where T L is the liquidus temperature, and T 4 is the temperature at which the viscosity becomes 10 4 dPa·s.
8. The information recording media according to claim 1 , wherein the glass has a glass transition temperature of at least 520° C.
9. The information recording media according to claim 1 , wherein the glass comprises said at least one alkaline earth metal oxide selected from the group consisting of CaO, SrO and BaO in an amount of from 0 to 0.75 mol %.
10. The information recording media according to claim 1 , wherein the glass comprises said at least one alkaline earth metal oxide selected from the group consisting of CaO, SrO and BaO in an amount of from 0 to 0.5% mol %.
11. The information recording media according to claim 1 , wherein the glass comprises from 63.5 to 65 mol % of SiO 2 .
12. The information recording media according to claim 1 , wherein the glass comprises from 12 to 14 mol % of Al 2 O 3 .
13. The information recording media according to claim 1 , wherein the glass comprises from 10 to 13 mol % of Li 2 O.
14. The information recording media according to claim 1 , wherein the glass comprises from 3 to 7 mol % of Na 2 O.
15. The information recording media according to claim 1 , wherein the glass comprises from 3 to 5 mol % of K 2 O.
16. The information recording media according to claim 1 , wherein the glass comprises from 19 to 21 mol % of Li 2 O+Na 2 O+K 2 O.