Thermoelectric material and composites made from thermoelectric material and a method for fabricating thereof
The thermoelectric material according to the present invention is characterized in that carbon nanotubes are dispersed in thermoelectric matrix powder by mechanically grinding, mixing, and treating by heating a mixed powder formed through a chemical reaction after mixing a first solution in which carbon nanotubes are dispersed and a second solution containing metallic salts. Further, a method for fabricating the thermoelectric material includes fabricating the first solution and the second solution, mixing the first solution and the second solution with each other to form a mixed solution, forming and growing a mixed powder in which carbon nanotubes and metals are mixed by a chemical reaction of the mixed solution, mechanically grinding and mixing the mixed powder, and heating the ground-and-mixed mixed powder to form the thermoelectric material. In addition, a composite can be made from the thermoelectric material by performing a spark plasma sintering process using the thermoelectric material, and has an improved thermoelectric efficiency due to the carbon nanotubes dispersed in the thermoelectric materials.
1. A thermoelectric material, comprising:
a mixed powder; and
carbon nanotubes dispersed within and embedded inside the mixed powder,
wherein the carbon nanotubes are dispersed within and embedded inside the mixed powder by mechanically grinding, mixing, and treating with heat the mixed powder,
wherein the mixed powder is formed by a chemical reaction between a first solution in which the carbon nanotubes are dispersed and a second solution having metallic salts, and
wherein said mixed powder comprises tellurium (Te) and bismuth (Bi), and further comprises one or both of antimony (Sb) and selenium (Se).
2. The thermoelectric material according to claim 1 , wherein said carbon nanotubes are multi-walled carbon nanotubes.
3. The thermoelectric material according to claim 1 , wherein the thermoelectric material comprises 1 to 10% volume fraction of said carbon nanotubes.
4. A composite of thermoelectric material, the composite comprising thermoelectric material and formed by passing the thermoelectric material through a spark plasma sintering process, wherein the thermoelectric material comprises:
a mixed powder; and
carbon nanotubes dispersed within and embedded inside the mixed powder,
wherein the carbon nanotubes are dispersed within and embedded inside the mixed powder through mechanical pulverization, mixture, and treatment by heating of the mixed powder,
wherein the mixed powder is formed by a chemical reaction after mixing a first solution in which the carbon nanotubes are dispersed and a second solution containing metallic salts, and
wherein said mixed powder comprises tellurium (Te) and bismuth (Bi), and further comprises one or both of antimony (Sb) and selenium (Se).
5. The composite according to claim 4 , wherein said carbon nanotubes are multi-walled carbon nanotubes.