Method for producing polytetrafluoroethylene fine powder
View Patent ↗The present invention provides a method for producing a polytetrafluoroethylene fine powder, which comprises emulsion polymerizing tetrafluoroethylene in the presence of an aqueous medium, a fluorinated surfactant and a radical polymerization initiator to produce an aqueous polytetrafluoroethylene emulsion, mixing and coagulating the aqueous emulsion to separate a polytetrafluoroethylene fine powder, and then drying the polytetrafluoroethylene fine powder in a wet state in an atmosphere containing ammonia.
1. A method for producing a polytetrafluoroethylene fine powder, which comprises
emulsion polymerizing tetrafluoroethylene in the presence of an aqueous medium, a fluorinated surfactant and a radical polymerization initiator to produce an aqueous polytetrafluoroethylene emulsion,
mixing and coagulating the aqueous emulsion to separate a polytetrafluoroethylene fine powder, and then
drying the polytetrafluoroethylene fine powder in a wet state in an atmosphere containing ammonia by heating at from 110 to 250° C., wherein the amount of the ammonia is from 0.1 to 10 parts by mass per 100 parts by mass of the dried polytetrafluoroethylene fine powder.
2. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the polytetrafluoroethylene fine powder in a wet state is dried in the presence of at least one member selected from the group consisting of ammonia, an ammonium salt and urea.
3. The method for producing a polytetrafluoroethylene fine powder according to claim 2 , wherein the amount of the ammonia, ammonium salt or urea to be used is from 0.1 to 10 parts by mass per 100 parts by mass of the dried polytetrafluoroethylene fine powder.
4. The method for producing a polytetrafluoroethylene fine powder according to claim 2 , wherein the ammonium salt is ammonium carbonate.
5. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the number of carbon atoms in a fluorinated compound constituting the fluorinated surfactant is from 4 to 10.
6. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the fluorinated surfactant is at least one member selected from the group consisting of a fluorinated carboxylic acid having from 1 to 4 etheric oxygen atoms in the molecule and salts thereof, a perfluoroalkylcarboxylic acid and salts thereof, and a fluorinated sulfonic acid and salts thereof.
7. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the polytetrafluoroethylene fine powder in a wet state has a water content of from 25 to 50 mass%.
8. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the time for drying in the atmosphere containing ammonia is from 4 to 20 hours.
9. The method for producing a polytetrafluoroethylene line powder according to claim 1 , wherein the fluorinated surfactant is at least one member selected from the group consisting of perfluorohexanoic acid, perfluoroheptanoic acid, C 4 F 9 OCF(CF 3 )COOH, C 4 F 9 OCF 2 CF 2 COOH, CF 3 OCF 2 CF 2 CF 2 OCF 2 COOH, C 2 F 5 OCF 2 CF 2 OCF 2 COOH, CF 3 OCF 2 OCF 2 OCF 2 COOH, C 4 F 9 OCF 2 COOH, C 3 F 7 OCF 2 CF 2 COOH, CF 3 OCF 2 CF 2 OCF 2 COOH, C 2 F 5 OCF 2 CF 2 COOH and salts thereof.
10. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the fluorinated surfactant is at least one member selected from the group consisting of perfluorohexanoic acid, C 2 F 5 OC 2 F 4 OCF 2 COOH, CF 3 OC 2 F 4 OCF 2 COOH, C 4 F 9 OCF 2 COOH and ammonium salts thereof.
11. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the polytetrafluoroethylene fine powder in a wet state is dried in the presence of ammonia.
12. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the polytetrafluoroethylene fine powder in a wet state is dried in the presence of an ammonium salt.
13. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the polytetrafluoroethylene fine powder in a wet state is dried in the presence of urea.
14. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the polytetrafluoroethylene fine powder in a wet state is dried in the presence of an ammonium salt, and the ammonium salt is ammonium carbonate.
15. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the polytetrafluoroethylene fine powder in a wet state is dried in the presence of ammonia, and the concentration of ammonia is 0.001 to 3.0 g/L.
16. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the amount of the ammonia is from 0.1 to 7 parts by mass per 100 parts by mass of the dried polytetrafluoroethylene fine powder.
17. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the amount of the ammonia is from 0.1 to 5 parts by mass per 100 parts by mass of the dried polytetrafluoroethylene fine powder.
18. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the heating is conducted at 120 to 230° C.
19. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the dried polytetrafluoroethylene fine powder has a standard specific gravity of 2.140 to 2.180.
20. The method for producing a polytetrafluoroethylene fine powder according to claim 1 , wherein the dried polytetrafluoroethylene fine powder has a standard specific gravity of 2.140 to 2.170.